Dewatering of an unvegetated muddy tidal flat during exposure—Desiccation or drainage?

An unvegetated muddy tidal flat was sampled to determine the changes in surface pore water content and salinity during exposure. Local evaporation accounted for 61% of the upper intertidal surface salinity, with evaporation rates increasing salinity as high as 2.2‰ per hour. In contrast, only 37% of the decrease in pore water content was attributed to evaporative processes. This suggests that drainage (a combination of porosity and permeability) controlled the water content rather than local evaporative conditions.     

The oxidation state of manganese in marine sediments and ferromanganese nodules

Marine sediments and ferromanganese nodules from the Pacific Ocean have been analyzed for the $\text{O}\text{Mn}$ ratio of solid manganese. We tested six chemical methods and concluded that the iodometric and oxalate methods were equivalent and were the best choice in terms of accuracy and precision on natural samples. We choose the iodometric method for most of our analyses because the oxalate procedure is a method of differences.The ferromanganese nodules that we analyzed were all from MANOP site H and had $\text{Mn}\text{Fe}$ ratios that ranged from 5.6 to 70. These nodules were invariably highly oxidized with $\text{O}\text{Mn}$ values ranging from 1.90 to 2.00. Our most precise analyses suggest that less than 1% of the total manganese is present as Mn(II).We also analyzed red clay and hemipelagic sediments from the eastern tropical Pacific (Baja borderland and MANOP site H) and carbonate ooze samples from the equatorial Pacific. These sediments are also highly oxidized ($\text{O}\text{Mn}\text{= 1.90 to 2.00}$) except when Mn(II) appears in the interstitial water. As dissolved Mn(II) increases the value of the $\text{O}\text{Mn}$ ratio in the solid phase decreases. The $\text{O}\text{Mn}$ ratio decreases to values as low as 1.40. This decrease appears to be due to a decrease in oxidized manganese by reduction, however, an increase in reduced manganese in the solid sediments by adsorption or MnCO₃ formation can not be ruled out in all cases.     

The last interglacial ocean

The final effort of the CLIMAP project was a study of the last interglaciation, a time of minimum ice volume some 122,000 yr ago coincident with the Substage 5e oxygen isotopic minimum. Based on detailed oxygen isotope analyses and biotic census counts in 52 cores across the world ocean, last interglacial sea-surface temperatures (SST) were compared with those today. There are small SST departures in the mid-latitude North Atlantic (warmer) and the Gulf of Mexico (cooler). The eastern boundary currents of the South Atlantic and Pacific oceans are marked by large SST anomalies in individual cores, but their interpretations are precluded by no-analog problems and by discordancies among estimates from different biotic groups. In general, the last interglacial ocean was not significantly different from the modern ocean. The relative sequencing of ice decay versus oceanic warming on the Stage 6/5 oxygen isotopic transition and of ice growth versus oceanic cooling on the Stage 5e/5d transition was also studied. In most of the Southern Hemisphere, the oceanic response marked by the biotic census counts preceded (led) the global ice-volume response marked by the oxygen-isotope signal by several thousand years. The reverse pattern is evident in the North Atlantic Ocean and the Gulf of Mexico, where the oceanic response lagged that of global ice volume by several thousand years. As a result, the very warm temperatures associated with the last interglaciation were regionally diachronous by several thousand years. These regional lead-lag relationships agree with those observed on other transitions and in long-term phase relationships; they cannot be explained simply as artifacts of bioturbational translations of the original signals.     

Petrology of garnet-, spinel-, and sillimanite-bearing granites from the bavarian forest,West Germany

Mineralogy and Petrology - Samples from 17 small granitic intrusions of late-Variscan age have been investigated for their chemical compositions and petrographic characteristics. All of them...     

A Dynamic Architecture for Distributing Geographic Information Services

Traditional GISystems are no longer appropriate for modern distributed, heterogeneous network environments due to their closed architecture, and their lack of interoperability, reusability, and flexibility. Distributed GIServices can provide broader capabilities and functions for data management, browsing, and exchange. This paper introduces a dynamic architecture for distributing GIServices. The term dynamic indicates that the architecture is constructed temporarily by connecting or migrating geodata objects and GIS components across a network. The intention of the paper is to overview components and protocols necessary for a workable implementation of dynamically linked GIServices. The paper introduces a metadata scheme for both geodata objects and software components, and proposes an implementation framework based on existing languages, computing architectures and web services. In the framework, GIS nodes form the basic processing unit. All GIServices can be accomplished through collaboration between GIS nodes. The design of the presented framework emphasizes scalability, reusability, and dynamic integration. Current distributed computing environments cannot fully support dynamic architectures for technical and other reasons. Throughout the discussion, we distinguish what currently can be implemented from what cannot. We summarize costs and benefits of adopting a dynamic GIServices paradigm in a final section.     

