Changes in trophic flow structure of Independence Bay (Peru) over an ENSO cycle

During the strong warm El Niño (EN) that occurred in 1997/98, Independence Bay (14°S, Peru) showed a ca. 10 °C increase in surface temperatures, higher oxygen concentrations, and clearer water due to decreased phytoplankton concentrations. Under these quasi-tropical conditions, many benthic species suffered (e.g. macroalgae, portunid crabs, and polychaetes) while others benefited (e.g. scallop, sea stars, and sea urchins). The most obvious change was the strong recruitment success and subsequent proliferation of the scallop Argopecten purpuratus, whose biomass increased fiftyfold. To understand these changes, steady-state models of the bay ecosystem trophic structure were constructed and compared for a normal upwelling year (1996) and during an EN (1998), and longer-term dynamics (1996–2003) were explored based on time series of catch and biomass using Ecopath with Ecosim (EwE) software. Model inputs were based on surveys and landings data collected by the Instituto del Mar del Perú (IMARPE). Results indicate that while ecosystem size (total throughput) is reduced by 18% during EN, mainly as a result of decreased total primary production, benthic biomass remains largely unchanged despite considerable shifts in the dominant benthic taxa (e.g. scallops replace polychaetes as secondary consumers). Under normal upwelling conditions, predation by snails and crabs utilize the production of their prey almost completely, resulting in more efficient energy flow to higher trophic levels than occurs during EN. However during EN, the proliferation of the scallop A. purpuratus combined with decreased phytoplankton increased the proportion of directly utilized primary production, while exports and flows to detritus are reduced. The simulations suggest that the main cause for the scallop outburst and for the reduction in crab and macroalgae biomass was a direct temperature effect, whereas other changes are partially explained by trophic interactions. The simulations suggest that bottom-up effects largely control the system.     

The Lateglacial interstadial at the southeastern limit of the Sonoran Desert,Mexico: vegetation and climate reconstruction based on pollen sequences from Ciénega San Marcial and comparison with the subrecent record

The last glacial–interglacial transition encompassed rapid climate oscillations that affected both hemispheres. At low latitudes, the pattern of oscillations is not well established. To address this issue, pollen analysis was performed at Ciénega San Marcial, a monsoon‐influenced site located on the southeastern edge of the Sonoran Desert at the limit of the tropical thornscrub. The pollen record covers the Late Wisconsinan glacial termination II, from 15 650 to 13 400 cal. a BP, including GS‐2 and the Lateglacial interstadial, and a recent historical period (AD c. 1919 to 2004). We applied the modern analogue technique, in which pollen taxa are assigned to plant functional types (PFTs), to reconstruct the past climates. At the end of GS‐2, a Juniperus–Pinus woodland is indicative of annual temperatures 10±2 °C colder than present and higher annual precipitation dominated by winter rains. The onset of the Lateglacial interstadial occurs at c. 15 500 cal. a BP, resulting in a lower sedimentation rate and the spread of a xeric grassland. This period is associated with an increase in summer insolation. A weak signal of summer monsoon intensification is dated to 14 825 cal. a BP but is associated with colder winter temperatures. A wider spread of tropical taxa occurs after 13 800 cal. a BP, along with the loss of Juniperus, suggesting a temperature increase of approximately 3 °C. In spite of the earlier Lateglacial warming, the transition from glacial to interstadial conditions seems to be related to North Atlantic atmospheric variations. We conclude that during the last glacial–interglacial transition, the Sonoran Desert at 28.5° latitude was sensitive to climate variations originating in northern latitudes. The recent historical sequence displays summer‐dominant precipitation and additional drivers of climate change, including anthropogenic factors and El Niño, thus showing a stronger Pacific circulation influence in the subrecent period.     

Inorganic ions and trace metals bulk deposition at an Atlantic Coastal European region

The inorganic chemical composition (major ions and trace metals) of bulk deposition samples collected monthly with bulk collectors at seven Atlantic Coastal European cities (Galicia, Northwest of Spain) during wet season (September 2011 to March 2012) has been assessed and compared. Trace metals (Al, As, Ba, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V and Zn) were analysed in soluble fraction and non-soluble fraction (after acid extraction) of the bulk deposition by inductively coupled plasma-mass spectrometry. Major inorganic ions (Cl^?, NO₃ ^?, SO₄ ^2?, Na⁺, K⁺, Ca²⁺, Mg²⁺ and NH₄ ⁺) were analysed in the soluble fraction of the bulk deposition by capillary zone electrophoresis. Univariate analysis (ANOVA and Multiple Range Test) according to the location of each sampling site was performed. Results also suggest a great influence of cleaner Atlantic air masses. After partition coefficients and enrichment factor estimation, similar sources could be assigned for the ionic and metal composition of bulk deposition at seven urban sites.     

Temporal changes of mollusc populations from a Zostera marina bed in southern Spain (Alboran Sea), with biogeographic considerations

