A spatial cross‐correlation model of spectral accelerations at multiple periods

Many seismic loss problems (such as disruption of distributed infrastructure and losses to portfolios of structures) are dependent upon the regional distribution of ground‐motion intensity, rather than intensity at only a single site. Quantifying ground‐motion over a spatially‐distributed region therefore requires information on the correlation between the ground‐motion intensities at different sites during a single event. The focus of the present study is to assess the spatial correlation between ground‐motion spectral accelerations at different periods. Ground motions from eight well‐recorded earthquakes were used to study the spatial correlations. On the basis of obtained empirical correlation estimates, we propose a geostatistics‐based method to formulate a predictive model that is suitable for simulation of spectral accelerations at multiple sites and multiple periods, in the case of crustal earthquakes in active seismic regions. While the calibration of this model and investigation of its implications were somewhat complex, the model itself is very simple to use for making correlation predictions. A user only needs to evaluate a simple equation relying on three sets of coefficients provided here to compute a correlation coefficient for spectral values at two periods and at a specified separation distance. These results may then be used in evaluating the seismic risk of portfolios of structures with differing fundamental periods. Copyright © 2012 John Wiley & Sons, Ltd.     

Conditional spectrum‐based ground motion selection. Part I: Hazard consistency for risk‐based assessments

The conditional spectrum (CS, with mean and variability) is a target response spectrum that links nonlinear dynamic analysis back to probabilistic seismic hazard analysis for ground motion selection. The CS is computed on the basis of a specified conditioning period, whereas structures under consideration may be sensitive to response spectral amplitudes at multiple periods of excitation. Questions remain regarding the appropriate choice of conditioning period when utilizing the CS as the target spectrum. This paper focuses on risk‐based assessments, which estimate the annual rate of exceeding a specified structural response amplitude. Seismic hazard analysis, ground motion selection, and nonlinear dynamic analysis are performed, using the conditional spectra with varying conditioning periods, to assess the performance of a 20‐story reinforced concrete frame structure. It is shown here that risk‐based assessments are relatively insensitive to the choice of conditioning period when the ground motions are carefully selected to ensure hazard consistency. This observed insensitivity to the conditioning period comes from the fact that, when CS‐based ground motion selection is used, the distributions of response spectra of the selected ground motions are consistent with the site ground motion hazard curves at all relevant periods; this consistency with the site hazard curves is independent of the conditioning period. The importance of an exact CS (which incorporates multiple causal earthquakes and ground motion prediction models) to achieve the appropriate spectral variability at periods away from the conditioning period is also highlighted. The findings of this paper are expected theoretically but have not been empirically demonstrated previously. Copyright © 2013 John Wiley & Sons, Ltd.     

Conditional spectrum‐based ground motion selection. Part II: Intensity‐based assessments and evaluation of alternative target spectra

In a companion paper, an overview and problem definition was presented for ground motion selection on the basis of the conditional spectrum (CS), to perform risk‐based assessments (which estimate the annual rate of exceeding a specified structural response amplitude) for a 20‐story reinforced concrete frame structure. Here, the methodology is repeated for intensity‐based assessments (which estimate structural response for ground motions with a specified intensity level) to determine the effect of conditioning period. Additionally, intensity‐based and risk‐based assessments are evaluated for two other possible target spectra, specifically the uniform hazard spectrum (UHS) and the conditional mean spectrum (CMS, without variability).It is demonstrated for the structure considered that the choice of conditioning period in the CS can substantially impact structural response estimates in an intensity‐based assessment. When used for intensity‐based assessments, the UHS typically results in equal or higher median estimates of structural response than the CS; the CMS results in similar median estimates of structural response compared with the CS but exhibits lower dispersion because of the omission of variability. The choice of target spectrum is then evaluated for risk‐based assessments, showing that the UHS results in overestimation of structural response hazard, whereas the CMS results in underestimation. Additional analyses are completed for other structures to confirm the generality of the conclusions here. These findings have potentially important implications both for the intensity‐based seismic assessments using the CS in future building codes and the risk‐based seismic assessments typically used in performance‐based earthquake engineering applications. Copyright © 2013 John Wiley & Sons, Ltd.     

Polybrominated diphenyl ethers and polychlorinated biphenyls in sediments of southwest Taiwan: regional characteristics and potential sources

Very little information is available on the contamination of coastal sediments of Taiwan by PBDEs and PCBs. In this study, we determined the concentrations of 19 PBDE and 209 PCB congeners in 57 surface sediment samples to identify the possible sources of PBDEs and PCBs. The total PBDE and PCB concentrations ranged from below detection limit to 7.73 ng/g and 0.88-7.13 ng/g, respectively; these values are within the ranges observed for most coastal sediments worldwide. The PBDE congeners were dominated by BDE-209 (50.7-99.7%), with minor contributions from penta- and octa-BDEs. The signatures of PCB congeners suggested that PCB residues in Kaohsiung coast may be the legacy of past use or the result of ongoing inputs from the maintenance, repair and salvage of old ships. Principal component analysis of the congener-specific composition of PBDEs and PCBs revealed distinct regional patterns that are related to the use of commercial products.     

