Cooling rates of porphyritic olivine chondrules in the Semarkona (LL3.00) ordinary chondrite: A model for diffusional equilibration of olivine during fractional crystallization

Abstract— Cooling rates of chondrules provide important constraints on the formation process of chondrite components at high temperatures. Although many dynamic crystallization experiments have been performed to obtain the cooling rate of chondrules, these only provide a possible range of cooling rates, rather than providing actual measured values from natural chondrules. We have developed a new model to calculate chondrule cooling rates by using the Fe‐Mg chemical zoning profile of olivine, considering diffusional modification of zoning profiles as crystals grow by fractional crystallization from a chondrule melt. The model was successfully verified by reproducing the Fe‐Mg zoning profiles obtained in dynamic crystallization experiments on analogs for type II chondrules in Semarkona. We applied the model to calculating cooling rates for olivine grains of type II porphyritic olivine chondrules in the Semarkona (LL3.00) ordinary chondrite. Calculated cooling rates show a wide range from 0.7 °C/h to 2400 °C/h and are broadly consistent with those obtained by dynamic crystallization experiments (10–1000 °C/h). Variations in cooling rates in individual chondrules can be attributed to the fact that we modeled grains with different core Fa compositions that are more Fe‐rich either because of sectioning effects or because of delayed nucleation. Variations in cooling rates among chondrules suggest that each chondrule formed in different conditions, for example in regions with varying gas density, and assembled in the Semarkona parent body after chondrule formation.     

The Petrology and Geochemistry of Cone-sheets from the Cuillin Igneous Complex, Isle of Skye: Evidence for Combined Assimilation and Fractional Crystallization during Lithospheric Extension

The origin and evolution of the magma(s) involved in the formationof the olivine tholeiite cone-sheets which invade the 60-MaCuillin Igneous Complex, Isle of Skye, have been investigatedusing mineral chemistry data together with whole-rock major-and trace-element and isotope (Sr and Nd) geochemistry data.The most primitive compositions identified are almost identicalto those of the basalts being erupted at the present day alongthe spreading centre in Iceland. Rare examples of lavas fromthe slightly older lava pile of west-central and north Skye,together with a large number of dykes from the axial zone ofthe Skye Main Swarm, are of similar composition and are referredto as being of the Preshal More Basalt type (spelling is accordingto current Ordnance Survey of Great Britain maps). The intra-suitecompositional variation exhibited by the cone-sheets can beexplained in terms of relatively low-pressure fractionationof the three-phase assemblage olivine+clinopyroxene+plagioclasein their cotectic proportions of 10: 35: 55. Modelling of major-and compatible trace-element data indicates that the most evolvedcomposition may be derived by 60% crystallization of the leastevolved composition. Incompatible trace-element modelling impliesgreater degrees of crystal-liquid fractionation: Y and Zr indicate64 and 68% crystallization, respectively, whereas the rare earthelements (Eu, Yb, Gd, and Ce) indicate between 71 and 75% crystallization.This decoupled behaviour of compatible and incompatible elementsis attributed to the cone-sheet magma(s) evolving in a subjacentmagma chamber, before final emplacement in the overlying crust.Sr- and Nd-isotope data indicate that the cone-sheet magma(s)assimilated upper-crustal lithologies during fractional crystallization,most likely involving amphibolite facies gneiss of the LewisianGneiss Complex. This style of simultaneous assimilation andfractional crystallization (AFC) process in the upper crustfor the Skye cone-sheet magma(s) is in direct contrast to theprocesses identified for the magmas which produced the bulkof the lava field of west-central and north Skye, where assimilationoccurred after fractionation. The cone-sheet magmas were generatedby relatively large degrees of partial melting of a depletedmantle source associated with significant lithospheric stretching.The cause of this depletion, together with the temporal relationshipsbetween the cone-sheet magmas and the dominant transitionalmagmas of the Skye lava field and sill complex, are also discussed. ^* Reprint request to B. R. Bell     

A COMPARISON OF TWO METHODS OF ESTIMATING STATIC FORMATION TEMPERATURE FROM WELL LOGS*

Two methods for estimating the true formation temperature from well logs are compared. One method requires knowledge of the circulation time, whereas the other requires an estimate of the thermal diffusivity of the contents of the well. Both methods require three or more successive bottom-hole temperature measurements. Data from 157 wells have been analyzed, and the calculated formation temperatures from the two methods agree well. By an analysis of best matching of the two methods, it is found that 0.35 × 10^-6 m² s^-1 is a good estimate for the thermal diffusivity of the well contents.     

