Microstructure-compositional variation in iron oxy-hydroxide minerals formed with manganese mineralization,Eastern Ghats Supergroup,Orissa

Large volume of iron oxy-hydroxide minerals occur in association with manganese oxide phase in manganese ores of the Eastern Ghats Supergroup, Koraput district, Orissa. On the basis of OH content, the iron mineral can be classified into hydrohematite, goethite, and hydrogoethite. These minerals exhibit eight types of microstructures such as ooloidal, caterpillar, disseminated, reniform, worm, mosaic, globular and spherulitic. Chemical composition of such micro-structures obtained through EPMA, distinguishes them into three domains, developed under different environment. Hydrohematite, having 8–10 % H₂O, characteristically contains higher pc of manganese (>5%) and phosphorous (>0.6%) but have low silica and alumina. These are formed syngenetically with Mn-oxide minerals in a manganese rich paragenesis. Goethite containing 11 to 12% water, has relatively low level of manganese and phosphorous, and formed in a later period, as secondary open space filling. Hydrogoethite shows very high water content (>16%), almost devoid of manganese, and impoverished in phosphorous but having higher percentage of alumina, silica and appreciable copper and nickel. This was latest to form in the zone of oxidation under supergene condition.     

Uncertainties of the 50-year wave height estimation using generalized extreme value and generalized Pareto distributions in the Indian Shelf seas

Natural Hazards - Information about waves with specific return period in a region is essential for the safe design of marine facilities. In this study, significant wave height for 50-year return...     

Identification of wet-prone regions over Northwest Himalaya using high-resolution satellite seasonal estimates

Natural Hazards - The present study aims to evaluate four satellite estimates, namely CMORPH v0.x, PERSIANN-CDR, TMPA-V7 and TMPA-V7-RT, over four seasons (during 2003–2017) against ground...     

Ecological risk assessment of trace metal accumulation in sediments of Veraval Harbor,Gujarat, Arabian Sea

In this study, different types of indices were used to assess the ecological risk of trace metal contamination in sediments on the basis of sediment quality guidelines at Veraval Fishery Harbor. Sediment samples were collected from three sectors in pre-, post-, and monsoon seasons in 2006. Trace metal concentrations were higher in the inner sector during post-monsoon, and it showed the highest statistical significance (p < 0.01) among the stations. Pollution load index was higher than unity, indicating alternation by effluent discharge from industries. Enrichment factor and geo-accumulation index showed that Cd, Pb, and Zn were enriched in the northern part of the harbor and Pb had accumulated in the harbor sediment. The ecological risk assessment index revealed that Ni, Zn, and Pb were higher than the effect range median values, indicating their potential toxicity to the aquatic environment in the Veraval Harbor. Hence, the harbor is dominated by anthropogenic activities rather than natural process.     

Integrated model for earthquake risk assessment using neural network and analytic hierarchy process:Aceh province,Indonesia

Catastrophic natural hazards,such as earthquake,pose serious threats to properties and human lives in urban areas.Therefore,earthquake risk assessment(ERA)is indispensable in disaster management.ERA is an integration of the extent of probability and vulnerability of assets.This study develops an integrated model by using the artificial neural network–analytic hierarchy process(ANN–AHP)model for constructing the ERA map.The aim of the study is to quantify urban population risk that may be caused by impending earthquakes.The model is applied to the city of Banda Aceh in Indonesia,a seismically active zone of Aceh province frequently affected by devastating earthquakes.ANN is used for probability mapping,whereas AHP is used to assess urban vulnerability after the hazard map is created with the aid of earthquake intensity variation thematic layering.The risk map is subsequently created by combining the probability,hazard,and vulnerability maps.Then,the risk levels of various zones are obtained.The validation process reveals that the proposed model can map the earthquake probability based on historical events with an accuracy of 84%.Furthermore,results show that the central and southeastern regions of the city have moderate to very high risk classifications,whereas the other parts of the city fall under low to very low earthquake risk classifications.The findings of this research are useful for government agencies and decision makers,particularly in estimating risk dimensions in urban areas and for the future studies to project the preparedness strategies for Banda Aceh.     

