Quantification of TCE Co‐Oxidation in Groundwater Using a 14C–Assay

Bacteria that degrade natural organic matter in groundwater contain oxygenase enzymes that can co‐oxidize trichloroethene (TCE). This degradation pathway is promising for large dilute plumes, but its evaluation is limited because the density of the bacteria with oxygenase enzymes has not been correlated to field scale rates of degradation. A ¹⁴C–TCE assay was developed to determine pseudo first‐order rate constants for the aerobic co‐oxidation of TCE in groundwater. The assay involved incubating ¹⁴C–TCE in samples of groundwater contained in 160 mL serum bottles, and monitoring the accumulation of radiolabel in degradation products. A first‐order rate constant for co‐oxidation was extracted from the rate of accumulation of ¹⁴C in products, accounting for volumetric changes in the serum bottles due to sampling and subsequent changes to the distribution of TCE between the aqueous and gaseous phases. Of the groundwater samples evaluated from 19 wells at five sites, eight samples at three sites had ¹⁴C product accumulation rates that exceeded the accumulation rate in filter‐sterilized groundwater controls. First‐order rate constants ranged from 2.65 to 0.0066 year^?1, which is equivalent to half‐lives of 0.26 to 105 years. Groundwater samples from a few of the wells in which co‐oxidation occurred had volatile organic contaminants in addition to TCE; their presence may have induced the oxygenase enzymes that are needed for TCE co‐oxidation. ¹⁴CO₂ represented ~37% to 97% of the ¹⁴C products that accumulated; the balance of the products was soluble and non‐volatile.     

Efficacy of an In‐Well Sonde to Determine Magnetic Susceptibility of Aquifer Sediment

Magnetite is a natural component of many aquifers. Abiotic degradation of chlorinated solvents by magnetite can be an important mechanism for natural attenuation of these contaminants. The quantity of magnetite in aquifer materials can be estimated by measuring the magnetic susceptibility of the materials. This is most commonly done by determining the magnetic susceptibility of core samples in an analytical laboratory using a magnetic susceptibility meter. Unfortunately, the cost of acquiring core samples often makes an evaluation of abiotic degradation by magnetite economically unrealistic. Downhole sondes (probes) are available for the determination of magnetic susceptibility. In this study, a downhole sonde was evaluated as an affordable alternative to acquiring and analyzing core samples. The sonde was introduced into 10 monitoring wells. The data from the sonde were then compared to data from core samples that were collected from the same elevation as the sonde data. The core samples analyzed in the laboratory were used as the standard against which the sonde data were compared. The downhole sonde reported values that were similar to values reported on core samples. At most wells, the means of the two measurements could not be distinguished at the 95% confidence interval. When the means could be distinguished, they still agreed within a factor of two.     

Soil formation and weathering in a permafrost environment of the Swiss Alps: a multi‐parameter and non‐steady‐state approach

Spatially discontinuous permafrost conditions frequently occur in the European Alps. How soils under such conditions have evolved and how they may react to climate warming is largely unknown. This study focuses on the comparison of nearby soils that are characterised by the presence or absence of permafrost (active‐layer thickness: 2–3 m) in the alpine (tundra) and subalpine (forest) range of the Eastern Swiss Alps using a multi‐method (geochemical and mineralogical) approach. Moreover, a new non‐steady‐state concept was applied to determine rates of chemical weathering, soil erosion, soil formation, soil denudation, and soil production. Long‐term chemical weathering rates, soil formation and erosion rates were assessed by using immobile elements, fine‐earth stocks and meteoric ¹⁰Be. In addition, the weathering index (K + Ca)/Ti, the amount of Fe‐ and Al‐oxyhydroxides and clay minerals characteristics were considered. All methods indicated that the differences between permafrost‐affected and non‐permafrost‐affected soils were small. Furthermore, the soils did not uniformly differ in their weathering behaviour. A tendency towards less intense weathering in soils that were affected by permafrost was noted: at most sites, weathering rates, the proportion of oxyhydroxides and the weathering stage of clay minerals were lower in permafrost soils. In part, erosion rates were higher at the permafrost sites and accounted for 79–97% of the denudation rates. In general, soil formation rates (8.8–86.7 t/km²/yr) were in the expected range for Alpine soils. Independent of permafrost conditions, it seems that the local microenvironment (particularly vegetation and subsequently soil organic matter) has strongly influenced denudation rates. As the climate has varied since the beginning of soil evolution, the conditions for soil formation and weathering were not stable over time. Soil evolution in high Alpine settings is complex owing to, among others, spatio‐temporal variations of permafrost conditions and thus climate. This makes predictions of future behaviour very difficult. Copyright © 2016 John Wiley & Sons, Ltd.     

