Metamorphism, Fluid Flow and Partial Melting in Pelitic Rocks from the Onawa Contact Aureole, Central Maine, USA

Field, petrologic and geochemical data were used to characterizefluid infiltration and partial melting during metamorphism ofpelitic rocks in the contact aureole of the Onawa pluton, centralMaine, USA. Mineral assemblages delineate five metamorphic zoneswithin the contact aureole: chlorite zone, andalusite–cordierite(a–c) zone, alkali feldspar zone, sillimanite zone andleucocratic-vein (l–v) zone. The sequence of observedmineral assemblages and mineral–fluid reactions calculatedby mass balance is similar to those observed in other contactaureoles. Pressure of contact metamorphism is 3 kbar, on thebasis of optimum geothermobarometry calculations. Metamorphictemperatures vary from 500C in the andalusite–cordieritezone to 65OC in the leucocratic-vein zone. Data from fieldobservations, mineral textures, observed reaction stoichiometry,geothermometry and major-element geochemistry suggest that theleucocratic veins of the l-v zone represent crystallized, partialmelts. Two overall calculated mineral reactions are responsiblefor vein formation: which can be modeled as combinations of two NKFMTASH meltingreactions: Progress of (M1) and (M2) was measured in eight samples, andreaction (M1) is the dominant melt-forming reaction in all samples.Partial melting (and vein formation) was therefore driven byinfiltration of the l-v zone by H²O-rich fluids. Calculatedtime-integrated fluid fluxes for l-v zone samples range from09 10⁴ to 31 10⁴ mol/cm², and flow was in the directionof increasing temperature. KEY WORDS: pelites; contact metamorphism; fluid infiltration; partial melting; Onawa Pluton; Maine; USA ^*Corresponding author. Telephone:(516) 632–8192. Fax (516)632–8240 e-mail: gsymmes{at}ccmail.sunysb.edu     

The Sulfide Capacity and the Sulfur Content at Sulfide Saturation of Silicate Melts at 1400{degrees}C and 1 bar

The solubility of sulfur as S^2– has been experimentallydetermined for 19 silicate melt compositions in the system CaO–MgO–Al₂O₃–SiO₂(CMAS)± TiO₂ ± FeO, at 1400°C and 1 bar, using CO–CO₂–SO₂gas mixtures to vary oxygen fugacity (fO₂) and sulfur fugacity(fS₂). For all compositions, the S solubility is confirmed tobe proportional to (fS₂/fO₂)^1/2, allowing the definition ofthe sulfide capacity (C_S) of a silicate melt as C_S = [S](fO₂/fS₂)^1/2.Additional experiments covering over 150 melt compositions,including some with Na and K, were then used to determine C_Sas a function of melt composition at 1400°C. The resultswere fitted to the equation     

Low-{{delta}}18O Rhyolites from Yellowstone: Magmatic Evolution Based on Analyses of Zircons and Individual Phenocrysts

The Yellowstone Plateau volcanic field is one of the largestcenters of rhyolitic magmatism on Earth. Major caldera-formingeruptions are followed by unusual low-     

Lake shoreline development, frost weathering and rock platform erosion in an alpine periglacial environment, Jotunheimen, southern Norway

Ice-dammed lake Boverbrevatnet existed for 75–125 years in the 'Little Ice Age'. After about A.D. 1826, glacier retreat led to a fall in lake level and to exposure of the former shoreline, which includes well-developed platforms cut in metamorphic bedrock. The rock platforms, up to 5.3 m wide and backed by cliffs up to 1.55 m high, are partially covered by large angular boulders which form pavements. Accurate levelling has permitted correlation of platform fragments, overflow cols and related features of the shoreline, such as benches eroded in moraines, ice-push ridges, a perched delta, vegetation trim-lines, lichen limits and a 'lichen-kill' zone. The evolution of the lake, the chronology of deglaciation and the period of formation of the rock platforms have been dated by lichenometry, supported by ¹⁴C dating, Schmidt hammer 'R'-values and historical data. The morphology of the rock platforms, together with estimates of their rate of erosion ranging from 1.4 to 7.1 cm/year, indicate the importance of frost shattering (frost riving, frost wedging or macrogelivation) at the lake margin under a periglacial climate, while the permanence of such platforms as landscape features suggests their use in the reconstruction of former periglacial environments. A semi-quantitative model is outlined for the development of rock platforms which emphasises deep penetration of the annual freeze-thaw cycle, the movement of unfrozen lake water towards the freezing plane, and the growth of segregation ice in fissures and cracks at the interface between lake ice and bedrock. Ice-push and ice-pull processes are involved primarily as transporting agents in the formation of boulder pavements and in the removal of debris from the platforms. Analogous processes may occur on polar coasts producing coastal rock platforms.     

