Role of biological soil crust cover in bioweathering and protection of sandstones in a semi‐arid landscape (Torrollones de Gabarda,Huesca, Spain)

Sandstone structural landscapes in the semi‐arid Torrollones de Gabarda area (Province of Huesca, NE Spain) are often covered by a well developed biological soil crust of lichens, mosses and cyanobacteria and black coatings on vertical surfaces. By using scanning electron microscopy with backscattered detector imaging, the biological soil crust studied evidenced high activity in the sandstone–crust interface. Processes such as physical disintegration, etching and dwelling as well as biomineralization by calcium oxalate and ?xation of mineral particles by extracellular polymeric substances were observed. On the horizontal sandstone surfaces these processes may cause the occurrence of gnammas and the development of a protective coating that favours intense ?aking when the crust is disturbed. On the sandstone cliffs, columnar and tafoni weathering development is clearly guided by the protective action of the biological soil crust. These qualitative observations are important to develop methodologies to address their quantitative importance in geomorphological processes in semi‐arid landscapes. Copyright © 2004 John Wiley & Sons, Ltd.     

Change-point analysis for serially correlated summit temperatures in the Romanian Carpathians

Characterizing climatic changes in the high-altitude mountain regions helps scientists and policy makers understand the effects of such changes on water resources, economic development, and the health of ecosystems. This paper proposes a change-point analysis to determine the time and magnitude of summer temperature changes in the summit areas of Romanian Carpathians between 1961 and 2007. Due to their altitude, massiveness, and position, Romanian Carpathians are an important barrier for different types of air masses between Western and Southeastern Europe. The results show that the change in summer temperatures occurred shortly after 1980. The average magnitude of this change is consistent with changes occurring in other parts of Southern Europe in the same time period although the magnitude of changes at individual weather stations may differ substantially. We aided our analysis by a statistical method based on regression models with serially correlated ARMA errors.     

Environmental factors controlling the spatiotemporal distribution of microbial communities in a coastal, sandy aquifer system (Doñana, southwest Spain)

Currently, aquifers are considered to be ecosystems that interchange materials and energy with other systems located in their surroundings. The aquifer system of Doñana (southwest Spain) has been studied over recent decades from a hydrogeological point of view, although nothing is known about its biological or ecological aspects. In order to describe the general characteristics of its microbial communities, bacterial abundance, cell biomass, bacterial biomass and microbial activities of functional groups were investigated by sampling, over a 2-year period, 13 wells located in the vicinity of four very productive shallow lakes in the most superficial part of this coastal, sandy aquifer system. Multivariate analysis of variance (MANOVA) indicated differences in abundance and biomass variables among sampling locations, seasons and sampling locations × seasons. Principal component analysis showed that temperature and dissolved oxygen appeared to be the most important factors controlling the temporal variability of microbial communities. Hydrological connectivity between surface water and groundwater was important in the control of the spatiotemporal distribution of microbial communities. Due to this hydrological connection, the aquifer system and the wetlands constitute a unique entity, a unique ecosystem, called the “hydroecosystem”, where microbial communities could play a central ecological role.     

The Bransfield current system

We use hydrographic data collected during two interdisciplinary cruises, CIEMAR and BREDDIES, to describe the mesoscale variability observed in the Central Basin of the Bransfield Strait (Antarctica). The main mesoscale feature is the Bransfield Front and the related Bransfield Current, which flows northeastward along the South Shetland Island Slope. A laboratory model suggests that this current behaves as a gravity current driven by the local rotation rate and the density differences between the Transitional Zonal Water with Bellingshausen influence (TBW) and the Transitional Zonal Water with Weddell Sea influence (TWW). Below the Bransfield Front we observe a narrow (10 km wide) tongue of Circumpolar Deep Water all along the South Shetland Islands Slope. At the surface, the convergence of TBW and TWW leads to a shallow baroclinic front close to the Antarctic Peninsula (hereafter Peninsula Front). Between the Bransfield Front and the Peninsula Front we observe a system of TBW anticyclonic eddies, with diameters about 20 km that can reach 300 m deep. This eddy system could be originated by instabilities of the Bransfield Current. The Bransfield Current, the anticyclonic eddy system, the Peninsula Front and the tongue of Circumpolar Deep Water, are the dynamically connected components of the Bransfield Current System.     

Wave drag in the planetary boundary layer over complex terrain

The concepts of mountain-induced wave drag are applied to the smaller scale problem of the boundary layer over complex terrain. It is found that the Reynolds stress and surface drag caused by surface-generated waves can be at least as large as those conventionally associated with turbulence. Conditions in which wave effects are important are identified.ATDD Contribution No. 88/5.     

