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31.
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Hydraulic flow and transport (heat and solute) within crystalline rocks is dominated by the fracture systems found within them. In situ stress conditions have a significant impact on the hydraulic, mechanical and thermal coupled processes, and quantification of these processes provides a key to understanding the often transient time-dependent behaviour of crystalline rocks. In this paper, a geomechanical model is presented which describes fracture closure as a function of effective stress and the changes in parameters such as storage, permeability, porosity and aperture. Allowing the fracture closure to be defined by the change in normal effective stress provides a link to the numerical consideration of parametrical changes due to rock stress alterations caused for example by changes in fracture fluid pressure, stress release, tectonic stress, thermal stress, orientation of the natural fracture in the pervasive stress system and local changes in a rock mass due to stress alteration. The model uses geometrical considerations based on a fractal distribution of apertures on the fracture surface, and applies well-established analytical elastic deformation solutions to calculate the deformation response to changes in effective stress. Analysis of the fractal generation method allows a standard normal distribution of fracture apertures to be predicted for all common fractal dimensions relating to a 2D surface. Changes in the fracture aperture are related to hydraulic functions such as permeability, storage and porosity of the fracture. The geomechanical model is experimentally validated against laboratory scale experimental data gained from the closure of a fractured sample recovered at a depth of 3,800 m from the KTB pilot borehole. Parameters for matching the experimental data were established externally, the only fitting parameters applied were the minimum and maximum contact area between the surfaces and the number of allowable contacts. The model provides an insight into the key processes determining the closure of a fracture, and can act as a material input function for numerical models linking the effects of changes in the stress field, hydraulic or thermal conditions, to the flow and transport parameters of a fractured system.
Résumé L’écoulement et le transport (chaleur et soluté) dans les roches cristallines sont dominés par les systèmes de fracture. Les conditions de stress in-situ ont un impact significatif sur l’hydraulique, les processus couplés de mécanique et thermique et la quantification de ces processus apportent une clé pour comprendre le comportement transitoire des roches cristallines. Dans cet article un modèle géomécanique est présenté, modèle qui décrit la fermeture des fractures comme une fonction de la contrainte effective et des changements de paramètres tels le coefficient d’emmagasinement, la perméabilité, la porosité et l’ouverture. En s’accordant que la fermeture des fractures est définit par les changements de la contrainte effective normale, on apporte le lien avec la considération numérique des changements paramétriques dus aux altérations de la contrainte des roches, causés par exemple par des variations de la pression des fluides dans les fractures, du dégagement de la contrainte, des contraintes tectoniques et thermiques, des orientations des fractures naturelles dans le système de contraintes pénétrantes, et des changements locaux dans un massif de roches dus à l’altération des contraintes. Le modèle utilise des considérations géométriques basées sur une distribution fractale des ouvertures à la surface des fractures, et permet d’établir des solutions analytiques de la déformation élastique pour calculer la réponse de la déformation à la contrainte effective. L’analyse de la méthode par génération fractale permet de prédire une distribution normale standard de l’ouverture des fractures, pour toutes les dimensions fractales en relation avec les surfaces 2D. Les changements dans l’ouverture des fractures sont mis en relation avec les fonctions hydrauliques tels la perméabilité, l’emmagasinement et la porosité de la fracture. Le modèle géoméchanique est expérimentalement validé à l’échelle du laboratoire sur un échantillon fracturé récupéré à une profondeur de 3,800 mètres sur le puits du site pilote KTB. Les paramètres du calibrage des données expérimentales ont été établies extérieurement, les seuls paramètres utilisés étant les surfaces de contact minimum et maximum, et le nombre de contacts permis. Le modèle apporte une connaissance perspicace sur le processus clé déterminant la fermeture des fractures, et peut servir de fonction input dans les modèles numériques reliant les effets des variations de la contrainte du terrain, les conditions hydrauliques ou thermales, les paramètres de l’écoulement et du transport et les systèmes de fracture.

