Using spatial statistics to identify the uranium hotspot in groundwater in the mid-eastern Gangetic plain,India

The occurrence of uranium in groundwater is of particular interest due to its toxicological and radiological properties. It has been considered as a relevant contaminant for drinking water even at a low concentration. Uranium is a ubiquitously occurring radionuclide in the environment. Four hundred and fifty-six (456) groundwater samples from different locations of five districts of South Bihar (SB) were collected and concentrations of uranium (U) were analyzed using a light-emitting diode (LED) fluorimetric technique. Uranium concentrations in groundwater samples varied from 0.1 µg l^?1 to 238.2 µg l^?1 with an average value of 12.3 µg l^?1 in five districts of Bihar in the mid-eastern Gangetic plain. This study used hot spot spatial statistics to identify the distribution of elevated uranium concentration in groundwater. The hypothesis whether spatial distribution of high value and low value of U is more likely spatially clustered due to random process near a uranium hotspot in groundwater was tested based on z score and Getis-Ord Gi* statistics. The method implemented in this study, can be utilized in the field of risk assessment and decision making to locate potential areas of contamination.     

Magnetotelluric impedance tensor analysis for identification of transverse tectonic feature in the Wagad uplift,Kachchh, northwest India

The 2001 Bhuj earthquake (Mw 7.7) occurred in northwestern region of Indian peninsula has reactivated a couple of transverse faults to its surroundings. Intermediate to moderate magnitude earthquakes are occurring along these faults which includes recent Dholavira earthquake (Mw 5.1, 2012) suggesting distinct tectonic scenario in the region. We present the results of magnetotelluric (MT) impedance tensors analyses of 18 sites located along a profile cutting various faults in the uplifted Wagad block of the Kachchh basin. The MT time series of 4–5 days recording duration have been processed and the earth response functions are estimated in broad frequency range (0.01–1000 s). The observed impedance tensors are analyzed by using three decomposition techniques as well as by the phase tensor method constraining with the induction arrows. The analyses suggest distinct tectonic feature within the block bounded by the South Wagad Fault (SWF) and the North Wagad Fault (NWF) particularly in the period band of 1–10 s. In the south of NWF, the telluric vectors and the major axes of the phase ellipses are aligned in the NNW–SSE to NW–SE direction where as a dominant E–W strike is obtained for northern side of the NWF. The transverse geo-electric strike coincides with the prominent clustering of seismicity after the Bhuj earthquake and trend of the Manfara transverse fault is located in close vicinity of the study area. We therefore suggest the presence NNW–SSE trending transverse structural feature in the Wagad uplift of the basin appears to play significant role in the current seismicity of the active intraplate region.     

Estimation of snow and glacial melt contribution through stable isotopes and assessment of its impact on river morphology through stream power approach in two Himalayan river basins

The impact of increased temperature on the Third Pole, as the Himalayas is referred to, and the likely cascading impacts on the general downstream hydrology have been widely noted. However, the impact on fluvial geomorphology has not received specific attention. Change in the glacial domain in terms of melt increase will change discharge and sediment flux into fluvial system, which will induce changes in fluvial processes and forms. The present work attempts to study this process-based glacio-fluvial coupling in the two neighbouring glaciated river basins in the Northwest Himalaya, viz., the Sutlej and the Yamuna river basins till the mountain front. A total of 194 samples of river, tributary and groundwater of pre- and post-monsoon seasons in the two river basins were analysed for stable isotopes. The trend of δ¹⁸O and electrical conductivity along the mainstream gives qualitative idea on the influence of headwaters in the downstream of the catchment thereby allowing inference on melt contribution. Further, two component mixing model using stable oxygen isotope of two seasons water samples showed that melt contributes about 41.1–66.8 and 6.6–10.6% at different points to the total river discharge in the Sutlej and the Tons River (the glaciated, major tributary of the Yamuna River) basins, respectively. For different scenarios of increase in melt, stream power increase in the Sutlej River basin is significant as opposed to the Tons River. River channel in the Sutlej River basin will be significantly more impacted in comparison with the Yamuna River system.     

