Benthic diatoms of an Alpine stream/lake network in Switzerland

We compared the benthic diatom composition of lakes, and lake inlet and outlet streams in a high elevation catchment (∼2600 m a.s.l.) in the Swiss Alps. The catchment consisted of a southern basin mostly fed by glacial-melt water and a northern basin fed by snowmelt and groundwater. Streams in both basins flowed through a series of small lakes before converging into a lake with a primary outlet channel. The south basin had on average 4°C cooler water temperatures and 2× higher nitrate-N levels (up to 300 μg/L) than the north basin. In contrast, the north basin had higher levels (2–4×) of particulate-P, particulate-N, and particulate organic matter than the south basin. A total of 109 and 143 diatom species was identified in lakes and streams, respectively, with a similar number of species found in each basin. Aulacoseira alpigena and Achnanthidium minutissimum were common benthic algae in north basin lakes, whereas Achnanthes subatomoides, Achnanthes marginulata, Pinnularia microstauron, and Psammothidium helveticum were most common in south basin lakes. One disconnected lake in the north basin had an assemblage dominated by Tabellaria flocculosa (66%) and Eunotia tenella (14%). Principal components analysis showed a clear separation between the north and south basins in lotic diatoms. Of the 10 most common species, streams in the south basin had greater abundances of Psammothidium helveticum, Achnanthes helvetica var. minor, Achnanthes marginulata, Achnanthes subatomoides, and Diatoma mesodon than the north basin, whereas north basin streams had higher abundances of Achnanthidium minutissimum, Aulacoseira alpigena, and Luticola goeppertiana. Lake outlet assemblages were similar to respective downstream lake inlet assemblages, and assemblages changed in composition along each basins longitudinal flow path. However, Aulacoseira alpigena had higher average abundances in north basin outlets than inlets, and Achnanthidium minutissimum, Psammothidium helveticum, and Achnanthes helvetica var. minor had higher average abundances in south basin outlets than inlets. In contrast, Diatoma mesodon, Fragilaria capucina, and Gomphonema parvulum had higher average abundances in south basin inlets than outlets. The spatial patterns in species composition reflected the hierarchical interaction of landscape features (geology, hydrology) on longitudinal gradients (lake position) in the stream/lake network.     

UV-Vis spectrophotometric and XAFS studies of ferric chloride complexes in hyper-saline LiCl solutions at 25-90 °C

The speciation and thermodynamic properties of ferric chloride complexes in hydrothermal solutions and hypersaline brines are still poorly understood, despite the importance of this element as a micronutrient and ore-component. Available experimental data are limited to room temperature and relatively low chloride concentrations. This paper reports results of UV-Vis spectrophotometric and synchrotron XAFS experiments of ferric chloride complexes in chloride concentrations up to 15 m and at temperatures of 25-90 °C. Qualitative interpretation of the UV-Vis spectra shows that FeCl²⁺, FeCl₂⁺, FeCl_3(aq) and FeCl₄⁻ were present in the experimental solutions. As chloride concentrations increase, higher ligand number complexes become important with FeCl₄⁻ predominating in solutions containing more than 10 m at 25 °C. The predominance fields of FeCl_3(aq) and FeCl₄⁻ expand to lower Cl concentrations with increasing T. Both XANES and UV-Vis spectra reveal a major change in the geometry of the complex between FeCl₂⁺ and FeCl_3(aq). EXAFS data confirm that the number of chloride ligands increases with increasing chloride concentration and show that Fe³⁺, FeCl²⁺ and FeCl₂⁺ share an octahedral geometry. FeCl_3(aq) could be either tetrahedral or trigonal dipyramidal, while FeCl₄⁻ is expected to be tetrahedral. EXAFS data support a tetrahedral geometry for FeCl₄⁻, especially at 90 °C, but do not allow to distinguish between a tetrahedral or trigonal dipyramidal geometry for FeCl_3(aq) because of similar Fe-Cl distances. At room temperature, EXAFS data suggest that FeCl_3(aq) may be a mixture of octahedral and tetrahedral or trigonal dipyramidal forms.The room temperature formation constants for three ferric chloride complexes (FeCl₂⁺, FeCl_3(aq) and FeCl₄⁻) determined from the UV data are generally in good agreement with previous studies. Calculations based on the properties extrapolated to 300 °C show that hematite solubility is much higher than previously estimated, and that the high orders complexes FeCl_3(aq) and FeCl₄⁻ are important at high temperatures even in solutions with low chloride concentrations. The accuracy of these properties is limited by a poor understanding of activity-composition relationships in concentrated electrolytes, and by limitations in the available experimental techniques and extrapolation algorithms; however, the inclusion of higher order complexes in numerical models of ore transport and deposition allows for a more accurate qualitative prediction of Fe behaviour in hydrothermal and hypersaline systems.     