Molluscs associated with a Zostera marina bed from Cantarriján bay (Southern Spain, Alboran Sea) at 14–16 m depth were sampled monthly from October 1996 to September 1997. A total of 44,819 individuals belonging to 80 species were identified. In spite of the high species richness, only seven species of gastropods showed a dominance value (D) higher than 1%. Jujubinus striatus was the dominant species of the assemblage with 70.8% of the total abundance. The other dominant species were Rissoa membranacea (9.8%), Nassarius pygmaeus (5.8%), Mitrella minor (4%), Smaragdia viridis (1.9%), Rissoa monodonta (1.4%), Bittium reticulatum (1.3%). The dynamic pattern of the mollusc populations showed a temporal trend with monthly values of species richness and abundance ranging between 10 and 25 species and between 178 and 4412 individuals·222 m⁻². The species richness and abundance were higher in the spring and summer months than in the autumn and winter ones. The diversity (Shannon–Wiener, H’) follows a similar trend, with increases from April to September and decreases from October to March. H’ values (ranging from 0.45 to 3.10) are more influenced by the evenness (J) than by the species richness. A multivariate analysis (Cluster, Multi-dimensional Scaling) based on both presence/absence and quantitative data has also pointed out a temporal trend, with spring–summer samples significantly different from autumn–winter samples. The temporal changes in abundance seem related with the species’ biology, such as recruitment events, as well as to the canopy features and shoot density variation in the Zostera meadow. From the biogeographical point of view, most of the molluscs (65%) found in the Cantarriján bed, have a Lusitanian–Mediterranean distribution (sensu Ekman 1953 ). The proximity to Africa is shown by the presence of four species with a mainly West African distribution. Only R. membranacea has a typical Atlantic distribution, driven by that of Z. marina in NW Europe.     

Trace element associations with Fe- and Mn-oxides in soil nodules: Comparison of selective dissolution with electron probe microanalysis

Selective dissolution methods have been largely used to get insight on trace element association with solid phases. Modern instrumental techniques offer many tools to test the validity of selective dissolution methods and should be systematically used to this end. The association of trace elements with Fe- and Mn-oxides in soil nodules has been studied here by electron probe microanalysis. The results were compared with findings from an earlier study on selective dissolution of the same nodules by hydroxylamine hydrochloride, acidified hydrogen peroxide, and Na-citrate-bicarbonate-dithionite. Electron probe microanalysis results were consistent with previous findings using selective dissolution and showed that P, As and Cr were mainly present in Fe-oxides, while Co was mainly associated with Mn-oxide phases. These results support the applicability of the studied selective dissolution methods for fractionation of trace elements in soils and sediments containing appreciable amounts of Fe and Mn-oxide phases.     

Monitoring permeable paver runoff with an open-innovation geospatial sensor network

Sensor networks are an essential tool for environmental scientists. As scientists and engineers are beginning to utilize these new methods and devices in their fieldwork, they need to be actively involved in the future of sensor-networking development. Continued sensor network innovation is important for improved standardization, affordability, and interoperability. This article uses a storm water case study to outline an end-to-end open-innovation sensor network. Open innovation by scientists, engineers, and entities is the collaborative process of creating value for this project in permeable paver runoff data and advances within sensor networking. This article focuses on the technical implementation of the near–real-time location and temporally aware sensor network. Data are streamed in near–real-time with subliter precision to the cloud using common off-the-shelf routers. The sensors use Maxim's 1-wire? protocol, and the unique digital serial numbers confirm the data. The data retrieved compare residence times within the permeable paver catchment basins and the control basin. Sensor network advances are made by bridging the gap between sensor protocols and communication systems. These advances enable the development of open-source representational state transfer web services. Our successful implementation serves as an example for others to study and expand upon for a variety of monitoring solutions.     

Wrack Removal as Short-Term Disturbance for <Emphasis Type="Italic">Talitrus Saltator</Emphasis> Density in the Supratidal Zone of Sandy Beaches: an Experimental Approach

A distinctive feature of sandy beaches is the stranded wrack, which represents a key element in the maintenance of their biodiversity and ecosystem function. However, these materials are commonly removed from beaches worldwide. In October–November 2012, a field experiment following an M-BACI design was conducted to assess the effect of wrack removal on sandhopper populations on two sandy beaches on the Atlantic southwest coast of Spain. The beaches, Levante (36°33′N, 6°13′W) and Cortadura (36°28′N, 6°15′W) differed in their morphodynamics (dissipative and intermediate, respectively) and in the dominant wrack sources (seagrasses vs. macroalgae). Wrack removal diminished the density of the sandhopper, Talitrus saltator, a dominant species in the supratidal zone especially under wrack, but the difference between impacted and control plots was short-lived (several days). Juvenile sandhoppers appeared more sensitive to this disturbance than adults, although this was found only at Levante. This study highlights the adaptability of this sandhopper to a single wrack removal event and shows that the magnitude of the effect is likely dependent on the particular characteristics of individual beaches. The consequences of frequent wrack removal from these beaches on sandhopper populations remain to be determined.     

A Comparative Study of the Use of Organoclay‐Based Formulations and Organic Amendment to Reduce the Leaching of the Herbicide MCPA in Soil

MCPA (4‐chloro‐2‐methylphenoxyacetic acid) is an acidic herbicide widely used on olive crops in Spain. Due to its anionic form at natural soil pH, there is high risk of leaching and groundwater contamination by the use of this herbicide. The aim of this work was to study the effects of organoclay‐based formulations of MCPA and olive oil waste amendment on MCPA leaching in a sandy loam soil. For this purpose, batch adsorption and column leaching studies were performed. The organoclays used to prepare the clay‐based formulations of MCPA were obtained by treating Wyoming montmorillonite (SWy‐2) and Arizona montmorillonite (SAz‐1) with an amount of hexadecyltrimethylammonium (HDTMA) cation equal to 100% of the CEC of the montmorillonites. The organic residue used in this study was a solid waste from olive oil production (olive oil waste, OOW). The soil was amended with the organic residue at the rate of 10% (w/w). Batch release and column leaching studies indicated that organoclay‐based formulations of MCPA reduced the release rate and the leaching of the herbicide as compared to the use of a conventional formulation containing the herbicide in an immediately available form. The increase in soil organic matter of the soil upon amendment with the organic residue also resulted in greater adsorption and reduced leaching of MCPA in the soil. Accordingly, both the use of organoclay‐based formulations and the amendment of soil with OOW are proposed as efficient strategies to reduce extensive leaching losses associated with the application of MCPA in high‐risk scenarios, such as Mediterranean olive groves.