The morphology and dynamics of low amplitude bedwaves upon upper stage plane beds and the preservation of planar laminae

Experimental studies of subcritical, unidirectional flow over upper stage plane beds of medium grained sand reveal the ubiquitous presence of low amplitude bedwaves. Flow depth was 0·11 m, mean flow velocities were 0·86–1·0 m s^?1, shear velocities were 0·058–0·71 m s^?1 and dimensionless shear stresses were 0·56–0·87. Bedwaves are asymmetrical in profile and range from 0·75 to 11 mm in height (mainly 2–6 mm), from 0·7 to 1·3 m in wavelength and have mean celerities of 10 mm s^?1. Flow records suggest that the bedwaves are associated with accelerating flow over the bedwave crests and flow which decelerates and diverges laterally over the troughs. High resolution bed profiling during aggradation of the bed combined with subsequent box coring illustrates that these bedwaves are responsible for the planar laminae characteristic of upper stage plane beds. Lamina preservation is dependent upon the mean aggradation rate and the sequence of bedwaves of different height crossing any point; individual laminae are more readily preserved at higher aggradation rates where the possibility of reworking by later bedwaves is reduced. Laminae are recognized by small changes in grain size and commonly a fining upwards at the top of laminae which is generated by fine grained material infiltrating a lower lamina in the leeside of a bedwave.     

Lake Torfadalsvatn: a high resolution record of the North Atlantic ash zone I and the last glacial-interglacial environmental changes in Iceland

High resolution environmental records with a refined chronology are essential to understand, reconstruct and model the climate dynamics of the last glacial-interglacial transition. Sediments from Lake Torfadalsvatn in northern Iceland contain at least four primary volcanic tephras that belong to ash zone I in the North Atlantic deep-sea cores. We chemically define these basaltic/rhyolitic tephras and the high resolution allows us to date them to about 10,800, 10,600, 9300 and 8900 BP. This detailed tephrostratigraphy will act as a refined dating and correlation tool in the North Atlantic region and enable calibration between different absolute chronologies. The pollen stratigraphy of the sediments suggests that by 10,400 ¹⁴C years BP plant colonization of coastal north Iceland had begun. The pollen stratigraphy shows a succession of pioneer plants, from open tundra vegetation towards birch-juniper woodland, which probably also reflects a transition from a cool climate at 10,400 BP to conditions similar to today's sub-polar oceanic climate around 9200 BP. Diatom data largely concur with the climatic information from pollen, indicating gradually increasing productivity in the lake.     

A Biotite Isograd in South-Central Maine, U.S.A.: Mineral Reactions, Fluid Transfer, and Heat Transfer

The biotite isograd in pelitic schists of the Waterville Formationinvolved reaction of muscovite + ankerite + rutile + pyrite+graphite + siderite or calcite to form biotite + plagioclase+ ilmenite. There was no single reaction in all pelites; eachrock experienced a unique reaction depending on the mineralogyand proportions of minerals in the chlorite-zone equivalentfrom which it evolved. Quartz, chlorite, and pyrrhotite werereactants in some rocks and products in others. All inferredbiotite-forming reactions involved decarbonation and desulfidation;some were dehydration reactions and others were hydration reactions.P-T conditions at the biotite isograd were near 3500 bars and400 °C. C-O-H-S fluids in equilibrium with the pelitic rockswere close to binary CO₂-H₂O mixtures with X_CO2 = 0.02–0.04.During the biotite-forming reaction, pelitic rocks (a) decreasedby 2–5 percent in volume, (b) performed – (4–11)kcal/liter P-V work on their surroundings, (c) absorbed 38–85kcal/liter heat from their surroundings, and (d) were infiltratedby at least 0.9–2.2 rock volumes H₂O fluid. The biotite isograd sharply marks the limit of a decarbonationfront that passed through the terrane during regional metamorphism.Decarbonation converted meta-shales with 6–10 per centcarbonate to carbonate-free pelitic schists. One essential causeof the decarbonation event was pervasive infiltration of theterrane by at least 1–2 rock volumes H₂O fluid early inthe metamorphic event under P-T conditions of the biotite isograd.Average shale contains 4–13 per cent siderite, ankerite,and/or calcite, but average pelitic schist is devoid of carbonateminerals. If the Waterville Formation serves as a general modelfor the metamorphism of pelitic rocks, it is likely that worldwidemany pelitic schists developed by decarbonation of shale caused,in part, by pervasive infiltration of metamorphic terranes byseveral rock volumes of aqueous fluid during an early stageof the metamorphic event.