Refining P nuclear magnetic resonance spectroscopy for marine particulate samples: Storage conditions and extraction recovery

Solution ³¹P nuclear magnetic resonance (NMR) spectroscopy has recently been used to characterize phosphorus species within marine particles. However, the effects of sample collection, storage and preparation have not been thoroughly examined. In this study, samples of settling particulates collected from a 1200-m sediment trap located in Monterey Bay, California, were subjected to various storage options (i.e., no storage, refrigeration, freezing, and oven-drying and grinding) prior to extraction for solution ³¹P-NMR spectroscopy. Freezing, refrigerating and drying samples for periods of up to 6 months prior to extraction with 0.25 M NaOH + 0.05 M Na₂EDTA increased the concentration of extracted P by an average of 16% relative to samples extracted without storage. Pre-extraction storage also introduced some minor changes in P speciation, by increasing the percentage of orthophosphate by up to 15% and decreasing the percentage of pyrophosphate by up to 5%, relative to the abundances of these P species in samples extracted without storage. Drying caused the biggest changes in speciation, specifically decreasing more extensively the relative percentage of pyrophosphate compared to other treatments. Nevertheless, observed changes in speciation due to sample storage within a specific sample were small relative to differences observed among samples collected sequentially in the same area, or reported differences among samples collected at different locations. Samples were also analyzed by solid-state ³¹P-NMR spectroscopy before and after extraction, to examine extraction-related changes in P speciation. Comparison of solution with solid-state ³¹P NMR indicates that extraction with NaOH–EDTA removes the majority of organic esters, but only a variable portion of phosphonates (39–67%). In addition, there was preferential extraction of Ca-associated phosphate over Mg-, Fe- and Al-associated phosphate. Solution ³¹P NMR enables much higher resolution of P species within samples, particularly when it is important to speciate orthophosphate monoesters and diesters, or if polyphosphates are present. However, combining solid-state ³¹P NMR with solution ³¹P NMR spectroscopy for marine particles should be conducted when examining inorganic P speciation and the abundance of phosphonates.     

Numerical modelling of the morphological response induced by low-crested structures in Lido di Dante,Italy

This paper analyses the morphological response induced by low-crested structures on the adjacent seabed, with particular interest in the erosion patterns that frequently develop at gaps and roundheads. The mechanisms responsible for erosion processes are examined by means of morphodynamic simulations with the numerical suite MIKE 21 CAMS developed by DHI Water & Environment. The main purpose of the paper is to verify how and how far a commercial code can predict bed evolution, in vicinity of defence structures in a real case, in order to get information that may be very useful for structure design and possible maintenance of existing works. The code is applied to a long-term simulation on a study site that is characterized by a composite intervention and suffers from severe erosion, Lido di Dante (Italy). The simulation covers the period (one year and a half) between two available multi-beam surveys, in order to have a detailed real bathymetry as starting point and another one, as accurate as the first, to compare numerical with surveyed results. All the other input data for the model, as waves, tide, wind and sediment characteristics, are derived from measurements in the area; moreover, the code is calibrated using wave and current data acquired during a field campaign. The bed evolution derived from simulations shows a good agreement with the survey both in the locations and in the intensity of erosive and depositional areas. A sensitivity analysis of results to some selected modelling parameters is performed on a shorter simulation period (one month), showing that accounting for bed slope in sediment transport modelling has greater effects in bathymetry evolution than the use of a complex sediment bathymetry or the representation of wave diffraction.     