Resumen El flujo hidráulico y transporte (de calor y solutos) dentro de rocas cristalinas está dominado por los sistemas de fracturas que se encuentran en ellas. Las condiciones de esfuerzos in-situ tienen un impacto significativo en los procesos aparejados termales, mecánicos e hidráulicos y la cuantificación de estos procesos aporta una clave para entender el frecuente comportamiento transitorio dependiente de las rocas cristalinas. En este artículo se presenta un modelo geomecánico que describe el cierre de fracturas en función del esfuerzo efectivo y los cambios en parámetros tal como almacenamiento, permeabilidad, porosidad y apertura. El definir el cierre de fractura mediante el cambio en esfuerzo normal efectivo aporta un vínculo con la consideración numérica de cambios paramétricos ocasionados por alteraciones de esfuerzos en la roca causadas, por ejemplo, por cambios en presión de fluidos en fractura, liberación de esfuerzo, esfuerzo tectónico, esfuerzo termal, orientación de fracturas naturales en el sistema de esfuerzos penetrante, y cambios locales en una masa rocosa ocasionados por alteración de esfuerzos. El modelo utiliza consideraciones geométricas basadas en la distribución fractal de aperturas en la superficie de fractura y aplica soluciones analíticas bien establecidas de deformación elástica para calcular la respuesta de deformación a cambios en el esfuerzo efectivo. Los análisis del método de generación fractal permiten predecir una distribución normal standard para la distribución de aperturas de fracturas para todas las dimensiones fractales comunes que se relacionan con una superficie 2D. Los cambios en la apertura de fractura se relacionan con funciones hidráulicas tal como permeabilidad, almacenamiento y porosidad de la fractura. El modelo geomecánico se ha validado experimentalmente en contra de datos experimentales a escala de laboratorio obtenidos a partir del cierre de una muestra fracturada recuperada a una profundidad de 3,800 m en el pozo piloto KTB. Se establecieron externamente parámetros que se ajustan a los datos experimentales, con los parámetros de ajuste aplicados que fueron el área máxima y mínima de contacto entre las superficies y el número de contactos permisibles. El modelo arroja luz sobre los procesos clave que determinan el cierre de una fractura y puede actuar como un material de función de entrada para modelos numéricos que vinculan los efectos de cambios en el campo de esfuerzos, condiciones termales o hidráulicas, con los parámetros de flujo y transporte de un sistema fracturado.
  相似文献   
33.
Pressure–temperature grids in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O and its subsystems have been calculatedin the range 15–45 kbar and 550–900°C, usingan internally consistent thermodynamic dataset and new thermodynamicmodels for amphibole, white mica, and clinopyroxene, with thesoftware THERMOCALC. Minerals considered for the grids includegarnet, omphacite, diopside, jadeite, hornblende, actinolite,glaucophane, zoisite, lawsonite, kyanite, coesite, quartz, talc,muscovite, paragonite, biotite, chlorite, and plagioclase. Compatibilitydiagrams are used to illustrate the phase relationships in thegrids. Coesite-bearing eclogites and a whiteschist from Chinaare used to demonstrate the ability of pseudosections to modelphase relationships in natural ultrahigh-pressure metamorphicrocks. Under water-saturated conditions, chlorite-bearing assemblagesin Mg- and Al-rich eclogites are stable at lower temperaturesthan in Fe-rich eclogites. The relative temperature stabilityof the three amphiboles is hornblende > actinolite > glaucophane(amphibole names used sensu lato). Talc-bearing assemblagesare stable only at low temperature and high pressure in Mg-and Al-rich eclogites. For most eclogite compositions, talccoexists with lawsonite, but not zoisite, in the stability fieldof coesite. Water content contouring of pressure–temperaturepseudosections, along with appropriate geotherms, provides newconstraints concerning dehydration of such rocks in subductingslabs. Chlorite and lawsonite are two important H2O-carriersin subducting slabs. Depending on bulk composition and pressure–temperaturepath, amphibole may or may not be a major H2O-carrier to depth.In most cases, dehydration to make ultrahigh-pressure eclogitestakes place gradually, with H2O content controlled by divariantor higher variance assemblages. Therefore, fluid fluxes in subductionzones are likely to be continuous, with the rate of dehydrationchanging with changing pressure and temperature. Further, eclogitesof different bulk compositions dehydrate differently. Dehydrationof Fe-rich eclogite is nearly complete at relatively shallowdepth, whereas Mg- and Al-rich eclogites dehydrate continuouslydown to greater depth. KEY WORDS: dehydration; eclogites; phase relations; THERMOCALC; UHP metamorphism; whiteschists  相似文献   
34.