Paragenetic Trends of Oxide Minerals in Carbonate-rich Kimberlites, with New Analyses from the Benfontein Sill, South Africa

The relationship among kimberlites, carbonate-rich bodies associatedwith them, and the carbonatites associated with alkalis rockcomplexes are reviewed. Particular attention is paid to theparageneses of oxide minerals in six carbonate-kimberlites:Peuyuk, Tunraq, Wesselton, Liqhobong, De Beers, and Benfontein.New analyses of spinel, limonite, and perovskite from the lowerBenfontein Sill, are consistent with previous reports and canbe divided into (1) early macrocrysts and cores of grains, and(2) late rims and groundmass grains. The evolution of a carbonate-richresiduum with progressive crystallization appears to be typicalof carbonate-rich kimberlite magmas, and is texturally relatedto the two stages of oxide precipitation in these carbonate-kimberlites.Thus, early Mg-ilmenite and Cr-rich spinel are separated byreaction textures and carbonate from later Mg-Al-titanomagnetite,perovskite, and accessory utile and apatite. The spinels spana large range in composition from Mg-Al-chromite to Mg-Al-titanomagnetite,with an intermediate gap. This simplified paragenetic scheme,and in particular the spinel trend, is repeated in the fiveother carbonate-kimberlites reviewed. It may be representativeof the hypabyssal kimberlites in general, and others where fluidizationprocesses did not completely disrupt the crystallization sequence.     

Diagenesis of late Cenozoic diatomaceous deposits and formation of the bottom simulating reflector in the southern Bering Sea*

Diatom ooze and diatomaceous mudstone overlie terrigenous mudstone beds at Leg 19 Deep Sea Drilling Project sites. The diatomaceous units are 300-725 m thick but most commonly are about 600 m. Diagenesis of diatom frustules follows a predictable series of physical and chemical changes that are related primarily to temperature (depth of burial and local geothermal gradient). During the first 300-400 m of burial frustules are fragmented and undergo mild dissolution. By 600 m dissolution of opal-A (biogenic silica) is widespread. Silica reprecipitates abundantly as inorganic opal-A between 600 and 700 m sub-bottom depth. Inorganic opal-A is rapidly transformed by crystal growth to opal-CT. The result is formation of silica cemented mudstone and porcelanite beds. A regional acoustic reflector (called the bottom-simulating reflector, or BSR) occurs near 600 m depth in the sections. This acoustic event marks the upper surface where silicification (cementation) is active. In Bering Sea deposits, opal-A is transformed to opal-CT at temperatures between 35° and 50°C. This temperature range corresponds to a sub-bottom depth of about 600 m and is the area where silicification is most active. Thus, the BSR represents an isothermal surface; the temperature it records is that required to transform opal-A to opal-CT. Deposition of at least 500 m of diatomaceous sediment was required before the temperature at the base of the diatomaceous section was appropriate (35°-50°C) for silica diagenesis to occur. Accordingly, silica diagenesis did not begin until Pleistocene time. Once silicification began, in response to sediment accumulation during the Quaternary, the diagenetic front (the BSR) moved upsection in pace with the upward migrating thermal boundary. X-ray diffractograms and SEM photographs show three silica phases, biogenic opal-A, inorganic opal-A’, and opal-CT. These have crystallite sizes of 11-16 A, 20-27 A, and 40-81 A, respectively, normal to 101. The d(101) reflection of opal-CT decreases with depth of burial at DSDP Site 192. This occurs by solid-state ordering and requires at least 700 m of burial. Most clinoptilolite in Leg 19 cores forms from the diagenesis of siliceous debris rather than from the alteration of volcanic debris as is commonly reported.     

