β-环糊精包合态三氟氯氰杀虫剂的制备

为了进一步提高三氟氯氰菊酯农药的防治效果。寻找适宜的农药新剂型，我们用液相法制备了三氟氯氰菊酯－β－环糊精包合物，并以水为基质进行了稳定性观察，同时又以差热分析法和气相色谱法确认了包合物的形成，以旋光度法证明两者间的包合比。结果表明，三氟氯氰菊酯与β-环糊精可形成1：1型包合物，该包合物稳定性高，具有一定的水溶性，而且在水中稳定，所以有望通过环糊 包合作用将三氟氯氰菊酯帛成水剂；当以气相法测试包合态三氟氯氰菊酯含量时，必须将其解络，使之成为游离状态，然后按常规方法进行含量测定。     

松辽盆地后五家户气田沉积相特征与控气作用

本文对松辽盆地东南部后五家户气田划分出22种沉积微相,建立7种相层序,分析了扇三角洲及三角洲沉积环境对天然气成藏的控制作用。指出了扇三角洲前缘砂体和三角洲前缘砂体较为发育,沉积物源来自气田东北部和东南部两个方向。后五家户气田多为构造—岩性气藏和岩性气藏。     

南海西部围区中特提斯东延通道问题

通过对南海西部围区中生代岩相古地理资料的收集整理和分析,编制了该区T_2,T_3~1,T_3~2,T_3~3,J_1-J_2,J_3-K_1共6个时段的岩相古地理简图,根据其中生代海相地层的时空分布和岩相特征,讨论了尚存争议的中特提斯进入南海的通道问题。实际资料表明,黑水河盆地在三叠纪受印支运动影响完成了从海到陆的过程,之后不再出现海相沉积,中特提斯不可能从红河裂谷带进入南海。在新加坡所见的晚三叠世至早侏罗世浅海至陆相沉积代表古特提斯的残余海,到中侏罗世完全消失。早侏罗世时期在印支半岛南部出现的近南北走向的海湾可能经过泰国湾与当时的滇缅海相通;但是这个海湾浅而短暂,滇缅海能否从这里进入南海值得怀疑,更不可能是中特提斯的通道。在南海西部围区,迄今已证实的中生代洋壳碎片(蛇绿岩套)和深海沉积仅见于南部Woyla—Maratus—Lupar一线及其附近。这套延伸2000余km,从洋壳、深海到浅海岩相齐全的岩石所代表的晚侏罗世至早白垩纪世大洋应是中特提斯洋的一部分。中特提斯东延而最可能是走南路,即从班公一怒江带南下之后,经Woyla线穿过苏门答腊岛,绕加里曼丹岛南缘到Maratus线,向北再经沙巴到Lupar线,在沙捞越北部或纳土纳岛附近进入南海。     

Discussion on the feature of strong earthquake: Orderly distribution in time, space and intensity before the Western Kunlun Mountain Pass M=8.1 earthquake

Introduction The Western Kunlun Mountain Pass M=8.1 earthquake occurred on November 14, 2001 is the other M=8 earthquake occurred 50 years after Dangxiong, Tibet M=8.0 earthquake in Chinese mainland. The earthquake has caused the attention of the seismologists in the following aspects: 1) The fracture length is more than 400 km, which is far away from the estimated length by the statistic empirical function between the magnitude and the fracture length (WANG, et al, 2002); 2) The aftersh…     

盆地岩石圈结构与油气成藏及分布

本文综述了大陆岩石圈研究现状和克拉通盆地、裂谷盆地和前陆盆地的岩石圈结构特征,指出在古裂谷、褶皱带或区域性深断裂等陆壳构造薄弱带上发育起来的多期叠合盆地,具有很好的含油气前景。大型含油气盆地往往存在地幔上隆、地壳减薄和地壳内低速层,盆地基底沉降与盖层沉积厚度较大。适度的后期构造活动改造和岩浆活动有利于沉积盆地内油气生成与保存。     

Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.     

铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究

在０３０ｍｏｌ／ＬＨＡｃ介质中，Ｐｂ（Ⅱ）与７＿碘＿８＿羟基喹啉＿５＿磺酸（试铁灵，Ｆｅｒｏｎ）的络合物于－０５４Ｖ（ｖｓ．ＳＣＥ）产生一尖锐的极谱波，加入溴化十六烷基三甲基铵（ＣＴＭＡＢ）显著增敏，可使极谱波增高约４倍。峰电流与Ｐｂ（Ⅱ）浓度在９６×１０－９～４８×１０－６ｍｏｌ／Ｌ呈良好的线性关系，检出限为４８×１０－９ｍｏｌ／Ｌ。用多种电化学方法研究了该极谱波的性质及电极反应机理表明，络合物组成比为ｎＰｂ（Ⅱ）∶ｎＦｅｒｏｎ＝１∶１，极谱波为吸附波，峰电流由中心离子Ｐｂ（Ⅱ）还原产生，电子转移数为２。试验了多种离子对峰电流的影响，拟定的方法用于矿样分析，结果与原结果相符。     

An estimate of hypocentre location accuracy in a large network: possible implications for tectonic studies in Italy

Data recorded by the Italian Telemetered Seismic Network (ITSN) of the Istituto Nazionale di Geofisica (ING) have been widely used in recent years to image slab structures and to find evidence for active processes along the Italian Peninsula. However, the use of seismic data for geostructural purposes may be affected by the well-known trade-off between earthquake location and seismic-velocity parameters. Furthermore, the confidence ellipse predicted by standard procedures may be inadequate for the representation of the probable error of a computed localization. This paper evaluates the probable errors on the hypocentre determinations of the seismic events recorded by the ITSN, using a Monte Carlo method.
We compute synthetic arrival times using a 1-D velocity model appropriate as an average for the Italian area. The hypocentres used are all those recorded by the ITSN during the period January 1992 to March 1994 (1972 events). Station locations are those of the current ITSN configuration. The synthetic arrival times are perturbed with a Gaussian distribution of errors and input to ING's standard hypocentral location procedure, but using crustal velocities differing by 10 per cent from those used to generate them. Each simulation is repeated at least 30 times. Average absolute shifts of hypocentres are assessed in grid cells of linear dimension 33 km covering the whole Italian region.
For regions within the ITSN, shifts are typically 5–10 km in location and up to 20 km in depth. However, for offshore and coastal regions, they are much greater: 50 km or more in both location and depth (far exceeding the equivalent uncertainties quoted by ING bulletins). Possible consequences of this are highlighted by producing a cross-section of subcrustal hypocentres from the Adriatic to the Tyrrhenian Sea, where the large uncertainty in depth precludes any confident interpretation of dipping tectonic features.