The stability of sapphirine + quartz: calculated phase equilibria in FeO–MgO–Al2O3–SiO2–TiO2–O

The presence in rocks of coexisting sapphirine + quartz has been widely used to diagnose conditions of ultra‐high‐temperature (UHT) metamorphism (>900 °C), an inference based on the restriction of this assemblage to temperatures >980 °C in the conventionally considered FeO–MgO–Al₂O₃–SiO₂ (FMAS) chemical system. With a new thermodynamic model for sapphirine that includes Fe₂O₃, phase equilibra modelling using thermocalc software has been undertaken in the FeO–MgO–Al₂O₃–SiO₂–O (FMASO) and FeO–MgO–Al₂O₃–SiO₂– TiO₂–O (FMASTO) chemical systems. Using a variety of calculated phase diagrams for quartz‐saturated systems, the effects of Fe₂O₃ and TiO₂ on FMAS phase relations are shown to be considerable. Importantly, the stability field of sapphirine + quartz assemblages extends down temperature to 850 °C in oxidized systems and thus out of the UHT range.     

Cooling rates of porphyritic olivine chondrules in the Semarkona (LL3.00) ordinary chondrite: A model for diffusional equilibration of olivine during fractional crystallization

Abstract— Cooling rates of chondrules provide important constraints on the formation process of chondrite components at high temperatures. Although many dynamic crystallization experiments have been performed to obtain the cooling rate of chondrules, these only provide a possible range of cooling rates, rather than providing actual measured values from natural chondrules. We have developed a new model to calculate chondrule cooling rates by using the Fe‐Mg chemical zoning profile of olivine, considering diffusional modification of zoning profiles as crystals grow by fractional crystallization from a chondrule melt. The model was successfully verified by reproducing the Fe‐Mg zoning profiles obtained in dynamic crystallization experiments on analogs for type II chondrules in Semarkona. We applied the model to calculating cooling rates for olivine grains of type II porphyritic olivine chondrules in the Semarkona (LL3.00) ordinary chondrite. Calculated cooling rates show a wide range from 0.7 °C/h to 2400 °C/h and are broadly consistent with those obtained by dynamic crystallization experiments (10–1000 °C/h). Variations in cooling rates in individual chondrules can be attributed to the fact that we modeled grains with different core Fa compositions that are more Fe‐rich either because of sectioning effects or because of delayed nucleation. Variations in cooling rates among chondrules suggest that each chondrule formed in different conditions, for example in regions with varying gas density, and assembled in the Semarkona parent body after chondrule formation.     

Microstructure and thermal history of metal particles in CH chondrites

Abstract We have studied metal microstructures in four CH chondrites, Patuxent Range (PAT) 91546, Allan Hills (ALH) 85085, Acfer 214, and Northwest Africa (NWA) 739, to examine details of the thermal histories of individual particles. Four types of metal particles are common in all of these chondrites. Zoned and unzoned particles probably formed as condensates from a gas of chondritic composition in a monotonic cooling regime, as has been shown previously. We have demonstrated that these particles were cooled rapidly to temperatures below 500 K after they formed, and that condensation effectively closed around 700 K. Zoned and unzoned particles with exsolution precipitates, predominantly high‐Ni taenite, have considerably more complex thermal histories. Precipitates grew in reheating episodes, but the details of the heating events vary among individual grains. Reheating temperatures are typically in the range 800–1000 K. Reheating could have been the result of impact events on the CH parent body. Some particles with precipitates may have been incorporated into chondrules, with further brief heating episodes taking place during chondrule formation. In addition to the four dominant types of metal particles, rare Ni‐rich metal particles and Si‐rich metal particles indicate that the metal assemblage in CH chondrites was a mixture of material that formed at different redox conditions. Metal in CH chondrites consists of a mechanical mixture of particles that underwent a variety of thermal histories prior to being assembled into the existing brecciated meteorites.     

Aeolian oriented clasts in beach sediments

Aeolian processes may cause shoreward tilting of discoidal pebbles in a beach sequence. Subsequent covering by washover, back-berm, plane-laminated sand may give a spurious indication of palaeo-sea position unless a regional sedimentological analysis is undertaken.     

A COMPARISON OF TWO METHODS OF ESTIMATING STATIC FORMATION TEMPERATURE FROM WELL LOGS*

Two methods for estimating the true formation temperature from well logs are compared. One method requires knowledge of the circulation time, whereas the other requires an estimate of the thermal diffusivity of the contents of the well. Both methods require three or more successive bottom-hole temperature measurements. Data from 157 wells have been analyzed, and the calculated formation temperatures from the two methods agree well. By an analysis of best matching of the two methods, it is found that 0.35 × 10^-6 m² s^-1 is a good estimate for the thermal diffusivity of the well contents.     

Braidplain deposition of the Upper Triassic Molteno Formation in the main Karoo (Gondwana) Basin, South Africa

ABSTRACT The Upper Triassic (Carnian?) Molteno Formation in the main Karoo (Gondwana) Basin, South Africa forms a northerly thinning, intracratonic clastic wedge comprising sandstones, shales and coals occurring within thick (up to 140 m) laterally persistent fining-upward sequences. These sequences were deposited by braided streams draining an alluvial plain which may have been built on to the distal slopes of alluvial fan complexes of glacial outwash type. Geometric relations between sequences indicate three phases of tectonic activity. The lowermost fining-upward sequence in the south accumulated against a rising mountain front; cessation of movement and an eastward shift in the main locus of tectonism and sedimentation was followed by renewed uplift and basinwide progradation of the second fining-upward sequence adjacent to a fault-block granite terrain located close to the present south-east coastline of South Africa. This is believed to be the granite at the eastern end of the Falkland Island Plateau, an interpretation consistent with its position on most continental reconstructions and the fracture zone marking its northern scarp face. Faulting is attributed to the first phase of extension prior to continental breakup. The sourceward recession and lack of gross fining-upward trends shown by the uppermost fining-upward sequences is accounted for by limited back-faulting of the still active basin margin. Cessation of activity and further basin margin recession occurred with deposition of the overlying floodplain deposits (Elliot Formation) which were distal equivalents of the braided alluvial plain.     

PLACING KANGWANE IN THE NEW SOUTH AFRICA*

ABSTRACT. The South African homelands were central to the apartheid ideology of racial segregation and separate development and as a result became the location for large segments of the African population. Apartheid‐era theorizations of the homelands tended to emphasize their importance to the state, with less attention directed to the divergent and unique social formations that often existed within them. Recent geographical research has been intent on evaluating the spatial imprint of these geographies for resident populations, as well as the varied class, gendered, and institutional formations that accompanied the democratic transition. Using a case study from the former KaNgwane homeland, this article examines the diverse ways in which rural households access environmental and economic resources to produce livelihoods. It is argued that a focus on community variation is needed to interrogate the differential encounters of these places with the local politics and development processes that are emerging in the new South Africa.