Numerical analysis of thermal effects during carbon dioxide injection with enhanced gas recovery: a theoretical case study for the Altmark gas field

Prediction about reservoir temperature change during carbon dioxide injection requires consideration of all, often subtle, thermal effects. In particular, Joule?CThomson cooling (JTC) and the viscous heat dissipation (VHD) effect are factors that cause flowing fluid temperature to differ from the static formation temperature. In this work, warm-back behavior (thermal recovery after injection completed), as well as JTC and VHD effects, at a multi-layered depleted gas reservoir are demonstrated numerically. OpenGeoSys (OGS) is able to solve coupled partial differential equations for pressure, temperature and mole-fraction of each component of the mixture with a combination of monolithic and staggered approaches. The Galerkin finite element approach is adapted for space discretization of governing equations, whereas for temporal discretization, a generalized implicit single-step scheme is used. For numerical modeling of warm-back behavior, we chose a simplified test case of carbon dioxide injection. This test case is numerically solved by using OGS and FeFlow simulators independently. OGS differs from FeFlow in the capability of representing multi-componential effects on warm-back behavior. We verify both code results by showing the close comparison of shut-in temperature profiles along the injection well. As the JTC cooling rate is inversely proportional to the volumetric heat capacity of the solid matrix, the injection layers are cooled faster as compared to the non-injection layers. The shut-in temperature profiles are showing a significant change in reservoir temperature; hence it is important to account for thermal effects in injection monitoring.     

Geochemical Characterization and Controlling Factors of Chemical Composition of Spring Water in a Part of Eastern Himalaya

This paper focuses on the suitability of spring water for drinking and irrigation purposes in a part of eastern Himalaya, south Sikkim. There are many anthropogenic and geogenic factors contributing as a source of major cations and anions in the spring water. The spring water chemistry show a variation in EC, pH, TDS, Temperature, Na⁺, K⁺, Mg²⁺, Ca²⁺, Fe²⁺, Pb, Mn, Cu, HCO₃^-, Cl^-, PO₄^3-, NO₃^-, F^- and SO₄^2-. Mainly two types of water quality indexing has been used, one for suitability of spring water for drinking purposes and the other for irrigation purposes. For drinking purposes, Piper diagram used for determination of water type, water quality index (WQI) for quality monitoring and saturation index for mineral dissolution in water. % Na, RSC (Residual Sodium Carbon) and SAR (sodium absorption ratio) have been used for irrigation suitability. Piper diagram shows that CaHCO₃ type of water was dominant in the study area. The WQI depicted excellent category and SAR, percent sodium and RSC (Residual Sodium Carbon) depict excellent, good and permissible category for irrigation purposes. Principle component analysis (PCA) was used to determine the major influencing factor responsible for the variability in the parameters analysed of spring water.     

Hydrogeochemistry of the Chhota Shigri glacier meltwater,Chandra basin,Himachal Pradesh,India: solute acquisition processes,dissolved load and chemical weathering rates

The chemical compositions of various ions in meltwater of the Chhota Shigri glacier were analysed during the observation period from May to October 2010. Total 164 samples of meltwater were collected in two times a day at 8.0 a.m and 6.0 p.m. Bicarbonate and calcium were the dominant anion and cation in meltwater of the investigation area. High ratios of (Ca + Mg) versus TZ⁺ and (Ca + Mg) versus (Na + K) demonstrate that hydrogeochemistry of the study area was mainly governed by carbonate type weathering. The average sulphate mass fraction of meltwater was computed to be 0.31 ± 0.12, showing dominancy of bicarbonate over sulphate. This excess bicarbonate would be generated by an alternative proton supply mechanism due to biological activities in the bed rock lithology and sulphide oxidation may be about the same as carbonation as a driver of chemical weathering at Chhota Shigri glacier. In general, major ions and total dissolved solid concentrations showed decreasing trend with increasing discharge from the study area. The average daily mean dissolved load of this glacier was much lower than that of the Gangotri glacier, which may be due to low meltwater runoff and lithology of the investigation area. The cation weathering rates of study area for early, peak and late melt seasons were computed to be 694, 1631 and 481 meq m^?2 a^?1, respectively. The average value of chemical denudation rates of the Chhota Shigri glacier meltwater was found lower than that of the Dokriani glacier.     