Petrogenetic grids in the system NCKFMASH (Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O)and the subsystems NCKMASH and NCKFASH calculated with the softwareTHERMOCALC 3.1 are presented for the PT range 7–30kbar and 450–680°C, for assemblages involving garnet,chloritoid, biotite, carpholite, talc, chlorite, kyanite, staurolite,paragonite, glaucophane, jadeite, omphacite, diopsidic pyroxene,plagioclase, zoisite and lawsonite, with phengite, quartz/coesiteand H2O in excess. These grids, together with calculated compatibilitydiagrams and PT and TXCa and PXCa pseudosectionsfor different bulk-rock compositions, show that incorporationof Ca into the NKFMASH system leads to many of the NKFMASH invariantequilibria moving to lower pressure and/or lower temperature,which results, in most cases, in the stability of jadeite andgarnet being enlarged, but in the reduction of stability ofglaucophane, plagioclase and AFM phases. The effect of Ca onthe stability of paragonite is dependent on mineral assemblageat different PT conditions. The calculated NCKFMASH diagramsare powerful in delineating the phase equilibria and PTconditions of natural pelitic assemblages. Moreover, contoursof the calculated phengite Si isopleths in PT and PXCapseudosections confirm that phengite barometry in NCKFMASH isstrongly dependent on mineral assemblage. KEY WORDS: phase relations; metapelites; NCKFMASH; THERMOCALC; phengite geobarometry  相似文献   
35.
To validate a resuspension model of particulate material (salmonid farm wastes), a UV fluorescent particle tracer was selected with similar settling characteristics. Tracer was introduced to the seabed (water depth ≈30 m) and sediment samples taken on days 0, 3, 10, 17 and 30 to measure the horizontal and vertical distribution of tracer in sediments. A concentric sampling grid was established at radii of 25, 50, 100, 150, 200, 400, 700 and 1, 000 m from the source on transects 30° apart. The bulk of the deployed tracer was initially concentrated in an area 25 m radius from the release point; tracer was observed to steadily decrease to zero over a period of 30 days. In a 200 m region measured from the release point in the direction of the residual current, the redeposition of tracer was low. A Lagrangian particle tracking model was validated using these observed data by varying resuspension model parameters within limits to obtain the best agreement between spatial and temporal distributions. The validated model generally gave good predictions of total mass budgets (±7% of total tracer released), particulary where tracer concentrations were high near the release point. Best fit model parameters (critical erosion shear stress=0.018 N m−2, erodibility constan=60 g m−2 d−1) are at the low end of reported parameters for coastal resuspension models. Such a low critical erosion shear stress indicates that the frequency of resuspension and deposition events for freshly deposited material is high.  相似文献   
36.
Low-molecular-weight (LMW) aqueous organic acids were generated from six oil-prone source rocks under hydrous-pyrolysis conditions. Differences in total organic carbon-normalized acid generation are a function of the initial thermal maturity of the source rock and the oxygen content of the kerogen (OI). Carbon-isotope analyses were used to identify potential generation mechanisms and other chemical reactions that might influence the occurrence of LMW organic acids. The generated LMW acids display increasing 13C content as a function of decreasing molecular weight and increasing thermal maturity. The magnitudes of observed isotope fractionations are source-rock dependent. These data are consistent with δ13C values of organic acids presented in a field study of the San Joaquin Basin and likely reflect the contributions from alkyl-carbons and carboxyl-carbons with distinct δ13C values. The data do not support any particular organic acid generation mechanism. The isotopic trends observed as a function of molecular weight, thermal maturity, and rock type are not supported by either generation mechanisms or destructive decarboxylation. It is therefore proposed that organic acids experience isotopic fractionation during generation consistent with a primary kinetic isotope effect and subsequently undergo an exchange reaction between the carboxyl carbon and dissolved inorganic carbon that significantly influences the carbon isotope composition observed for the entire molecule. Although generation and decarboxylation may influence the δ13C values of organic acids, in the hydrous pyrolysis system described, the nondestructive, pH-dependent exchange of carboxyl carbon with inorganic carbon appears to be the most important reaction mechanism controlling the δ13C values of the organic acids.  相似文献   
37.
