Present environmental status of Al-Kharrar Lagoon,central of the eastern Red Sea coast,Saudi Arabia

Al-Kharrar Lagoon is a fossil back-reef basin with hypersaline waters, situated 10 km northwest of Rabigh city, central of the eastern Red Sea coast, Saudi Arabia. About 130 stations were selected for measurements of the lagoon’s water temperature, salinity, pH, dissolved oxygen, and water depths during March 2014. The common macro-algae, flora, and fauna were also sampled and identified. The present study aims to investigate the prevailing environmental parameters and their impact on the macro-fauna/flora of the lagoon. The average water depth of the lagoon was around 5 m and reached maximum values of 8 and 16 at the lagoon centre and inlet, respectively. The results showed that the lagoon’s surface water temperature and salinity have mean values of 25 °C and 40‰, but with extreme values of 30 °C and 45‰ that occurred only at the enclosed intertidal areas, respectively. Their dissolved oxygen (DO) and pH were 6.5 mg/l and 8.3, respectively and the latter showing the highest values up to 8.5 in the intertidal areas dominated by the green cyanobacteria. These physicochemical conditions make the lagoon as a favorite place for the mangrove Avicennia marina, macro-algae, seagrasses (Halophila stipulacea and Cymodocea rotundata), and algal mats (Cyanobacteria) which dominate the intertidal and supratidal areas of the lagoon, tolerating extremely high-salinity and high-temperature conditions. On the other hand, corals were observed alive at the southern part of the lagoon, immediately south of the Al-Ultah Islet. Vertical profiles of temperature, salinity, and density in the lagoon’s water indicated that the water column consists of two layers throughout the year.     

Update earthquake risk assessment in Cairo,Egypt

The Cairo earthquake (12 October 1992; m _b  = 5.8) is still and after 25 years one of the most painful events and is dug into the Egyptians memory. This is not due to the strength of the earthquake but due to the accompanied losses and damages (561 dead; 10,000 injured and 3000 families lost their homes). Nowadays, the most frequent and important question that should rise is “what if this earthquake is repeated today.” In this study, we simulate the same size earthquake (12 October 1992) ground motion shaking and the consequent social-economic impacts in terms of losses and damages. Seismic hazard, earthquake catalogs, soil types, demographics, and building inventories were integrated into HAZUS-MH to produce a sound earthquake risk assessment for Cairo including economic and social losses. Generally, the earthquake risk assessment clearly indicates that “the losses and damages may be increased twice or three times” in Cairo compared to the 1992 earthquake. The earthquake risk profile reveals that five districts (Al-Sahel, El Basateen, Dar El-Salam, Gharb, and Madinat Nasr sharq) lie in high seismic risks, and three districts (Manshiyat Naser, El-Waily, and Wassat (center)) are in low seismic risk level. Moreover, the building damage estimations reflect that Gharb is the highest vulnerable district. The analysis shows that the Cairo urban area faces high risk. Deteriorating buildings and infrastructure make the city particularly vulnerable to earthquake risks. For instance, more than 90 % of the estimated buildings damages are concentrated within the most densely populated (El Basateen, Dar El-Salam, Gharb, and Madinat Nasr Gharb) districts. Moreover, about 75 % of casualties are in the same districts. Actually, an earthquake risk assessment for Cairo represents a crucial application of the HAZUS earthquake loss estimation model for risk management. Finally, for mitigation, risk reduction, and to improve the seismic performance of structures and assure life safety and collapse prevention in future earthquakes, a five-step road map has been purposed.     

Recent increase in surface fCO<Subscript>2</Subscript> in the western subtropical North Pacific

We observed unusually high levels (> 440 μatm) of carbon dioxide fugacity (fCO₂) in surface seawater in the western subtropical North Pacific, the area where Subtropical Mode Water is formed, during summer 2015. The NOAA Kuroshio Extension Observatory moored buoy located in this region also measured high CO₂ values, up to 500 μatm during this period. These high sea surface fCO₂ (fCO_2SW) values are explained by much higher normalized total dissolved inorganic carbon and slightly higher normalized total alkalinity concentrations in this region compared to the equatorial Pacific. Moreover, these values are much higher than the climatological CO₂ values, even considering increasing atmospheric CO₂, indicating a recent large increase in sea surface CO₂ concentrations. A large seasonal change in sea surface temperature contributed to higher surface fCO_2SW in the summer of 2015.     