The 3D Geometry of Active Region Upflows Deduced from Their Limb-to-Limb Evolution

We analyze the evolution of coronal plasma upflows from the edges of AR 10978, which has the best limb-to-limb data coverage with Hinode’s EUV Imaging Spectrometer (EIS). We find that the observed evolution is largely due to the solar rotation progressively changing the viewpoint of nearly stationary flows. From the systematic changes in the upflow regions as a function of distance from disc center, we deduce their 3D geometrical properties as inclination and angular spread in three coronal lines (Si vii, Fe xii, and Fe xv). In agreement with magnetic extrapolations, we find that the flows are thin, fan-like structures rooted in quasi separatrix layers (QSLs). The fans are tilted away from the AR center. The highest plasma velocities in these three spectral lines have similar magnitudes and their heights increase with temperature. The spatial location and extent of the upflow regions in the Si vii, Fe xii, and Fe xv lines are different owing to i) temperature stratification and ii) line of sight integration of the spectral profiles with significantly different backgrounds. We conclude that we sample the same flows at different temperatures. Further, we find that the evolution of line widths during the disc passage is compatible with a broad range of velocities in the flows. Everything considered, our results are compatible with the AR upflows originating from reconnections along QSLs between over-pressure AR loops and neighboring under-pressure loops. The flows are driven along magnetic field lines by a pressure gradient in a stratified atmosphere. Our interpretation of the above results is that, at any given time, we observe the superposition of flows created by successive reconnections, leading to a broad velocity distribution.     

A search for amino acids and nucleobases in the Martian meteorite Roberts Massif 04262 using liquid chromatography‐mass spectrometry

The investigation into whether Mars contains signatures of past or present life is of great interest to science and society. Amino acids and nucleobases are compounds that are essential for all known life on Earth and are excellent target molecules in the search for potential Martian biomarkers or prebiotic chemistry. Martian meteorites represent the only samples from Mars that can be studied directly in the laboratory on Earth. Here, we analyzed the amino acid and nucleobase content of the shergottite Roberts Massif (RBT) 04262 using liquid chromatography‐mass spectrometry. We did not detect any nucleobases above our detection limit in formic acid extracts; however, we did measure a suite of protein and nonprotein amino acids in hot‐water extracts with high relative abundances of β‐alanine and γ‐amino‐n‐butyric acid. The presence of only low (to absent) levels of several proteinogenic amino acids and a lack of nucleobases suggest that this meteorite fragment is fairly uncontaminated with respect to these common biological compounds. The distribution of straight‐chained amine‐terminal n‐ω‐amino acids in RBT 04262 resembled those previously measured in thermally altered carbonaceous meteorites (Burton et al. 2012; Chan et al. 2012). A carbon isotope ratio of ?24‰ ± 6‰ for β‐alanine in RBT 04262 is in the range of reduced organic carbon previously measured in Martian meteorites (Steele et al. 2012). The presence of n‐ω‐amino acids may be due to a high temperature Fischer‐Tropsch‐type synthesis during igneous processing on Mars or impact ejection of the meteorites from Mars, but more experimental data are needed to support these hypotheses.     

Metamorphism and Metasomatism at King Island Scheelite Mine

Abstract

The King Island Scheelite Mine lies in the contact aureole of a granodiorite stock. Its open cut and numerous drill cores expose a contact metamorphosed and metasomatized series of finely interbedded argillaceous and calcareous sediments, with interleaved flows of picrite-basalt and basic pyroclastics, the scheelite ore being limited to two limestone horizons. The range and gradation in composition of the original rocks has resulted in an unusual variety of meta-morphic rocks, including forsterite-phlogopite-spinel-tremolite hornfels, anthophyllite-cordierite hornfels, biotite hornfels, actinolite hornfels, a variety of calc-flinta, and marbles. The original sedimentation gave rise to a rapid alternation of limestone and shale, many times repeated, and during metamorphism these rocks reacted with each other to produce narrow bands of calc-flinta.

Subsequent pyrometasomatism selectively converted the greater part of the marble beds to scheelite-bearing andradite skarn, leaving the various hornfels and calc-flinta very little affected. The replacement of the marble was a volume for volume process, and the conversion of 1,000,000 tons of marble to average grade ore involved the introduction of about 350,000 tons of SiO₂, 250,000 tons of Fe₂O₃, 55,000 tons AI₂O₃, 30,000 tons of H₂O and 82,500 tons of CaO.

The temperature of the contact metamorphism attained over 500° C, and the rocks cooled to about 400° C. before the pyrometasomatism occurred. The rocks giving rise to the various hornfels underwent varying degrees of contraction during metamorphism, whereas the limestones probably expanded during metamorphism, and became more permeable to solutions.     

Polycyclic aromatic hydrocarbons in sediments,mussels and crustacea around a former gasworks site in Shoreham-by-Sea,UK

Concentrations of polycyclic aromatic hydrocarbons have been determined in sediments, mussels and crustacea in the vicinity of a former gasworks site by Shoreham Harbour, UK. Very high concentrations of PAH were found in the substrate, an ash-like material deposited on the former gasworks site, which exhibited a profile consistent with the major source of contamination being coal or coke tar produced during the period of gas production at the site. Elevated PAH concentrations were also found in mussels both from the beach below the former gasworks site, and from sites further to the east in Portslade and Hove. The significance of these concentrations were assessed using an approach which involved the calculation of benzo[a]pyrene equivalent conoentrations (BaPEs), summing concentrations of individual PAH on the basis of their comparative potency as carcinogens. BaPE ranged from values of, or close to, zero for crustacea, to 336 microg kg(-1) wet weight in mussels from Southwick Beach. The contaminated mussels are not exploited commercially but may be taken by casual gatherers, and notices have been posted to warn potential consumers.