Goethite Morphology and Composition in Banded Iron Formation, Orissa, India

Iron ore deposits are generally described in terms of size, grade and chemical composition rather than the mineralogical and microstructural characteristic of different ore types. It is essential, however, to know the morphology, microstructure and chemical composition of individual minerals for optimum mineral processing. Goethite is reported to occur as a ubiquitous phase in many iron ore types and is particularly abundant in the Precambrian banded iron ore formation of north Orissa, India. Goethite from the Bonai–Keonjhar Belt in Orissa has been examined in terms of its morphology and microstructure in relation to chemical composition. Electron microscopy indicated several goethite morphotypes including botryoidal, nodular, spheroidal, platy, stalactitic and flaky. These different morphotypes display intergranular, intragranular, wedge, reniform, comb, prismatic, cavity-line and bead microstructures. In situ analysis using electron probe microanalyzer indicated a wide compositional variation among the different morphotypes and microstructures. Goethite replacing hematite is generally devoid of deleterious elements while re-precipitated goethite generally contains adsorbed alumina, silica and/or phosphorus. Nodular goethite commonly has a high phosphorus level while botryoidal, spheroidal and platy goethite often contains increased combined alumina and silica. Goethite having a reniform, wedge, intergranular or intragranular microstructure is highly water bearing and cryptocrystalline in nature. During dehydration, bead, comb, cavity-lined or prismatic goethite develop, which are more crystalline and which have a higher iron concentration. Goethite with a wedge, prismatic or bead-type microstructure has a higher adsorption of silica (2–4%), while goethite having an intergranular, bead or prismatic microstructure invariably contains appreciable phosphorus, generally at levels deleterious to processing.     

Application of oxidative stress indices in natural populations of Perna viridis as biomarker of environmental pollution

Oxidative stress indices were measured in gills and digestive glands of Perna viridis collected from three coastal locations in Goa i.e., Bambolim, Marmugao Harbour and Malim. In addition to lipid peroxidation, the activities of antioxidant enzymes such as superoxide dismutase, catalase, glutathione peroxidase, glutathione reductase and glutathione S-transferase and two non-enzymatic antioxidants (ascorbic acid and reduced glutathione) were investigated in order to understand their variation with respect to pollution status of the sampling locations. We observed a significant increase in lipid peroxidation and antioxidant enzymes of both the tissues at Mormugao Harbour and Malim, suggesting that the animals at these two locations are at higher level of oxidative stress as compared to those at Bambolim. Conversely, low levels of non-enzymatic antioxidants such as ascorbic acid and reduced glutathione, observed at Mormugao Harbour and Malim indicate that the animals may use these compounds to counteract stress in the tissues. This study shows that changes in lipid peroxidation, superoxide dismutase, catalase, glutathione reductase, glutathione S-transferase and reduced glutathione in tissues of P. viridis can be used as molecular biomarkers in environmental monitoring programs.     

The H i opacity of the intergalactic medium at redshifts 1.6 < z < 3.2

We use high-quality echelle spectra of 24 quasi-stellar objects to provide a calibrated measurement of the total amount of Lyα forest absorption (DA) over the redshift range  2.2 < z < 3.2  . Our measurement of DA excludes absorption from metal lines or the Lyα lines of Lyman-limit systems and damped Lyα systems. We use artificial spectra with realistic flux calibration errors to show that we are able to place continuum levels that are accurate to better than 1 per cent. When we combine our results with our previous results between  1.6 < z < 2.2  , we find that the redshift evolution of DA is well described over  1.6 < z < 3.2  as   A (1 + z )^γ  , where   A = 0.0062  and  γ= 2.75  . We detect no significant deviations from a smooth power-law evolution over the redshift range studied. We find less H  i absorption than expected at   z = 3  , implying that the ultraviolet background is  ∼40  per cent higher than expected. Our data appears to be consistent with an H  i ionization rate of  Γ∼ 1.4 × 10⁻¹² s⁻¹  .     

Numerical Modeling of Suspended Sediment Transport in the Gulf of Kachchh Including Kandla Creek,West Coast of India

A depth-averaged numerical model has been developed to study tidal circulation and suspended sediment transport in the Gulf of Kachchh including Kandla creek, west coast of India. The resolution of the model is taken as 750 m × 750 m, which is found to be adequate for the gulf region. However, this resolution could not produce the realistic circulation pattern and suspended sediment concentration in the Kandla creek region. There is a major seaport at Kandla which serves as the sea gate to northwest India. Therefore, a 2-D fine resolution (75 m × 75 m) model for Kandla creek has been developed and coupled with the coarser gulf model to compute the flow features in the creek region. The model dynamics and basic formulation remain the same for both the gulf model and the creek model. The models are barotropic, based on shallow water equations, and neglect horizontal diffusion and wind stress terms in the momentum equations. The models are fully nonlinear and use a semiexplicit finite difference scheme to solve mass, momentum, and advection-diffusion equations in a horizontal plane. The tide in the gulf is represented in the model by the semidiurnal M₂ constituent mainly. In this study, no fresh water discharge conditions have been considered so the results are appropriate for the dry season. Numerical experiments are carried out to study the circulation and suspended sediment concentrations in the gulf and the creek regions. The computed results are validated with the available observations.