Influence of magnetic effect,anisotropy, irregularity,initial stress and heterogeneity on propagation of SH-wave in an irregular pre-stressed magnetoelastic monoclinic sandwiched layer

Monoclinic materials viz. quartz, lithium niobate and lithium tantalate are among the most abundant materials, finding numerous applications throughout the technological world. Moreover, the presence of irregularity, initial stresses, anisotropy and heterogeneity in a material medium is obvious. These facts motivate the study of magnetoelastic SH-wave propagation in an irregular monoclinic sandwiched layer between a heterogeneous isotropic layer and an isotropic half space, all under initial stress. The heterogeneity in the uppermost layer is caused due to exponential variation in rigidity, density and initial stress in terms of space variable pointing vertically downward. The dispersion relation has been obtained using first-order perturbation technique. The substantial effect of wave number, anisotropy, irregularity, width ratio of the layers, horizontal compressive/tensile initial stresses, heterogeneity and monoclinic-magnetoelastic coupling parameter associated with sandwiched layer on phase velocity of SH-wave has been studied and depicted by means of graph. Comparative study made for the case when pre-stressed irregular sandwiched layer is monoclinic-magnetoelastic to the case when it is isotropic magnetoelastic layer is one of the major highlights of the current study.     

Roughness control on hydraulic conductivity in fractured rocks

The influence of joint roughness on the typologies of fluid flow inside fractures is well known and, thanks to experiences in the field of hydraulics, it has been studied from both a physical and mathematical point of view. Nevertheless, the formulations adopted by traditional hydraulic models are hardly applicable in the geological field, because of the difficulty encountered in the roughness parameter estimation. Normally this parameter can be estimated using the joint roughness coefficient (JRC), which considers both the asperity height and its regularity and directional trend. The main advantage in using the JRC arises from the fact that it can easily be obtained from geological-technical surveys and from comparison with the standard Barton profiles. Some relationships have been built up that allow for the estimation of the hydraulic conductivity tensor (an essential parameter for understanding water flow in fractured rock masses), not only as a function of traditional parameters like aperture, spacing, dip and dip direction, etc., but also of joint roughness, precisely expressed in terms of the roughness coefficient. These relationships have been studied initially from a theoretical point of view and then practically, through laboratory investigations.

---

Resumen  Se conoce muy bien la influencia de la rugosidad de las grietas en las tipologías del flujo de fluidos a lo interior de las fracturas y gracias a las experiencias en el campo de hidráulica ha sido posible estudiarla desde puntos de vista matemáticos y físicos. Sin embargo, las formulaciones adoptadas por los modelos hidráulicos tradicionales tienen poca aplicabilidad en el campo geológico debido a la dificultad relacionada con la estimación del parámetro de rugosidad. Normalmente este parámetro puede estimarse usando el coeficiente de rugosidad de grieta (JRC) el cual considera tanto la altura de la aspereza como su regularidad y tendencia direccional. La principal ventaja de utilizar el JRC se deriva del hecho que puede obtenerse fácilmente de levantamientos técnico-geológicos y de la comparación con los perfiles Standard Barton. Se han construido algunas relaciones que permiten la estimación del tensor de conductividad hidráulica (un parámetro esencial para el entendimiento del flujo de agua en masas de roca fracturadas), no solo en función de parámetros tradicionales como apertura, espaciado, buzamiento y dirección de buzamiento, etc., sino también en función de la rugosidad de la grieta estimada con precisión en términos del coeficiente de rugosidad. Estas relaciones se han estudiado inicialmente desde un punto de vista teórico y luego de modo práctico a través de investigaciones de laboratorio.

---

Résumé  L’influence de la rugosité des joints sur les types d’écoulement de fluide dans les fractures est bien connue et a été étudiée aussi bien du point de vue physique que mathématique grace à des expériences menées dans le domaine de l’hydraulique. Cependant les formulations adoptées dans les modèles hydrauliques traditionnels sont difficilement applicables dans le domaine de la géologie à cause de la difficulté rencontrée pour estimer la rugosité. Ce paramètre peut normalement être apprécié grace au coefficient de rugosité du joint (JRC), lequel prend en compte à la fois la hauteur de l’aspérité ainsi que sa régularité et sa direction. Le principal avantage dans l’utilisation du JRC réside dans le fait qu’il peut facilement être obtenu à partir d’études techniques-géologiques et par comparaison avec la classification de Barton. Des relations qui permettent une estimation du tenseur de conductivité hydraulique (un paramètre essentiel pour comprendre l’écoulement de l’eau dans les masses rocheuses fracturées) ont été élaborées, pas seulement en fonction de paramètres traditionnels tels que l’ouverture, l’espacement, l’inclinaison et la direction d’inclinaison, etc , mais aussi en prenant en compte la rugosité des joints à travers le coefficient de rugosité. Ces relations ont initialement été étudiées d’un point de vue théorique puis expérimentalement à travers des recherches en laboratoire.