Long-range dependence in the time series of Taiţa River discharges

ABSTRACT

The aim of this article is to offer an insight into the hydrology of southeast Romanian catchments, which have not been studied systematically. The complex behaviour of the Tai?a, one of the most important rivers situated in the northern part of Dobrogea, is demonstrated. Long-range dependence (LRD) in the time series of its streamflow, including the presence of trends, is supported by an estimated Hurst exponent of approximately 0.8, as well as statistical tests.

Editor D. Koutsoyiannis; GUEST editor S. Weijs     

Variations in cereal crop phenology in Spain over the last twenty-six years (1986–2012)

Over recent years, the Iberian Peninsula has witnessed an increase both in temperature and in rainfall intensity, especially in the Mediterranean climate area. Plant phenology is modulated by climate, and closely governed by water availability and air temperature. Over the period 1986–2012, the effects of climate change on phenology were analyzed in five crops at 26 sites growing in Spain (southern Europe): oats, wheat, rye, barley and maize. The phenophases studied were: sowing date, emergence, flag leaf sheath swollen, flowering, seed ripening and harvest. Trends in phenological response over time were detected using linear regression. Trends in air temperature and rainfall over the period prior to each phenophase were also charted. Correlations between phenological features, biogeographical area and weather trends were examined using a Generalized Lineal Mixed Model approach. A generalized advance in most winter-cereal phenophases was observed, mainly during the spring. Trend patterns differed between species and phenophases. The most noticeable advance in spring phenology was recorded for wheat and oats, the “Flag leaf sheath swollen” and “Flowering date” phenophases being brought forward by around 3 days/year and 1 day/year, respectively. Temperature changes during the period prior to phenophase onset were identified as the cause of these phenological trends. Climate changes are clearly prompting variations in cereal crop phenology; their consequences could be even more marked if climate change persists into the next century. Changes in phenology could in turn impact crop yield; fortunately, human intervention in crop systems is likely to minimize the negative impact.     

Aluminum coprecipitates with Fe (hydr)oxides: Does isomorphous substitution of Al for Fe in goethite occur?

Iron (hydr)oxides are common in natural environments and typically contain large amounts of impurities, presumably the result of coprecipitation processes. Coprecipitation of Al with Fe (hydr)oxides occurs, for example, during alternating reduction-oxidation cycles that promote dissolution of Fe from Fe-containing phases and its re-precipitation as Fe-Al (hydr)oxides. We used chemical and spectroscopic analyses to study the formation and transformation of Al coprecipitates with Fe (hydr)oxides. In addition, periodic density functional theory (DFT) computations were performed to assess the structural and energetic effects of isolated or clustered Al atoms at 8 and 25 mol% Al substitution in the goethite structure. Coprecipitates were synthesized by raising the pH of dilute homogeneous solutions containing a range of Fe and Al concentrations (100% Fe to 100% Al) to 5. The formation of ferrihydrite in initial suspensions with ?20 mol% Al, and of ferrihydrite and gibbsite in initial suspensions with ?25 mol% Al was confirmed by infrared spectroscopic and synchrotron-based X-ray diffraction analyses. While base titrations showed a buffer region that corresponded to the hydrolysis of Fe in initial solutions with ?25 mol% Al, all of the Al present in these solutions was retained by the solid phases at pH 5, thus indicating Al coprecipitation with the primary Fe hydroxide precipitate. In contrast, two buffer regions were observed in solutions with ?30 mol% Al (at pH ∼2.25 for Fe³⁺ and at pH ∼4 for Al³⁺), suggesting the formation of Fe and Al (hydr)oxides as two separate phases. The Al content of initial coprecipitates influenced the extent of ferrihydrite transformation and of its transformation products as indicated by the presence of goethite, hematite and/or ferrihydrite in aged suspensions. DFT experiments showed that: (i) optimized unit cell parameters for Al-substituted goethites (8 and 25 mol% Al) in clustered arrangement (i.e., the formation of diaspore-like clusters) were in good agreement with available experimental data whereas optimized unit cell parameters for isolated Al atoms were not, and (ii) Al-substituted goethites with Al in diaspore-like clusters resulted in more energetically favored structures. Combined experimental and DFT results are consistent with the coprecipitation of Al with Fe (hydr)oxides and with the formation of diaspore-like clusters, whereas DFT results suggest isomorphous Al for Fe substitution within goethite is unlikely at ?8 mol% Al substitution.