Local site effects in Latur, India: an empirical study based on the aftershocks of the Killari earthquake of September 29, 1993

The site amplification is estimated at five seismic stations of the Latur region using the horizontal to vertical spectral ratios of 33 aftershocks of the main Killari earthquake of September 29, 1993 (UTC). Spectral amplifications, ranging from a factor of 2–6 are found to vary with frequency at different places. Significant amplification is found at four sites within the Latur region, at Basavakalyan, Kasgi, Killari, and Mudgad Eakoji villages. Our results show a positive correlation between the site amplification and the damage pattern in area. The pattern and the nature of the site amplification estimated in the present study corroborates also with the analytical models and the borehole data indicating alternating layers of unconsolidated sediments and basaltic rocks.     

Surface and groundwater quality characterization of Deoria District,Ganga Plain,India

A water quality investigation was carried out in the Deoria district, Ganga plain, to assess the suitability of surface and groundwaters for domestic, agricultural, and industrial purposes. As much as 50 representative samples from river and groundwater were collected from various stations to monitor the water chemistry of various ions, comprising Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ⁻, SO₄ ²⁻, NO₃ ⁻, Cl⁻, F⁻, and trace metals, such as Fe, Cu, Mn, Zn, Cd, and Pb. The results showed that electrical conductance (EC), total dissolved solids (TDS), HCO₃ ⁻, Mg²⁺, Na⁺, and total hardness (TH) are above the maximum desirable limit, and apart from Fe and Mn all other trace metals are within the maximum permissible limit for drinking water. The calculated values for sodium absorption ratio (SAR), salinity, residual sodium carbonate (RSC), and permeability index (PI) indicate well to permissible use of water for irrigation. High values of Na%, RSC, and Mg-hazard (MH) at some stations restrict its use for agricultural purpose. Anthropogenic activities affect the spatial variation of water quality. Economic and social developments of the study area is closely associated with the characteristics of the hydrological network.     

Aftershock sequences of two great Sumatran earthquakes of 2004 and 2005 and simulation of the minor tsunami generated on September 12, 2007 in the Indian Ocean and its effect

We present the seismic energy, strain energy, frequency–magnitude relation (b-value) and decay rate of aftershocks (p-value) for the aftershock sequences of the Andaman–Sumatra earthquakes of December 26, 2004 (M _w 9.3) and March 28, 2005 (M _w 8.7). The energy released in aftershocks of 2004 and 2005 earthquake was 0.135 and 0.365% of the energy of the respective mainshocks, while the strain release in aftershocks was 39 and 71% for the two earthquakes, respectively. The b-value and p-value indicate normal value of about 1. All these parameters are in normal range and indicate normal stress patterns and mechanical properties of the medium. Only the strain release in aftershocks was considerable. The fourth largest earthquake in this region since 2004 occurred in September 2007 off the southern coast of Island of Sumatra, generating a relatively minor tsunami as indicated by sea level gauges. The maximum wave amplitude as registered by the Padang, tide gauge, north of the earthquake epicenter was about 60 cm. TUNAMI-N2 model was used to investigate ability of the model to capture the minor tsunami and its effect on the eastern Indian Coast. A close comparison of the observed and simulated tsunami generation, propagation and wave height at tide gauge locations showed that the model was able to capture the minor tsunami phases. The directivity map shows that the maximum tsunami energy was in the southwest direction from the strike of the fault. Since the path of the tsunami for Indian coastlines is oblique, there were no impacts along the Indian coastlines except near the coast of epicentral region.