Mesoscale raised rim depressions (MRRDs) on Earth: A review of the characteristics,processes, and spatial distributions of analogs for Mars

Fields of mesoscale raised rim depressions (MRRDs) of various origins are found on Earth and Mars. Examples include rootless cones, mud volcanoes, collapsed pingos, rimmed kettle holes, and basaltic ring structures. Correct identification of MRRDs on Mars is valuable because different MRRD types have different geologic and/or climatic implications and are often associated with volcanism and/or water, which may provide locales for biotic or prebiotic activity. In order to facilitate correct identification of fields of MRRDs on Mars and their implications, this work provides a review of common terrestrial MRRD types that occur in fields. In this review, MRRDs by formation mechanism, including hydrovolcanic (phreatomagmatic cones, basaltic ring structures), sedimentological (mud volcanoes), and ice-related (pingos, volatile ice-block forms) mechanisms. For each broad mechanism, we present a comparative synopsis of (i) morphology and observations, (ii) physical formation processes, and (iii) published hypothesized locations on Mars. Because the morphology for MRRDs may be ambiguous, an additional tool is provided for distinguishing fields of MRRDs by origin on Mars, namely, spatial distribution analyses for MRRDs within fields on Earth. We find that MRRDs have both distinguishing and similar characteristics, and observation that applies both to their mesoscale morphology and to their spatial distribution statistics. Thus, this review provides tools for distinguishing between various MRRDs, while highlighting the utility of the multiple working hypotheses approach.     

Sub-bottom profiling and coring of sub-basins along the lower French River, Ontario: insights into depositional environments within the North Bay outlet

Sub-bottom profiling was conducted at eight sub-basins within the lower French River area, Ontario, to investigate deposits preserved within the ancient North Bay outlet. Ten cores were collected that targeted the four depositional acoustic facies identified in the sub-bottom profiling records. The rhythmically laminated/bedded glaciolacustrine deposits of facies I are interpreted to have aggraded within glacial Lake Algonquin and its associated recessional lakes that persisted between 13,000 and 11,300 cal BP (~11,100 and 9,900 BP). The majority of the facies II, III and IV lacustrine deposits accumulated between about 9,500 cal BP (~8,500 BP) and the mid-Holocene, based on radiocarbon-dated organic materials. These deposits represent sedimentation within a ‘large’ lake during the late portion of the Mattawa-Stanley phase, and the Nipissing transgression, Nipissing Great Lakes and post-Nipissing recession phases of lake levels. Two sets of organic-rich sand beds are preserved within facies II deposits and reveal that the large lake lacustrine depositional environment was interrupted during the late Mattawa-Stanley phase between 9,500–9,300 and 9,000–8,400 cal BP (~8,500–8,300 and ~8,000–7,600 BP), when the water surface of Lake Hough fell below the outlet threshold and the lake basin became hydrologically closed. Pre-9,500 cal BP (~8,500 BP), the early and middle portions of the Mattawa-Stanley phase were dominated by erosion, as reflected by an unconformity at the base of facies II that occurs widely in the sub-basins and the general lack of preserved deposits for these intervals in the cores. This erosion is attributed to wave action and fluvial scouring within the outlet mouth during the early and mid-Stanley-Hough low stages and relates specifically to the period when the flowing portion of the North Bay outlet was situated over the lower French River area. This study reveals that the majority of the post-glacial deposits accumulated after the outlet threshold had shifted permanently eastwards and the lower French River area was inundated under the multiple phases of the large lake occupying the Nipissing Lowlands and Georgian-Huron basins, extending well into the mid-Holocene. The occurrence of deposits marking two closed-basin intervals during the late Stanley-Hough stage are well preserved locally within the lacustrine depositional sequence, but identifying earlier closed-basin intervals from the French River stratigraphy is hindered by the lack of preserved pre-9,500 cal BP (~8,500 BP) post-glacial deposits.     

Contending with unequal and privileged access to natural resources and land in the Okavango Delta, Botswana

This paper reviews how state policy and regulatory instruments, including protected area alienations and concessions, have altered or denied the access to land and natural livelihood resources of the indigenous Basarwa and minority subsistence-oriented communities in the Okavango Delta (OD) in Botswana. Drawing on field research and guided by a sustainable rural livelihoods framework, the paper provides an overview of key institutional interventions – in particular the setting up of the Moremi Game Reserve, Wildlife Conservation Policy, Tourism Policy, Agricultural Development Policy and the erection of veterinary fences – that have served to privilege a foreign-owned and dominated commercialized wildlife and nature tourism sector and the export-oriented beef industry in the OD. The officially sanctioned barriers to customary and usufructory rights and access, and the non-recognition of historically embedded traditional land uses have decimated already marginalized resource-based subsistence livelihoods, and precipitated intergroup conflicts over preferential rights and access to resources and opportunities, notably wildlife, non-timber veld products, agriculture and community-based tourism schemes. Such outcomes, moreover, will have consequences for the longer-term sustainability of the OD both as a socioeconomic resource base and as a natural ecosystem.     

