Quantification of TCE Co‐Oxidation in Groundwater Using a 14C–Assay

Bacteria that degrade natural organic matter in groundwater contain oxygenase enzymes that can co‐oxidize trichloroethene (TCE). This degradation pathway is promising for large dilute plumes, but its evaluation is limited because the density of the bacteria with oxygenase enzymes has not been correlated to field scale rates of degradation. A ¹⁴C–TCE assay was developed to determine pseudo first‐order rate constants for the aerobic co‐oxidation of TCE in groundwater. The assay involved incubating ¹⁴C–TCE in samples of groundwater contained in 160 mL serum bottles, and monitoring the accumulation of radiolabel in degradation products. A first‐order rate constant for co‐oxidation was extracted from the rate of accumulation of ¹⁴C in products, accounting for volumetric changes in the serum bottles due to sampling and subsequent changes to the distribution of TCE between the aqueous and gaseous phases. Of the groundwater samples evaluated from 19 wells at five sites, eight samples at three sites had ¹⁴C product accumulation rates that exceeded the accumulation rate in filter‐sterilized groundwater controls. First‐order rate constants ranged from 2.65 to 0.0066 year^?1, which is equivalent to half‐lives of 0.26 to 105 years. Groundwater samples from a few of the wells in which co‐oxidation occurred had volatile organic contaminants in addition to TCE; their presence may have induced the oxygenase enzymes that are needed for TCE co‐oxidation. ¹⁴CO₂ represented ~37% to 97% of the ¹⁴C products that accumulated; the balance of the products was soluble and non‐volatile.     

Efficacy of an In‐Well Sonde to Determine Magnetic Susceptibility of Aquifer Sediment

Magnetite is a natural component of many aquifers. Abiotic degradation of chlorinated solvents by magnetite can be an important mechanism for natural attenuation of these contaminants. The quantity of magnetite in aquifer materials can be estimated by measuring the magnetic susceptibility of the materials. This is most commonly done by determining the magnetic susceptibility of core samples in an analytical laboratory using a magnetic susceptibility meter. Unfortunately, the cost of acquiring core samples often makes an evaluation of abiotic degradation by magnetite economically unrealistic. Downhole sondes (probes) are available for the determination of magnetic susceptibility. In this study, a downhole sonde was evaluated as an affordable alternative to acquiring and analyzing core samples. The sonde was introduced into 10 monitoring wells. The data from the sonde were then compared to data from core samples that were collected from the same elevation as the sonde data. The core samples analyzed in the laboratory were used as the standard against which the sonde data were compared. The downhole sonde reported values that were similar to values reported on core samples. At most wells, the means of the two measurements could not be distinguished at the 95% confidence interval. When the means could be distinguished, they still agreed within a factor of two.     

Soil formation and weathering in a permafrost environment of the Swiss Alps: a multi‐parameter and non‐steady‐state approach

Spatially discontinuous permafrost conditions frequently occur in the European Alps. How soils under such conditions have evolved and how they may react to climate warming is largely unknown. This study focuses on the comparison of nearby soils that are characterised by the presence or absence of permafrost (active‐layer thickness: 2–3 m) in the alpine (tundra) and subalpine (forest) range of the Eastern Swiss Alps using a multi‐method (geochemical and mineralogical) approach. Moreover, a new non‐steady‐state concept was applied to determine rates of chemical weathering, soil erosion, soil formation, soil denudation, and soil production. Long‐term chemical weathering rates, soil formation and erosion rates were assessed by using immobile elements, fine‐earth stocks and meteoric ¹⁰Be. In addition, the weathering index (K + Ca)/Ti, the amount of Fe‐ and Al‐oxyhydroxides and clay minerals characteristics were considered. All methods indicated that the differences between permafrost‐affected and non‐permafrost‐affected soils were small. Furthermore, the soils did not uniformly differ in their weathering behaviour. A tendency towards less intense weathering in soils that were affected by permafrost was noted: at most sites, weathering rates, the proportion of oxyhydroxides and the weathering stage of clay minerals were lower in permafrost soils. In part, erosion rates were higher at the permafrost sites and accounted for 79–97% of the denudation rates. In general, soil formation rates (8.8–86.7 t/km²/yr) were in the expected range for Alpine soils. Independent of permafrost conditions, it seems that the local microenvironment (particularly vegetation and subsequently soil organic matter) has strongly influenced denudation rates. As the climate has varied since the beginning of soil evolution, the conditions for soil formation and weathering were not stable over time. Soil evolution in high Alpine settings is complex owing to, among others, spatio‐temporal variations of permafrost conditions and thus climate. This makes predictions of future behaviour very difficult. Copyright © 2016 John Wiley & Sons, Ltd.     

An event stratigraphy for the Last Termination in the North Atlantic region based on the Greenland ice-core record: a proposal by the INTIMATE group

It is suggested that the GRIP Greenland ice-core should constitute the stratotype for the Last Termination. Based on the oxygen isotope signal in that core, a new event stratigraphy spanning the time interval from ca. 22.0 to 11.5 k GRIP yr BP (ca. 19.0–10.0 k ¹⁴C yr BP) is proposed for the North Atlantic region. This covers the period from the Last Glacial Maximum, through Termination 1 of the deep-ocean record, to the Pleistocene–Holocene boundary, and encompasses the Last Glacial Late-glacial of the traditional northwest European stratigraphy. The isotopic record for this period is divided into two stadial episodes, Greenland Stadials 1 (GS-1) and 2 (GS-2), and two interstadial events, Greenland Interstadials 1 (GI-1) and2 (GI-2). In addition, GI-1 and GS-2 are further subdivided into shorter episodes. The event stratigraphy is equally applicable to ice-core, marine and terrestrial records and is considered to be a more appropriate classificatory scheme than the terrestrially based radiocarbon-dated chronostratigraphy that has been used hitherto. © 1998 John Wiley & Sons, Ltd.     