An event stratigraphy for the Last Termination in the North Atlantic region based on the Greenland ice-core record: a proposal by the INTIMATE group

It is suggested that the GRIP Greenland ice-core should constitute the stratotype for the Last Termination. Based on the oxygen isotope signal in that core, a new event stratigraphy spanning the time interval from ca. 22.0 to 11.5 k GRIP yr BP (ca. 19.0–10.0 k ¹⁴C yr BP) is proposed for the North Atlantic region. This covers the period from the Last Glacial Maximum, through Termination 1 of the deep-ocean record, to the Pleistocene–Holocene boundary, and encompasses the Last Glacial Late-glacial of the traditional northwest European stratigraphy. The isotopic record for this period is divided into two stadial episodes, Greenland Stadials 1 (GS-1) and 2 (GS-2), and two interstadial events, Greenland Interstadials 1 (GI-1) and2 (GI-2). In addition, GI-1 and GS-2 are further subdivided into shorter episodes. The event stratigraphy is equally applicable to ice-core, marine and terrestrial records and is considered to be a more appropriate classificatory scheme than the terrestrially based radiocarbon-dated chronostratigraphy that has been used hitherto. © 1998 John Wiley & Sons, Ltd.     

Prediction of the long-term performance of abandoned lead zinc mine tailings in a Welsh catchment

In this study we investigated the sulphidic mine tailings from Frongoch and Grogwynion, two abandoned lead zinc mines in mid-Wales, UK. Despite falling within the same ore field the mine waste characterisation has identified differences in the tailings from the two sites. Bulk concentrations range from 10 to 52 g kg^− 1 for Pb, 1.1 to 2.9 g kg^− 1 for Zn in Grogwynion and from 1.0 to 130 g kg^− 1 for Pb, 11 to 110 g kg^− 1 for Zn in Frongoch. An experimental (European standard leaching tests TS 14429 and TS 14405) and geochemical modelling approach was used to study the leaching composition as a function of pH and liquid/solid ratio. There was little correlation between the tailings bulk metal concentrations and the leachate composition, but variations in Pb and Zn concentrations were found to be consistent with control of dissolved Pb and Zn by secondary minerals and the mechanisms of dissolution/precipitation/sorption involving them. Specifically, the Grogwynion mine tailings with near-neutral pH have predominantly lead and zinc carbonates controlling Pb and Zn solubility in the leachates, whereas the Pb and Zn concentrations in Frongoch leachates are best modelled with a surface complexation model for metal sorption to oxyhydroxides. The different speciation results in a greater sensitivity of Grogwynion tailings to acidification with a potential release of Pb in solution up to 10 times higher than in Frongoch, despite similar bulk Pb concentrations. At acid pH, Zn is similarly dissolved to a greater extent in Grogwynion than in Frongoch tailings. There was no evidence of sulphide oxidation during the batch and column leaching tests and the suitability of using these European leaching standards for the characterisation of sulphidic mine waste materials for waste management purposes has been considered.     

Determination of the Atmospheric Boundary Layer Height from Radiosonde and Lidar Backscatter

The height of the atmospheric boundary layer is derived with the help of two different measuring systems and methods. From radiosoundings the boundary layer height is determined by the parcel method and by temperature and humidity gradients. From lidar backscatter measurements a combination of the averaging variance method and the high-resolution gradient method is used to determine boundary layer heights. In this paper lidar-derived boundary layer heights on a 10 min basis are presented. Datasets from four experiments – two over land and two over the sea – are used to compare boundary layer heights from both methods. Only the daytime boundary layer is investigated because the height of the nighttime stable boundary layer is below the range of the lidar. In many situations the boundary layer heights from both systems coincide within ±200 m. This corresponds to the standard deviation of lidar-derived 10-min values within a 1-h interval and is due to the time and space variability of the boundary layer height. Deviations appear for certain situations and depend on which radiosonde method is applied. The parcel method fails over land surfaces in the afternoon when the boundary layer stabilizes and over the ocean when the boundary layer is slightly stable. An automatic radiosonde gradient method sometimes fails when multiple layers are present, e.g. a residual layer above the growing convective boundary layer. The lidar method has the advantage of continuous tracing and thus avoids confusion with elevated layers. On the other hand, it mostly fails in situations with boundary layer clouds     

Late Eocene–Pliocene basin evolution in the Eastern Cordillera of northwestern Argentina (25°–26°S): regional implications for Andean orogenic wedge development

Important aspects of the Andean foreland basin in Argentina remain poorly constrained, such as the effect of deformation on deposition, in which foreland basin depozones Cenozoic sedimentary units were deposited, how sediment sources and drainages evolved in response to tectonics, and the thickness of sediment accumulation. Zircon U‐Pb geochronological data from Eocene–Pliocene sedimentary strata in the Eastern Cordillera of northwestern Argentina (Pucará–Angastaco and La Viña areas) provide an Eocene (ca. 38 Ma) maximum depositional age for the Quebrada de los Colorados Formation. Sedimentological and provenance data reveal a basin history that is best explained within the context of an evolving foreland basin system affected by inherited palaeotopography. The Quebrada de los Colorados Formation represents deposition in the distal to proximal foredeep depozone. Development of an angular unconformity at ca. 14 Ma and the coarse‐grained, proximal character of the overlying Angastaco Formation (lower to upper Miocene) suggest deposition in a wedge‐top depozone. Axial drainage during deposition of the Palo Pintado Formation (upper Miocene) suggests a fluvial‐lacustrine intramontane setting. By ca. 4 Ma, during deposition of the San Felipe Formation, the Angastaco area had become structurally isolated by the uplift of the Sierra de los Colorados Range to the east. Overall, the Eastern Cordillera sedimentary record is consistent with a continuous foreland basin system that migrated through the region from late Eocene through middle Miocene time. By middle Miocene time, the region lay within the topographically complex wedge‐top depozone, influenced by thick‐skinned deformation and re‐activation of Cretaceous rift structures. The association of the Eocene Quebrada del los Colorados Formation with a foredeep depozone implies that more distal foreland deposits should be represented by pre‐Eocene strata (Santa Barbara Subgroup) within the region.     

