Can stable isotopes be used to monitor landfill leachate impact on surface waters?

Bacterially mediated methanogenesis in municipal solid waste landfills has been shown to cause an enrichment of carbon stable isotope ratios of dissolved inorganic carbon and hydrogen stable isotope ratios of water in landfill leachate. In the present study, we investigate the universality of this enrichment in leachate obtained from four diverse landfill sites in New Zealand. At each site, surface water samples upstream and downstream of landfills were analysed to examine the applicability of stable isotope ratios as a tool for monitoring leachate contamination in landfill-associated streams. The design of leachate collection systems, operational history, and landfill location appeared to strongly influence leachate isotopic values and the effectiveness of isotope ratios as an environmental monitoring tool for surface water.     

Mesozoic transtensional basin history of the Eastern Cordillera, Colombian Andes: Inferences from tectonic models

Backstripping analysis and forward modeling of 162 stratigraphic columns and wells of the Eastern Cordillera (EC), Llanos, and Magdalena Valley shows the Mesozoic Colombian Basin is marked by five lithosphere stretching pulses. Three stretching events are suggested during the Triassic–Jurassic, but additional biostratigraphical data are needed to identify them precisely. The spatial distribution of lithosphere stretching values suggests that small, narrow (<150 km), asymmetric graben basins were located on opposite sides of the paleo-Magdalena–La Salina fault system, which probably was active as a master transtensional or strike-slip fault system. Paleomagnetic data suggesting a significant (at least 10°) northward translation of terranes west of the Bucaramanga fault during the Early Jurassic, and the similarity between the early Mesozoic stratigraphy and tectonic setting of the Payandé terrane with the Late Permian transtensional rift of the Eastern Cordillera of Peru and Bolivia indicate that the areas were adjacent in early Mesozoic times. New geochronological, petrological, stratigraphic, and structural research is necessary to test this hypothesis, including additional paleomagnetic investigations to determine the paleolatitudinal position of the Central Cordillera and adjacent tectonic terranes during the Triassic–Jurassic. Two stretching events are suggested for the Cretaceous: Berriasian–Hauterivian (144–127 Ma) and Aptian–Albian (121–102 Ma). During the Early Cretaceous, marine facies accumulated on an extensional basin system. Shallow-marine sedimentation ended at the end of the Cretaceous due to the accretion of oceanic terranes of the Western Cordillera. In Berriasian–Hauterivian subsidence curves, isopach maps and paleomagnetic data imply a (>180 km) wide, asymmetrical, transtensional half-rift basin existed, divided by the Santander Floresta horst or high. The location of small mafic intrusions coincides with areas of thin crust (crustal stretching factors >1.4) and maximum stretching of the subcrustal lithosphere. During the Aptian–early Albian, the basin extended toward the south in the Upper Magdalena Valley. Differences between crustal and subcrustal stretching values suggest some lowermost crustal decoupling between the crust and subcrustal lithosphere or that increased thermal thinning affected the mantle lithosphere. Late Cretaceous subsidence was mainly driven by lithospheric cooling, water loading, and horizontal compressional stresses generated by collision of oceanic terranes in western Colombia. Triassic transtensional basins were narrow and increased in width during the Triassic and Jurassic. Cretaceous transtensional basins were wider than Triassic–Jurassic basins. During the Mesozoic, the strike-slip component gradually decreased at the expense of the increase of the extensional component, as suggested by paleomagnetic data and lithosphere stretching values. During the Berriasian–Hauterivian, the eastern side of the extensional basin may have developed by reactivation of an older Paleozoic rift system associated with the Guaicáramo fault system. The western side probably developed through reactivation of an earlier normal fault system developed during Triassic–Jurassic transtension. Alternatively, the eastern and western margins of the graben may have developed along older strike-slip faults, which were the boundaries of the accretion of terranes west of the Guaicáramo fault during the Late Triassic and Jurassic. The increasing width of the graben system likely was the result of progressive tensional reactivation of preexisting upper crustal weakness zones. Lateral changes in Mesozoic sediment thickness suggest the reverse or thrust faults that now define the eastern and western borders of the EC were originally normal faults with a strike-slip component that inverted during the Cenozoic Andean orogeny. Thus, the Guaicáramo, La Salina, Bitúima, Magdalena, and Boyacá originally were transtensional faults. Their oblique orientation relative to the Mesozoic magmatic arc of the Central Cordillera may be the result of oblique slip extension during the Cretaceous or inherited from the pre-Mesozoic structural grains. However, not all Mesozoic transtensional faults were inverted.     

