Linkages between spatio‐temporal patterns of environmental factors and distribution of plant assemblages across a boreal peatland complex

Here we examine the arrangement of plant species across an oligotrophic bog/poor fen peatland complex in the North American boreal plain and the relationships of these species to their physical and chemical environment. A semi‐uniform spatial sampling approach was utilized to describe the species assemblages, pore‐water chemistry and physical condition of 100 plots throughout a single peatland complex. Regardless of sharing the same ground cover of Sphagnum mosses, the remaining species separated into four distinct assemblages, each with unique indicators. These species groups along with associated chemical and physical factors are organized into four ecosites: bog, margin (edge) and two poor fen ecosites. The plant assemblages of this peatland have a complex relationship with numerous gradients, both physical and chemical, including depth to water table, shade, pH, nutrient and base cation. Rather than being homogenous across the landscape, most environmental variables exhibit distinct spatial patterns and do so in relationship to the plant assemblages, forming spatially distinct ecosites across the complex. Base cation concentrations play a smaller role than previously thought in differentiating these ecosites, and in addition to shade and depth to water table, nitrogen in the form of dissolved organic nitrogen was highly related to the placement of these ecosites. Many significant chemical factors appear related to evaporative water loss within the peatland complex, and these chemical factors are used to differentiate the ecosites. However, the mediation of evaporative water loss is due largely to self‐generated responses of the plant assemblages related to shade through plant morphology and peat acrotelm development related to depth to water table. We conclude that plant species and associated environmental gradients act together to form spatially distinct ecosites. The distribution of these ecosites within this large, environmentally complex peatland is largely controlled by differing self‐generated responses along the hydrotopographical gradient of differential water loss.     

Characterization of dissolved organic matter across the Subtropical Convergence off the South Island,New Zealand

Dissolved organic matter (DOM) was investigated along a gradient across the Subtropical Convergence (STC) off the South Island, New Zealand. Ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS), excitation emission matrix fluorescence (EEM) spectroscopy, and molecular lignin analysis techniques were used to study this DOM. The analysis revealed a group of compounds found only in the coastal DOM samples, which were also characterized by an elevated terrestrial DOM fluorescence pattern and elevated lignin content if compared to the offshore samples. This group exhibited a high degree of carbon unsaturation, as evident from high double bond equivalence minus oxygen values (DBE-O > 9) and maximum fluorescence intensity. Sulfur-containing molecular formulae for summer DOM samples were much more abundant across the entire transect of the STC compared to winter and exhibited distinctly different hydrogen:carbon and oxygen:carbon elemental ratios, suggesting a possible correlation between biological activity and sulfur compounds. The molecular formulae common to all STC samples were compared with those calculated for DOM extracted from freshwater collected from a stream discharging into Doubtful Sound (West Coast, New Zealand). ESI-FT-ICR-MS measurements undertaken in negative electrospray ionization (ESI?) mode indicated that 30% of the molecular formulae were present in both types of DOM, while in positive ESI mode (ESI+) over 90% of the formulae were present in all samples. Hence, a significant portion of the molecular formulae assigned to the solid-phase extractable DOM pool (SPE-DOM) appear to be identical in oceanic and freshwater samples.     

Pyrite—‘fool's gold’ or misunderstood mineral?

Pyrite (FeS₂) is the most abundant sulphide mineral in the Earth's crust, and with its characteristic shape and appearance, is easily one of the most recognizable. Yet, pyrite has a somewhat tarnished reputation with many considering it to be waste material and of little economic importance, never-mind interest. This assessment however, is misleading and a considerable volume of current research focuses upon the unique characteristics and formation of pyrite. Indeed, with its potential for revealing the very foundations of life, as well as maximizing the discovery and exploitation of society's future metallic resources, pyrite may be of much greater interest and benefit than many geologists realize.     

The Eltanin asteroid impact: possible South Pacific palaeomegatsunami footprint and potential implications for the Pliocene–Pleistocene transition

Large asteroid impacts are rare, and those into the deep ocean are rarer still. The Eltanin asteroid impact around 2.51 ± 0.07 Ma occurred at a time of great climatic and geological change associated with the Pliocene–Pleistocene boundary. Numerical models of the event indicate that a megatsunami was generated, although there is debate concerning its magnitude and the region‐wide extent of its influence. We summarise the existing evidence for possible Eltanin megatsunami deposits in Antarctica, Chile and New Zealand, while also examining other potential sites from several locations, mainly around the South Pacific region. In reviewing these data we note that these events were unfolding at the same time as those associated with the Pliocene–Pleistocene boundary and, as such, most of the geological evidence from that time has a climatic interpretation. The potential climatic and geological ramifications of the Eltanin asteroid impact, however, have failed to be considered by most researchers studying this time period. Although we are not advocating that all geological activity at that time is connected with the Eltanin asteroid impact, it raises interesting questions about the role potentially played by such catastrophic events in contributing to or even triggering epochal transitions. Copyright © 2012 John Wiley & Sons, Ltd.     