Facies analysis of coal seams from the Cracow Sandstone Series of the Upper Silesia Coal Basin, Poland

The main purpose of this study was to recognise the variability of petrographical structure of two coal seams occurring in the Cracow Sandstone Series (Upper Carboniferous/Pennsylvanian, Upper Westphalian), being exploited in the Siersza mine. This mine is located in the eastern part of the Upper Silesia Coal Basin (USCB). The chemical analyses and petrographical features allow the inclusion of these coals to the group of hard brown coals belonging to subbituminous class.Two coal seams (207 and 209/210) of a considerable thickness (7.44 and 6.54 m, respectively), representative of the Cracow Sandstone Series (CSS), were chosen for the petrographic studies. Dominant macroscopic constituents of both seams are banded bright coal and banded coal.The coal seams were sampled in 284 intervals using a channel profile sampling strategy. The microscopical examinations revealed the majority of macerals from the vitrinite group (55%), followed by inertinite (21%), liptinite (11%), and mineral matter (13%). Low values of the vitrinite reflectance (R_o=0.46%) confirm very low coalification of the coal in both seams. Facies analysis indicates that in the course of a mire development, in which the studied coal seams originated, wet forest swamp conditions dominated characterized by a high degree of flooding and gelification as well as by a prevalence of arborescent plants. In such conditions, lithotypes with a large content of bright coal were mainly formed. Petrographic and facies data point to the rheotrophic character of these peatbogs. Frequent changes of the conditions in the peatbog, as it is shown by the variability of petrographic structure of the studied profiles, as well as by lateral changes of the phytogenic sedimentary environment within the coal seams, indicate a strong influence of a river channel on the adjoining peatbogs. An accretion of clastic sediments within the wide river channel belts was balanced mainly by the peatbog growth on the areas outside channels. Frequency and rate of avulsion of the river channels influenced the size, continuity and variability of the peatbogs.     

Spatial transferability of the physically based model TRIGRS using parameter ensembles

The development of better, more reliable and more efficient susceptibility assessments for shallow landslides is becoming increasingly important. Physically based models are well-suited for this, due to their high predictive capability. However, their demands for large, high-resolution and detailed input datasets make them very time-consuming and costly methods. This study investigates if a spatially transferable model calibration can be created with the use of parameter ensembles and with this alleviate the time-consuming calibration process of these methods. To investigate this, the study compares the calibration of the model TRIGRS in two different study areas. The first study area was taken from a previous study where the dynamic physically based model TRIGRS was calibrated for the Laternser valley in Vorarlberg, Austria. The calibrated parameter ensemble and its performance from this previous study are compared with a calibrated parameter ensemble of the model TRIGRS for the Passeier valley in South Tyrol, Italy. The comparison showed very similar model performance and large similarities in the calibrated geotechnical parameter values of the best model runs in both study areas. There is a subset of calibrated geotechnical parameter values that can be used successfully in both study areas and potentially other study areas with similar lithological characteristics. For the hydraulic parameters, the study did not find a transferable parameter subset. These parameters seem to be more sensitive to different soil types. Additionally, the results of the study also showed the importance of the inclusion of detailed information on the timing of landslide initiation in the calibration of the model.     

Effect of source-varying input data on erosion potential model performance

This paper examines the performance of the Erosion Potential Method (EPM or Gavrilovi?) and the model response to input data variations caused by choosing different sources of information for the same parameter. The research presented addresses the input data uncertainty via an analysis of the two model input parameters (the soil protection coefficient and the soil erodibility coefficient). The parameter uncertainty analysis is performed following two different approaches: uncertainty analyses of both the selected sample size and the entire population are conducted for an erosion assessment case study of the Dubra?ina River catchment, Croatia. The analysis indicated that, when changing the data source, significant changes in the model outcome values can occur (up to 47% for this case study). Future method modifications should consider the mitigation of these two parameters by potentially making structural changes in the model and therefore moderating the effect.     

Weathering of Oil in a Surficial Aquifer

The composition of crude oil in a surficial aquifer was determined in two locations at the Bemidji, MN, spill site. The abundances of 71 individual hydrocarbons varied within 16 locations sampled. Little depletion of these hydrocarbons (relative to the pipeline oil) occurred in the first 10 years after the spill, whereas losses of 25% to 85% of the total measured hydrocarbons occurred after 30 years. The C_6‐30 n‐alkanes, toluene, and o‐xylene were the most depleted hydrocarbons. Some hydrocarbons, such as the n‐C_10–24 cyclohexanes, tri‐ and tetra‐ methylbenzenes, acyclic isoprenoids, and naphthalenes were the least depleted. Benzene was detected at every sampling location 30 years after the spill. Degradation of the oil led to increases in the percent organic carbon and in the δ ¹³C of the oil. Another method of determining hydrocarbon loss was by normalizing the total measured hydrocarbon concentrations to that of the most conservative analytes. This method indicated that the total measured hydrocarbons were depleted by 47% to 77% and loss of the oil mass over 30 years was 18% to 31%. Differences in hydrocarbon depletion were related to the depth of the oil in the aquifer, local topography, amount of recharge reaching the oil, availability of electron acceptors, and the presence of less permeable soils above the oil. The results from this study indicate that once crude oil has been in the subsurface for a number of years there is no longer a “starting oil concentration” that can be used to understand processes that affect its fate and the transport of hydrocarbons in groundwater.     

Perturbation Features Imprinted on Ionosphere by Successive Clusters of Strong Earthquakes: Role of Atmospheric Coupling Dynamics

Geomagnetism and Aeronomy - The paper presents atmospheric coupling physics through identifying a few significant features imprinted on the ionosphere by certain unique seismic environments when a...