Prediction of the long-term performance of abandoned lead zinc mine tailings in a Welsh catchment

In this study we investigated the sulphidic mine tailings from Frongoch and Grogwynion, two abandoned lead zinc mines in mid-Wales, UK. Despite falling within the same ore field the mine waste characterisation has identified differences in the tailings from the two sites. Bulk concentrations range from 10 to 52 g kg^− 1 for Pb, 1.1 to 2.9 g kg^− 1 for Zn in Grogwynion and from 1.0 to 130 g kg^− 1 for Pb, 11 to 110 g kg^− 1 for Zn in Frongoch. An experimental (European standard leaching tests TS 14429 and TS 14405) and geochemical modelling approach was used to study the leaching composition as a function of pH and liquid/solid ratio. There was little correlation between the tailings bulk metal concentrations and the leachate composition, but variations in Pb and Zn concentrations were found to be consistent with control of dissolved Pb and Zn by secondary minerals and the mechanisms of dissolution/precipitation/sorption involving them. Specifically, the Grogwynion mine tailings with near-neutral pH have predominantly lead and zinc carbonates controlling Pb and Zn solubility in the leachates, whereas the Pb and Zn concentrations in Frongoch leachates are best modelled with a surface complexation model for metal sorption to oxyhydroxides. The different speciation results in a greater sensitivity of Grogwynion tailings to acidification with a potential release of Pb in solution up to 10 times higher than in Frongoch, despite similar bulk Pb concentrations. At acid pH, Zn is similarly dissolved to a greater extent in Grogwynion than in Frongoch tailings. There was no evidence of sulphide oxidation during the batch and column leaching tests and the suitability of using these European leaching standards for the characterisation of sulphidic mine waste materials for waste management purposes has been considered.     

Determination of the Atmospheric Boundary Layer Height from Radiosonde and Lidar Backscatter

The height of the atmospheric boundary layer is derived with the help of two different measuring systems and methods. From radiosoundings the boundary layer height is determined by the parcel method and by temperature and humidity gradients. From lidar backscatter measurements a combination of the averaging variance method and the high-resolution gradient method is used to determine boundary layer heights. In this paper lidar-derived boundary layer heights on a 10 min basis are presented. Datasets from four experiments – two over land and two over the sea – are used to compare boundary layer heights from both methods. Only the daytime boundary layer is investigated because the height of the nighttime stable boundary layer is below the range of the lidar. In many situations the boundary layer heights from both systems coincide within ±200 m. This corresponds to the standard deviation of lidar-derived 10-min values within a 1-h interval and is due to the time and space variability of the boundary layer height. Deviations appear for certain situations and depend on which radiosonde method is applied. The parcel method fails over land surfaces in the afternoon when the boundary layer stabilizes and over the ocean when the boundary layer is slightly stable. An automatic radiosonde gradient method sometimes fails when multiple layers are present, e.g. a residual layer above the growing convective boundary layer. The lidar method has the advantage of continuous tracing and thus avoids confusion with elevated layers. On the other hand, it mostly fails in situations with boundary layer clouds     

EAF implementation in Southern Africa: Lessons learnt

The practical implementation of an ecosystem approach to fisheries (EAF) management has proved difficult to achieve. Without simple and structured guidelines for implementing an EAF, managers are grappling with the complexity of implementation and the need to prioritise resources and management actions. Ecological risk assessment has been put forward as a structured procedure. There is a need to review regularly whether progress is being made in addressing the issues and priorities identified through ecological risk assessment. Such reviews require a framework providing clear objectives for the respective fishery and delineating the steps required towards their achievement. This paper proposes a generic framework for reviewing ecological risk assessments through stakeholder workshops. This framework is aided by a fuzzy logic tool to track EAF implementation and informs the development of proactive work plans which incorporate EAF objectives. The advantages and disadvantages of a generic and participatory approach are discussed and compared with other related methods for evaluating progress in implementing an EAF.     

Remotely sensed rivers in the Anthropocene: state of the art and prospects

The rivers of the world are undergoing accelerated change in the Anthropocene, and need to be managed at much broader spatial and temporal scales than before. Fluvial remote sensing now offers a technical and methodological framework that can be deployed to monitor the processes at work and to assess the trajectories of rivers in the Anthropocene. In this paper, we review research investigating past, present and future fluvial corridor conditions and processes using remote sensing and we consider emerging challenges facing fluvial and riparian research. We introduce a suite of remote sensing methods designed to diagnose river changes at reach to regional scales. We then focus on identification of channel patterns and acting processes from satellite, airborne or ground acquisitions. These techniques range from grain scales to landform scales, and from real time scales to inter-annual scales. We discuss how remote sensing data can now be coupled to catchment scale models that simulate sediment transfer within connected river networks. We also consider future opportunities in terms of datasets and other resources which are likely to impact river management and monitoring at the global scale. We conclude with a summary of challenges and prospects for remotely sensed rivers in the Anthropocene. © 2019 John Wiley & Sons, Ltd.