Process length variation of the cyst of the dinoflagellate Protoceratium reticulatum in the North Pacific and Baltic‐Skagerrak region: calibration as an annual density proxy and first evidence of pseudo‐cryptic speciation

Process length variation of cysts of the dinoflagellate Protoceratium reticulatum (Claparède et Lachmann) Bütschli in surface sediments from the North Pacific was investigated. The average process length showed a significant inverse relation to annual seawater density: σ_{t annual} = ?0.8674 × average process length + 1029.3 (R² = 0.84), with a standard error of 0.78 kg m^?3. A sediment trap study from Effingham Inlet in British Columbia revealed the same relationship between average process length and local seawater density variations. In the Baltic–Skagerrak region, the average process length variation was related significantly to annual seawater density: σ_{t annual} = 3.5457 × average process length ? 993.28 (R² = 0.86), with a standard error of 3.09 kg m^?3. These calibrations cannot be reconciled, which accentuates the regional character of the calibrations. This can be related to variations in molecular data (small subunit, long subunit and internal transcribed spacer sequences), which show the presence of several genotypes and the occurrence of pseudo‐cryptic speciation within this species. Copyright © 2012 John Wiley & Sons, Ltd.     

Estimating impacts of warming temperatures on California's electricity system

Despite a clear need, little research has been carried out at the regional-level to quantify potential climate-related impacts to electricity production and delivery systems. This paper introduces a bottom-up study of climate change impacts on California's energy infrastructure, including high temperature effects on power plant capacity, transmission lines, substation capacity, and peak electricity demand. End-of-century impacts were projected using the A2 and B1 Intergovernmental Panel on Climate Change emission scenarios. The study quantifies the effect of high ambient temperatures on electricity generation, the capacity of substations and transmission lines, and the demand for peak power for a set of climate scenarios. Based on these scenarios, atmospheric warming and associated peak demand increases would necessitate up to 38% of additional peak generation capacity and up to 31% additional transmission capacity, assuming current infrastructure. These findings, although based on a limited number of scenarios, suggest that additional funding could be put to good use by supporting R&D into next generation cooling equipment technologies, diversifying the power generation mix without compromising the system's operational flexibility, and designing effective demand side management programs.     

Initialization and data assimilation experiments with a primitive equation model

The process of combining models of the ocean circulation with large data sets is known in meteorology as model initialization and data assimilation. This process is new to oceanographers, who only now are on the verge of having available world-wide synoptic maps of dynamic variables. In this paper we carry out a series of idealized initialization/assimilation experiments with a primitive equation (PE) model, which constitute a first step in developing a realistic process model and data assimilation techniques for the Gulf Stream system. The PE model is used in a spin-down mode and initialized with an analytic jet profile with geostrophically balanced fields.Two major questions are addressed in the present study. The first concerns the initialization process of a PE model during which internal/inertial gravity wave noise is produced. We ask: are the initialization shocks equally crucial for ocean models as they have been for their atmospheric counterparts? The results of an extensive series of balanced versus unbalanced initializations indicate that, for a PE model with a rigid lid, a brutally unbalanced initialization is required to produce strong internal gravity wave shocks. A geostrophically balanced initialization is sufficient to ensure smooth jet evolutions, with no apparent gravity waves, over long time durations in the spin-down mode. No sophisticated initialization procedures seem, therefore, to be required.The second question addressed is: which component of the flow is the most important in data assimilation to drive the model response towards a baseline reference ocean? We specifically compare the knowledge of the depth-integrated flow only, corresponding to measurements of the total transport, with the knowledge of the density field only, or equivalently the velocity shear. The knowledge of the interior density field is much more effective in decreasing the root-mean-square (r.m.s.) errors relative to the reference ocean. If the baroclinic structure is known, coarse horizontal resolutions of data insertion can be reached before significantly worsening the model estimates. If only the depth-averaged flow is known, a decrease in the horizontal resolution of data assimilation has an immediate effect: the r.m.s. errors sharply increase and the assimilation run diverges from the reference ocean. In the assimilation of the barotropic flow alone, even with dense resolution, the errors in the deep layers always show an increasing trend. The relative effectiveness of baroclinic versus barotropic data insertion can be rationalized in the context of geostrophic adjustment theory.