Hierarchical star formation in M33: properties of the star-forming regions

Star formation within galaxies occurs on multiple scales, from spiral structure, to OB associations, to individual star clusters, and often as substructure within these clusters. This multitude of scales calls for objective methods to find and classify star-forming regions, regardless of spatial size. To this end, we present an analysis of star-forming groups in the Local Group spiral galaxy M33, based on a new implementation of the Minimum Spanning Tree (MST) method. Unlike previous studies, which limited themselves to a single spatial scale, we study star-forming structures from the effective resolution limit (～20 pc) to kpc scales. Once the groups have been identified, we study their properties, such as their size and luminosity distributions, and compare these with studies of young star clusters and giant molecular clouds (GMCs). We find evidence for a continuum of star-forming group sizes, which extends into the star cluster spatial-scale regime. We do not find a characteristic scale for OB associations, unlike that found in previous studies, and we suggest that the appearance of such a scale was caused by spatial resolution and selection effects. The luminosity function of the groups is found to be well represented by a power law with an index of ?2, as has also been found for the luminosity and mass functions of young star clusters, as well as for the mass function of GMCs. Additionally, the groups follow a similar mass-radius relation as GMCs. The size distribution of the groups is best described by a log-normal distribution, the peak of which is controlled by the spatial scale probed and the minimum number of sources used to define a group. We show that within a hierarchical distribution, if a scale is selected to find structure, the resulting size distribution will have a log-normal distribution. We find an abrupt drop of the number of groups outside a galactic radius of ～4 kpc (although individual high-mass stars are found beyond this limit), suggesting a change in the structure of the star-forming interstellar medium, possibly reflected in the lack of GMCs beyond this radius. Finally, we find that the spatial distribution of H?ii regions, GMCs, and star-forming groups are all highly correlated.     

Stability of inclined orbits of terrestrial planets in habitable zones

In long-term stability studies of terrestrial planets moving in the habitable zone (HZ) of a sun-like star, we distinguish four different configurations: (i) planets moving in binary star systems, (ii) the inner type (where the gas giant moves outside the HZ), (iii) the outer type (where the gas giant is closer to the star, than the HZ) and (iv) the Trojan type (where the gas giant moves in the HZ). Since earlier calculations indicated, that the stability of the motion in the HZ also depends on the inclination of the terrestrial planet orbits, we present a detailed numerical investigation to show correlations between the eccentricity, the mass and the distance of the giant planet for various inclinations of the terrestrial planets. The orbital stability of the HZ was examined for all four configurations stated above. While we could find hardly any stable orbits for the first three types for inclinations higher than 40^°, the Trojan planets can be stable up to an inclination of 60^°. Additionally, we could also find some stabilizing effects of the inclination for the first three types. As dynamical model we used the elliptic restricted three-body problem, which consists of two massive and one mass-less body. This allows an application to all detected and future extrasolar single planet systems.     

The effects of spatially distributed ionisation sources on the temperature structure of H <Emphasis Type="SmallCaps">ii</Emphasis> regions

Spatially resolved studies of star-forming regions show that the assumption of spherical geometry is not realistic in most cases, with a major complication posed by the gas being ionised by multiple non-centrally located stars or star clusters. Geometrical effects including the spatial configuration of ionising sources affect the temperature and ionisation structure of these regions. We try to isolate the effects of multiple non-centrally located stars, via the construction of 3D photoionisation models using the 3D Monte Carlo photoionisation code mocassin with very simple gas density distributions, but various spatial configurations for the ionisation sources.Emission-line spectra from H?ii regions are often used to study the metallicity of star-forming regions, as well as for providing a constraint on temperatures and luminosities of the ionising sources. Empirical metallicity diagnostics must often be calibrated with the aid of photoionisation models. However, most studies so far have been carried out by assuming spherical or plane-parallel geometries, with major limitations on the allowed gas and dust density distributions and with the spatial distribution of multiple, non-centrally located ionising sources not being accounted for. We compare integrated emission-line spectra from our models and quantify any systematic errors caused by the simplifying assumption of a single, central location for all ionising sources. We find that the dependence of the metallicity indicators on the ionisation parameter causes a clear bias, due to the fact that models with a fully distributed configuration of stars always display lower ionisation parameters than their fully concentrated counterparts. The errors found imply that the geometrical distribution of ionisation sources may partly account for the large scatter in metallicities derived using model-calibrated empirical methods.