Sources of mud volcano fluids in the Gulf of Cadiz—indications for hydrothermal imprint

Mud volcanism in the Gulf of Cadiz occurs over a large area extending from the shelf to more than 3500 m water depth and is triggered by compressional stress along the European-African plate boundary, affecting a deeply faulted sedimentary sequence of locally more than 5 km thickness. The investigation of six active sites shows that mud volcano (MV) fluids, on average, are highly enriched in CH₄, Li, B, and Sr and depleted in Mg, K, and Br. The purity of the fluids is largely controlled by the intensity of upward directed flow. Flow rates could be constrained by numerical modelling and vary between <0.05 and 15 cm yr⁻¹. Application of δD-δ¹⁸O systematics identifies clay mineral dehydration, most likely within Mesozoic and Tertiary shales and marls, as the major source of fluids. Hence, Cl and Na in the pore fluids are mostly depleted below seawater values, following a general trend of dilution. However, deviations from this trend occur and are likely caused by the dissolution of halite in evaporitic deposits. Other secondary processes overprinting the original fluid composition may occur along the flow path, such as dissolution of anhydrite or gypsum and/or the formation of calcite and dolomite. Different sources of fluids are also indicated by variations in ⁸⁷Sr/⁸⁶Sr, which range from 0.7086 to 0.7099 at the different sites. Dehydration may be induced primarily by overburden and tectonic compression; however, very high concentrations of Li and B, specifically at Captain Arutyunov MV (CAMV) indicate additional leaching at temperatures above 150 °C, which could be explained by the injection of hot fluids along deep penetrating, major E-W strike-slip fault systems. This hypothesis is supported by the occurrence of generally thermogenic, but significantly CH₄-enriched, light volatile hydrocarbon gases at CAMV which cannot be explained by shallow microbial methanogenesis. Li and Li/B ratios from different types of hot and cold vents are used to infer that high temperature signals seem to be preserved at various cold vent locations and indicate a closer coupling of both systems in continental margin environments than outlined in previous studies.     

Abiotic formation of hydrocarbons under hydrothermal conditions: Constraints from chemical and isotope data

To understand reaction pathways and isotope systematics during mineral-catalyzed abiotic synthesis of hydrocarbons under hydrothermal conditions, experiments involving magnetite and CO₂ and H₂-bearing aqueous fluids were conducted at 400 °C and 500 bars. A robust technique for sample storage and transfer from experimental apparatus to stable isotope mass spectrometer provides a methodology for integration of both carbon and hydrogen isotope characterization of reactants and products generated during abiogenic synthesis experiments. Experiments were performed with and without pretreatment of magnetite to remove background carbon associated with the mineral catalyst. Prior to experiments, the abundance and carbon isotope composition of all carbon-bearing components were determined. Time-series samples of the fluid from all experiments indicated significant concentrations of dissolved CO and C₁-C₃ hydrocarbons and relatively large changes in dissolved CO₂ and H₂ concentrations, consistent with formation of additional hydrocarbon components beyond C₃. The existence of relatively high dissolved alkanes in the experiment involving non-pretreated magnetite in particular, suggests a complex catalytic process, likely involving reinforcing effects of mineral-derived carbon with newly synthesized hydrocarbons at the magnetite surface. Similar reactions may be important mechanisms for carbon reduction in chemically complex natural hydrothermal systems. In spite of evidence supporting abiotic hydrocarbon formation in all experiments, an “isotopic reversal” trend was not observed for ¹³C values of dissolved alkanes with increasing carbon number. This may relate to the specific mechanism of carbon reduction and hydrocarbon chain growth under hydrothermal conditions at elevated temperatures and pressures. Over time, significant ¹³C depletion in CH₄ suggests either depolymerization reactions occurring in addition to synthesis, or reactions between the C₁-C₃ hydrocarbons and carbon species absorbed on mineral surfaces and in solution.     