Microstructural changes accompanying the opal-A to opal-CT transition: new evidence from the siliceous sinters of Geysir, Haukadalur, Iceland

Opaline silica (opal-A) has formed in marine, lacustrine and geothermal environments throughout geological time. During diagenesis opal-A normally changes to opal-CT, then opal-C, and finally to quartz. Such changes commonly destroy the original fabrics and any fossils that opal-A contained. The physical changes that accompany the opal-A to opal-CT transition, however, are known poorly. X-ray diffraction analyses, electron microprobe analyses and high-resolution, high-magnification scanning electron microscope imagery of siliceous sinters from the Geysir geothermal area in Iceland show that opal-A is formed of heterometric arrays of randomly packed microspheres (up to 5  μ m diameter) with neighbouring spheres commonly being joined by small connection pads. In contrast, enlarged spheres, lepispheres, inverse opal (two types) and spindle frameworks with hexagonal motifs characterize opal-CT. The textures in opal-CT, which vary on a microscale, reflect the complex interplay between dissolution (e.g. inverse opal) and precipitation (e.g. enlarged spheres, spindle frameworks) that probably was mediated by groundwater in a near-surface environment. The processes deciphered from these young rocks should, however, be applicable to sedimentary opal-A and opal-CT of all ages, irrespective of their origin.     

Rates and causes of proglacial river terrace formation in southeast Iceland: an application of lichenometric dating techniques

The immediate proglacial areas of most of the Oraefajökull outlet glaciers in southeast Iceland are characterized by well-developed river terraces, formed by the recent downcutting of the major meltwater streams. This paper examines the rates and causes of dissection in two contrasting cases, using lichenometric dating to establish the ages of individual terraces. An age–size curve for the aggregated Rhizocarpon sub-genus is developed from lichen measurements on dated recessional moraines, and is compared with similar curves obtained by previous workers. Levelling profiles of the terraces are then used in conjunction with the lichenometric dates to determine mean rates of net erosion between each dated surface, and to study the associated variations in channel slope. The results obtained for the Svinafellsá show that the timing and rates of downcutting have been closely related to frontal movements of the Svinafellsjökull glacier. The Kotá terraces, however, may have been formed independently of glacier fluctuations, and are thought to represent stages in the gradual recovery of the stream from the aggradational effects of the 1727 jökulhlaup.     

Microstructure and thermal history of metal particles in CH chondrites

Abstract We have studied metal microstructures in four CH chondrites, Patuxent Range (PAT) 91546, Allan Hills (ALH) 85085, Acfer 214, and Northwest Africa (NWA) 739, to examine details of the thermal histories of individual particles. Four types of metal particles are common in all of these chondrites. Zoned and unzoned particles probably formed as condensates from a gas of chondritic composition in a monotonic cooling regime, as has been shown previously. We have demonstrated that these particles were cooled rapidly to temperatures below 500 K after they formed, and that condensation effectively closed around 700 K. Zoned and unzoned particles with exsolution precipitates, predominantly high‐Ni taenite, have considerably more complex thermal histories. Precipitates grew in reheating episodes, but the details of the heating events vary among individual grains. Reheating temperatures are typically in the range 800–1000 K. Reheating could have been the result of impact events on the CH parent body. Some particles with precipitates may have been incorporated into chondrules, with further brief heating episodes taking place during chondrule formation. In addition to the four dominant types of metal particles, rare Ni‐rich metal particles and Si‐rich metal particles indicate that the metal assemblage in CH chondrites was a mixture of material that formed at different redox conditions. Metal in CH chondrites consists of a mechanical mixture of particles that underwent a variety of thermal histories prior to being assembled into the existing brecciated meteorites.     

A chondrule origin for dusty relict olivine in unequilibrated chondrites

Abstract— We address the origin of “dusty,” metal-bearing relict olivine grains in chondrules. It has been suggested previously that these grains may be either primitive condensates or derived from a previous generation of chondrules. In this paper, we infer the original composition of dusty olivine grains, before they were reduced, and examine the possibility that they were derived from a previous generation of chondrules. Original compositions of dusty grains, including their estimated initial FeO contents and their minor element contents, match closely with compositions of olivines from chondrules in unequilibrated chondrites. In addition, the cores of some dusty grains are unaltered, and the compositions of these cores are also consistent with a chondrule origin. Therefore, we conclude that a derivation from a previous generation of chondrules is a plausible origin for these relicts. Although alternative origins, such as condensates or interstellar grains, cannot be ruled out on the basis of the available data, chondrules are an obvious source, and we suggest that this is the most likely interpretation. If this is the case, it is additional evidence for the importance of recycling of chondrule material in the chondrule-forming region.