Surface circulation of the Indian Ocean during the last glacial maximum, approximately 18,000 yr B.P.

A seasonal reconstruction of the Indian Ocean during the last glacial maximum (18,000 yr B.P.) reveals that its surface circulation and sea surface temperature patterns were significantly different from the modern Indian Ocean. This reconstruction is based on the planktonic foraminiferal biogeography and estimated sea surface temperatures in 42 Indian Ocean samples. Compared to modern conditions, the polar front was 5° to 10° latitude further north during the last glacial maximum; the Subtropical Convergence was 2° to 5° latitude further north. The West Australian Current was more intense as part of the West Wind Drift was deflected northward along the coast of Australia. The Agulhas Current was cooler and weaker during the summer and more saline and subtropical during the winter. In general, the low latitudes underwent little temperature change. The western Arabian Sea was warmer which implies less upwelling and a weaker Southwest Monsoon. On the average, the Indian Ocean was 1.9°C cooler in February and 1.7°C cooler in August during the last glacial maximum.     

The influence of carbon source on abiotic organic synthesis and carbon isotope fractionation under hydrothermal conditions

A series of laboratory experiments were performed to investigate the relative contributions of CO and other single-carbon compounds to abiotic synthesis of organic compounds in hydrothermal environments. Experiments were conducted by heating aqueous solutions of CO, CO₂, HCOOH, or CH₄ at 250 °C under reducing conditions, and observing production of CH₄ and other hydrocarbons. Native Fe was included in the experiments as a source of H₂ through reaction with water and as a potential catalyst. Experiments with CO or HCOOH as the carbon source resulted in rapid generation of CH₄ and other hydrocarbons that closely resembled typical products of Fischer-Tropsch organic synthesis. In contrast, experiments using CO₂ or CH₄ as the carbon source yielded no detectable hydrocarbon products. Carbon isotope measurements of reaction products from the CO experiments indicate that the CH₄ and other hydrocarbons were substantially depleted in ¹³C, with CH₄ δ¹³C values 30 to 34‰ lighter than the initial CO. Most of the fractionation apparently occurs during attachment of CO to the catalyst surface and subsequent reduction to surface-bound methylene. The initial step in polymerization of these methylene units to form hydrocarbons involves a small, positive fractionation, so that ethane and ethene are slightly enriched in ¹³C relative to CH₄. However, subsequent addition of carbon molecules to the growing hydrocarbon chain proceeds with no net observable fractionation, so that the isotopic compositions of the C₃₊ light hydrocarbons are controlled by isotopic mass balance. This result is consistent with a previously proposed model for carbon isotopic patterns of light hydrocarbons in natural samples. The abundance and isotopic composition of light hydrocarbons produced with HCOOH as the carbon source were similar to those generated with CO, but the isotopic compositions of non-volatile hydrocarbons diverged, suggesting that the higher hydrocarbons were formed by different mechanisms in the CO and HCOOH experiments. The experiments indicate that CO, and possibly HCOOH, may be critical intermediates in the abiotic formation of organic compounds in geologic environments, and suggest that the low levels of these compounds present in most hydrothermal systems could represent a bottleneck restricting the extent of abiotic organic synthesis in some circumstances.     

Carolina Bay geoarchaeology and Holocene landscape evolution on the Upper Coastal Plain of South Carolina

Surface water on the mainly dry, upland interfluves of the Upper Coastal Plain of South Carolina occurs currently as a sporadic distribution of shallow ponds held within Carolina bays and other small, isolated basins. At seven bays on the U.S. Department of Energy's Savannah River Site on the Upper Coastal Plain of South Carolina, we investigated Holocene changes in bay morphology, ecology, and prehistoric human activity. At Flamingo Bay, we employed archaeological survey and testing, shovel and auger testing, sediment analysis, and ground-penetrating radar to document stratigraphy and chronology of the sand rim on the eastern side of the bay. Artifact assemblage indicate changes in intensity of human use of the bay. Radiocarbon dates from a sediment core establish time scales for depositional processes at the center of the basin. Ground-penetrating radar data from the other bays indicate that the stratigraphy of all seven bays is broadly similar. We conclude that: (1) Significant modification of the bays, including rim development and basin infilling, occurred during the Holocene; (2) ponds on the early Holocene landscape were larger and more permanent than at present; (3) early Holocene climate, as indicated by both depositional processes and human activity, was not characterized by prolonged periods of extremely dry conditions; and (4) fluvial-centric models of terminal Pleistocene—early Holocene human adaptations require revision to include intensive use of isolated upland ponds. © 1996 John Wiley & Sons, Inc.