Climate, water management, and policy in the San Pedro Basin: results of a survey of Mexican stakeholders near the U.S.–Mexico border

This paper reviews regional climate knowledge and vulnerability in the northern Mexico San Pedro River Basin, with a focus on water quality, quantity, and management issues on the Mexican side of the border. A discussion based on the available literature is supplemented by a survey assessing concerns about water and the quality and usability of climate and hydrologic information available to water managers and communities. The surveys indicate that the central concern for urban residents is the lack of reliable potable water due to frequent service breakdowns–with climate change and variability, specifically drought and high temperatures, as contributing factors. Water managers desire appropriate meteorological and hydrologic information to improve planning strategies, but access to this information remains limited. Considerable disagreement exists about who should pay for previously free or low-cost water and wastewater treatment. Urban users have little incentive to conserve because of the present flat, low rate and frustration with service. In rural areas, while a majority of ranchers recognize that variable climate and water loss could increasingly jeopardize their lifestyle, they seldom use meteorological information in planning or modify their water consumption. Climate vulnerability also includes potential for serious environmental health issues due to the presence of heavy metals and organic contaminants in the San Pedro.     

Permian high-temperature metamorphism in the Western Alps (NW Italy)

International Journal of Earth Sciences - During the late Palaeozoic, lithospheric thinning in part of the Alpine realm caused high-temperature low-to-medium pressure metamorphism and partial...     

Multi-Century Record of Anthropogenic Impacts on an Urbanized Mesotidal Estuary: Salem Sound,MA

Salem, MA, located north of Boston, has a rich, well-documented history dating back to settlement in 1626 ce, but the associated anthropogenic impacts on Salem Sound are poorly constrained. This project utilized dated sediment cores from the sound to assess the proxy record of anthropogenic alterations to the system and compared the proxy records to the known history. Proxies included bulk stable isotopes of organic matter, magnetic susceptibility, and trace metal concentrations. Our data reveal clear changes in organic matter composition and concentration associated with land use changes and twentieth century sewage disposal practices. Further, metal data correspond with local industrial activity, particularly the historic tanning industry in Peabody, MA. Although conservation practices of past decades have improved the state of Salem Sound, the stratigraphic record demonstrates that the environment is still affected by anthropogenic influences, and has not attained conditions consistent with pre-anthropogenic baseline. The approach and results of this study are applicable to coastal embayments that are being assessed for remediation, especially those with scant historic or monitoring data.     

Application of turning bands technique to simulate values of copper ore deposit parameters in Rudna mine (Lubin-Sieroszowice region in SW part of Poland)

ABSTRACT

The turning bands simulation is a valuable and highly useful tool in solving various geological-mining, environmental and geological-engineering problems when it is essential to determine the uncertainty of the estimates of simulated values Z_s (realizations) and assess the risk. This paper presents an investigative methodology and the results of calculations connected with the use of conditional turning bands simulation and bundled indicator kriging, making it possible to analyse the risk at different levels of uncertainty in the solution of optimization of the exploitation problems encountered in the mining of the polymetallic copper ore deposits in the Lubin-Sieroszowice region (Foresudetic monocline, the SW part of Poland). Examples of the evaluation of simulated values Z_s and probability P average values Z* of the deposit parameters within the block located in the Rudna Mine (the block R-3) area are provided.     

Treating risk as relational on shore platforms and implications for public safety on microtidal rocky coasts

Natural Hazards - Drowning on rocky coasts is a problem with global significance, but it is a particularly acute issue in Australia where rocky coasts account for 19% of coastal drownings. The risk...     

Letšeng diamond mine,Lesotho: a variant of Kimberley-type pyroclastic kimberlite emplacement

The Letšeng Diamond Mine comprises two ~91 Ma kimberlite pipes. An update of the geology is presented based on the 2012–2017 detailed investigation of open pit exposures and all available drillcores which included mapping, logging and petrography. Each of the steep-sided volcanic pipes comprises a number of phases of kimberlite with contrasting diamond contents which were formed by the emplacement of at least four batches of mantle-derived magma. The resulting range of textures includes resedimented volcaniclastic kimberlite (RVK), Kimberley-type pyroclastic kimberlite (KPK), coherent kimberlite (CK) and minor amounts of hypabyssal kimberlite (HK). The pipes are compared with KPK occurrences from southern Africa and worldwide. Many features of the Letšeng pipes are similar to KPK infilled pipes particularly those of the widespread Cretaceous kimberlite province of southern Africa. The differences displayed at Letšeng compared to other large KPK pipe infills described from around the world are attributed to the marginal or melnoitic nature of the magma and the upper diatreme to crater setting of the Letšeng pipes, where processes become extrusive. It is concluded that the pipes comprise a variant of Kimberley-type pyroclastic kimberlite emplacement. The classification of many of the Letšeng rocks as KPK is important for developing the internal geology of the pipes as well as for predicting the distribution of diamonds within the bodies.