38.
Employment and Socio-spatial Relations in Australia's Cultural Economy   总被引:1,自引:0,他引:1  
This paper examines the significance and contribution of Australian 'creative' industry activities in light of recent debates on the emergence of the 'cultural economy of cities'. First, census employment data and business location counts are used to illustrate patterns of metropolitan primacy and concentration in the cultural industries both across states and in Sydney. Second, the specificities of the locations of cultural production, and the links between cultural industry activities and wider urban-regional change are explored in more detail. A set of observations of urban-regional change is used to demonstrate how the notion of 'cultural economy' should include complex interactions between the material activities of consumers and producers, and the discursive worlds of image makers and place marketers. Urban renewal, housing market pressures and intra-regional migration all mediate Australian experiences of the 'cultural economy'. Such interactions, in addition to key quantitative data on employment and business activity, suggest important policy considerations.  相似文献   
39.
High-resolution seismic data (onshore and offshore), geophysical borehole data as well as detailed lithofacies from airlift boreholes were acquired in northern Netherlands on and around the island of Ameland. Marine and land seismic data combined with information from land boreholes have been explored with the objective of providing a sedimentary model. Qualitative seismic facies analysis of the valley fill commonly shows a thin unit with high amplitude reflectors at the base. Thick units of variable seismic facies (transparent to high amplitude) occur higher up in the sequence. Onlap is common at mid–upper levels within the sandy valley fill (with clay in mm layering), and a transparent seismic facies, corresponding to firm clays, is common at the top. Almost all lithological unit boundaries recognised within core parameters correspond with seismic unconformities within error margins. Subunits contain multiple cyclical trends in gamma ray and grain size. Cyclical trends show lower order fluctuations in gamma radiation on a scale of less than 1 m. Gamma-ray pattern variability between units, e.g. in general coarsening-up or fining-up units, suggests migration of subaqueous outwash fans or ice margin fluctuations. Seismic results could support a headward excavation and backfilling process suggested by Praeg [Morphology, stratigraphy and genesis of buried Elsterian tunnel valleys in the southern North Sea basin [PhD thesis]: University of Edinburgh, 207 pp.; Journal of Applied Geophysics, (this volume)] as being responsible for the formation of buried valleys. On a lithological scale, a more complicated, detailed and cyclical pattern arises. Catastrophic processes are considered unlikely as being responsible for the infill sequence because of the observed small-scale facies variability and because of the presence of diamicton layers. Diamicton layers at the base of basal unconformities as well as higher in sequence could suggest subglacial deformation by grounded ice before and during the valley-fill process.  相似文献   
40.
This article documents the analytical study and feasibility of placing a tuned mass damper in the form of a limber rooftop moment frame atop relatively stiff structures to reduce seismic acceleration response. Six existing structures were analytically studied using a suite of time history and response spectra records. The analyses indicate that adding mass in conjunction with a limber frame results in an increase in the fundamental period of each structure. The fundamental period increase generally results in a decrease in seismic acceleration response for the same time history and response spectra records. Owing to the limber nature of the rooftop frames, non‐linear analysis methods were required to evaluate the stability of the rooftop tuned mass damper frame. The results indicate the addition of a rooftop tuned mass damper frame reduces the seismic acceleration response for most cases although acceleration response can increase if the rooftop frame is not tuned to accommodate the specific structure's dynamic behaviour and localized soil conditions. Appropriate design of the rooftop tuned mass damper frame can result in decreased seismic acceleration response. This translates to safer structures if used as a retrofit measure or a more economical design if used for new construction. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
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