     

Linear Elastic and Cohesive Fracture Analysis to Model Hydraulic Fracture in Brittle and Ductile Rocks

Hydraulic fracturing technology is being widely used within the oil and gas industry for both waste injection and unconventional gas production wells. It is essential to predict the behavior of hydraulic fractures accurately based on understanding the fundamental mechanism(s). The prevailing approach for hydraulic fracture modeling continues to rely on computational methods based on Linear Elastic Fracture Mechanics (LEFM). Generally, these methods give reasonable predictions for hard rock hydraulic fracture processes, but still have inherent limitations, especially when fluid injection is performed in soft rock/sand or other non-conventional formations. These methods typically give very conservative predictions on fracture geometry and inaccurate estimation of required fracture pressure. One of the reasons the LEFM-based methods fail to give accurate predictions for these materials is that the fracture process zone ahead of the crack tip and softening effect should not be neglected in ductile rock fracture analysis. A 3D pore pressure cohesive zone model has been developed and applied to predict hydraulic fracturing under fluid injection. The cohesive zone method is a numerical tool developed to model crack initiation and growth in quasi-brittle materials considering the material softening effect. The pore pressure cohesive zone model has been applied to investigate the hydraulic fracture with different rock properties. The hydraulic fracture predictions of a three-layer water injection case have been compared using the pore pressure cohesive zone model with revised parameters, LEFM-based pseudo 3D model, a Perkins-Kern–Nordgren (PKN) model, and an analytical solution. Based on the size of the fracture process zone and its effect on crack extension in ductile rock, the fundamental mechanical difference of LEFM and cohesive fracture mechanics-based methods is discussed. An effective fracture toughness method has been proposed to consider the fracture process zone effect on the ductile rock fracture.     

Recent Rapid Regional Climate Warming on the Antarctic Peninsula

The Intergovernmental Panel on Climate Change (IPCC) confirmed that mean global warming was 0.6 ± 0.2 °C during the 20th century and cited anthropogenic increases in greenhouse gases as the likely cause of temperature rise in the last 50 years. But this mean value conceals the substantial complexity of observed climate change, which is seasonally- and diurnally-biased, decadally-variable and geographically patchy. In particular, over the last 50 years three high-latitude areas have undergone recent rapid regional (RRR) warming, which was substantially more rapid than the global mean. However, each RRR warming occupies a different climatic regime and may have an entirely different underlying cause. We discuss the significance of RRR warming in one area, the Antarctic Peninsula. Here warming was much more rapid than in the rest of Antarctica where it was not significantly different to the global mean. We highlight climate proxies that appear to show that RRR warming on the Antarctic Peninsula is unprecedented over the last two millennia, and so unlikely to be a natural mode of variability. So while the station records do not indicate a ubiquitous polar amplification of global warming, the RRR warming on the Antarctic Peninsula might be a regional amplification of such warming. This, however, remains unproven since we cannot yet be sure what mechanism leads to such an amplification. We discuss several possible candidate mechanisms: changing oceanographic or changing atmospheric circulation, or a regional air-sea-ice feedback amplifying greenhouse warming. We can show that atmospheric warming and reduction in sea-ice duration coincide in a small area on the west of the Antarctic Peninsula, but here we cannot yet distinguish cause and effect. Thus for the present we cannot determine which process is the probable cause of RRR warming on the Antarctic Peninsula and until the mechanism initiating and sustaining the RRR warming is understood, and is convincingly reproduced in climate models, we lack a sound basis for predicting climate change in this region over the coming century.     

Retrieval of the Change of Precipitable Water Vapor by GPS Technique

The feasibility of GPS precipitable water vapor (PWV) is discussed based on the comparison of Radiosonde and GPS PWV where the correlation coefficient is 0.94 and the RMS is 4.0 mm. PWV change in the C...     

Rank statistical analysis of nickel sulphide resources of the Norseman-Wiluna Greenstone Belt,Western Australia

Estimating the undiscovered mineral resources of a terrane is a challenging, yet essential, task in mineral exploration. We apply Zipf’s law rank statistical analysis to estimate the undiscovered nickel sulphide resources in the Norseman-Wiluna Greenstone Belt, Western Australia. The analysis suggests that about 3.0 to 10.0 Mt of nickel sulphide resources are yet to be discovered in this belt, compared to the currently known total nickel sulphide endowment of 10.8 Mt. This undiscovered nickel sulphide endowment is likely to be hosted by incompletely delineated deposits and undiscovered deposits in less explored komatiites in the belt. Using the more detailed data subset of the Kambalda domain, this study manipulates Zipf’s law to estimate the sizes of undiscovered deposits, in addition to the domain’s total nickel sulphide endowment estimate. Importantly, regression analysis shows that the gradient of the line of best fit through the logarithmic rank-size plot for the detailed Kambalda data subset is −1. This gradient, which is the key Zipf’s law constant k, has the value of −0.92 for the Norseman-Wiluna Greenstone Belt which is collectively less mature than the Kambalda domain. This result corroborates the use of k = −1 in Zipf’s law predictive analyses of mineral resources for deposit populations for which the value of k = −1 has not yet been attained due to exploration immaturity.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

Open image in new window

Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.