Denudation and cooling of the Lake Teletskoye Region in the Altai Mountains (South Siberia) as revealed by apatite fission-track thermochronology

Lake Teletskoye occupies a narrow graben located in the northwestern sector of the Altai fold belt in South Siberia. The lake basin is thought to have formed during the Pleistocene as a distant result of the Cenozoic collision of India and Eurasia that caused a tectonic reactivation of the Palaeozoic Gorny–Altai (GA) and West Sayan (WS) blocks.The present work reports of a pilot fission-track study performed on 13 apatite separates collected from rocks that were sampled along two profiles in close proximity of the lake. The age–length data and AFT thermochronological modelling reveal two important phases of cooling in the Altai Mountains, a first one during the Late Jurassic–Early Cretaceous and a second one that started in the Miocene–Pliocene and that persists until today. The first event is interpreted to result from uplift-induced denudation probably related to the closure of the Mongol–Okhotsk Ocean; the second event can be linked to the young Cenozoic movements that lie at the origin of the formation of the Lake Teletskoye basin.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Impact of suboxia on sinking particulate organic carbon: Enhanced carbon flux and preferential degradation of amino acids via denitrification

Fluxes of particulate organic carbon (POC) through the oxygen deficient waters in the eastern tropical North Pacific were found to be relatively less attenuated with depth than elsewhere in the eastern North Pacific. The attenuation coefficient (b) for the flux was found to be 0.40 versus the composite value of 0.86 determined by Martin et al. (1987). To examine this further, sinking POC was collected using sediment traps and allowed to degrade in oxic and suboxic experiments. Using a kinetic model, it was found that degradation proceeded at similar rates (roughly 0.8 day⁻¹) under oxic and suboxic conditions, but a greater fraction of bulk POC was resistant to degradation in the suboxic experiments (61% vs. 23%). Amino acids accounted for 37% of POC collected at 75m, but following degradation the value dropped to 17% and 16% in the oxic and suboxic experiments respectively. POC collected from 500m was 10% amino acids. The non-AA component of POC collected at 75m was not degraded under suboxic conditions, while under oxic conditions it was. These results suggest that microbes degrading OC under suboxic conditions via denitrification preferentially utilize nitrogen-rich amino acids. This preferential degradation of amino acids suggests that 9% more nitrogen may be lost via water column denitrification than is accounted for when a more “Redfieldian” stoichiometry for POC is assumed.     

Flexural subsidence by 29 Ma on the NE edge of Tibet from the magnetostratigraphy of Linxia Basin, China

This study provides a detailed magnetostratigraphic record of subsidence in the Linxia Basin, documenting a 27 Myr long sedimentary record from the northeastern edge of the Tibetan Plateau. Deposition in the Linxia Basin began at 29 Ma and continued nearly uninterruptedly until 1.7 Ma. Increasing rates of subsidence between 29 and 6 Ma in the Linxia Basin suggest deposition in the foredeep portion of a flexural basin and constrain the timing of shortening in the northeastern margin of the plateau to Late Oligocene–Late Miocene time. By Late Miocene–Early Pliocene time, a decrease in subsidence rates in the Linxia Basin associated with thrust faulting and a 10° clockwise rotation in the basin indicates that the deformation front of the Tibetan plateau had propagated into the currently deforming region northeast of the plateau.     

Water-quality trends in White Rock Creek Basin from 1912-1994 identified using sediment cores from White Rock Lake reservoir, Dallas, Texas

Historical trends in selected water-quality variables from 1912 to 1994 in White Rock Creek Basin were identified by dated sediment cores from White Rock Lake. White Rock Lake is a 4.4-km² reservoir filled in 1912 and located on the north side of Dallas, Texas, with a drainage area of 259 km². Agriculture dominated land use in White Rock Creek Basin before about 1950. By 1990, 72% of the basin was urban. Sediment cores were dated using cesium-137 and core lithology. Major element concentrations changed, and sedimentation rates and percentage of clay-sized particles in sediments decreased beginning in about 1952 in response to the change in land use. Lead concentrations, normalized with respect to aluminum, were six times larger in sediment deposited in about 1978 than in pre-1952 sediment. Following the introduction of unleaded gasoline in the 1970s, normalized lead concentrations in sediment declined and stabilized at about two and one-half times the pre-1952 level. Normalized zinc and arsenic concentrations increased 66 and 76%, respectively, from before 1952 to 1994. No organochlorine compounds were detected in sediments deposited prior to about 1940. Concentrations of polychlorinated biphenyls (PCB) and DDE (a metabolite of DDT) increased rapidly beginning in the 1940s and peaked in the 1960s at 21 and 20 µg kg^-1, respectively, which is coincident with their peak use in the United States. Concentrations of both declined about an order of magnitude from the 1960s to the 1990s to 3.0 and 2.0 µg kg^-1, respectively. Chlordane and dieldrin concentrations increased during the 1970s and 1980s. The largest chlordane concentration was 8.0 µg kg^-1 and occurred in a sediment sample deposited in about 1990. The largest dieldrin concentration was 0.7 µg kg^-1 and occurred in the most recent sample deposited in the early 1990s. Agricultural use of chlordane and dieldrin was restricted in the 1970s; however, both were used as termiticides, and urban use of chlordane continued at least until 1990. Recent use of dieldrin and aldrin, which degrades to dieldrin, has not been reported; however, increasing trends in dieldrin since the 1970s suggest recent urban use could have occurred.