The Romanian earthquake of August 30, 1986: A study based on GEOSCOPE very long-period and broadband data

The Romanian earthquake of August 30, 1986 is the second largest intermediate depth event in this area since the worldwide deployment of digital instrumentation, and the first one since the installation of GEOSCOPE network. It offers the unique opportunity to document this well-known but poorly understood zone of deep continental seismicity using high quality teleseismic data in different frequency bands. The source is well constrained both from very-long period surface wave data observed on GEOSCOPE stations and, independently, from body wave modelling at various worldwide stations. The depth obtained is approximately 140 kilometers, the seismic moment, 0.8 10²⁷ dyne-cm and the mechanism from both data sets is very similar to that of the previous 1940 and 1977 Vancrea events, indicating that these events, although having occurred at noticeably different depths, are expressions of the same tectonic process. However, from the detailed study of the source using broadband data, it can be inferred that the source presents much less complexity than the 1977 event.     

Interactions between European agricultural policy and climate change: a Slovenian case study

This article analyses the interactions between agricultural policy measures in the EU and the factors affecting GHG emissions from agriculture on the one hand, and the adaptation of agriculture to climate change on the other. To this end, the article uses Slovenia as a case study, assessing the extent to which Slovenian agricultural policy is responding to the challenges of climate change. All agricultural policy measures related to the 2007–2013 programming period were analysed according to a new methodological approach that is based on a qualitative (expert evaluation) and a quantitative (budgetary transfers validation) assessment. A panel of experts reached consensus on the key factors through which individual measures affect climate change, in which direction and how significantly. Data on budgetary funds for each measure were used as weights to assess their relative importance. The results show that there are not many measures in (Slovenian) agricultural policy that are directly aimed at reducing GHG emissions from agriculture or at adaptation to climate change. Nevertheless, most affect climate change, and their impact is far from negligible. Current measures have both positive and negative impacts, but overall the positive impacts prevail. Measures that involve many beneficiaries and more budgetary funds had the strongest impact on aggregate assessments. In light of climate change, agricultural policy should pay more attention to measures that are aimed at raising the efficiency of animal production, as it is the principal source of GHG emissions from agriculture.

Policy relevance

Agricultural policy must respond to climate challenges and climate change impact assessment must be included in the process of forming European agricultural policy. Agricultural policy measures that contribute to the reduction of emissions and adaptation, whilst acting in synergy with other environmental, economic and social goals, should be promoted. The approach used in this study combines qualitative and quantitative data, yielding an objective assessment of the climate impact of agricultural policy measures and providing policy makers with a tool for either ex ante or ex post evaluations of climate-relevant policy measures.     

The oxidation state of manganese in marine sediments and ferromanganese nodules

Marine sediments and ferromanganese nodules from the Pacific Ocean have been analyzed for the $\text{O}\text{Mn}$ ratio of solid manganese. We tested six chemical methods and concluded that the iodometric and oxalate methods were equivalent and were the best choice in terms of accuracy and precision on natural samples. We choose the iodometric method for most of our analyses because the oxalate procedure is a method of differences.The ferromanganese nodules that we analyzed were all from MANOP site H and had $\text{Mn}\text{Fe}$ ratios that ranged from 5.6 to 70. These nodules were invariably highly oxidized with $\text{O}\text{Mn}$ values ranging from 1.90 to 2.00. Our most precise analyses suggest that less than 1% of the total manganese is present as Mn(II).We also analyzed red clay and hemipelagic sediments from the eastern tropical Pacific (Baja borderland and MANOP site H) and carbonate ooze samples from the equatorial Pacific. These sediments are also highly oxidized ($\text{O}\text{Mn}\text{= 1.90 to 2.00}$) except when Mn(II) appears in the interstitial water. As dissolved Mn(II) increases the value of the $\text{O}\text{Mn}$ ratio in the solid phase decreases. The $\text{O}\text{Mn}$ ratio decreases to values as low as 1.40. This decrease appears to be due to a decrease in oxidized manganese by reduction, however, an increase in reduced manganese in the solid sediments by adsorption or MnCO₃ formation can not be ruled out in all cases.