Asia-Pacific mussel watch: monitoring contamination of persistent organochlorine compounds in coastal waters of Asian countries

Contamination of persistent organochlorines (OCs) such as PCBs (polychlorinated biphenyls), DDT and its metabolites (DDTs), HCH (hexachlorocyclohexane) isomers (HCHs), chlordane compounds (CHLs), and HCB (hexachlorobenzene) were examined in mussels collected from coastal waters of Asian countries such as Cambodia, China, Hong Kong, India, Indonesia, Japan, Korea, Malaysia, Philippines, Far East Russia, Singapore, and Vietnam in 1994, 1997, 1998, 1999, and 2001 to elucidate the contamination status, distribution and possible pollution sources and to assess the risks on aquatic organisms and human. OCs were detected in all mussels collected from all the sampling sites investigated. Considerable residue levels of p,p(')-DDT and alpha-HCH were found in mussels and the concentrations of DDTs and HCHs found in mussels from Asian developing countries were higher than those in developed nations suggesting present usage of DDTs and HCHs along the coastal waters of Asian developing countries. On the other hand, lower concentrations of PCBs detected in mussels from Asian developing countries than those in developed countries indicate that PCBs contamination in mussels is strongly related to industrial and activities. To our knowledge, this is a first comprehensive report on monitoring OCs pollution in the Asia-Pacific region.     

Relationships between tissue concentrations of chlorinated hydrocarbons (polychlorinated biphenyls and chlorinated pesticides) and antioxidative responses of marine mussels,Perna viridis

Marine mussels, Perna viridis, were transplanted from a reference site to various polluted sites around Hong Kong. After 30 d of exposure, antioxidative responses in the gills and hepatopancreas and tissue concentrations of chlorinated hydrocarbons [polychlorinated biphenyls (PCBs) and chlorinated pesticides (CPs)] were determined for individual mussels. Glutathione S transferase (GST) and glutathione (GSH) were positively correlated with tissue PCB concentrations. Only one of the enzymatic antioxidants, glutathione peroxidase (GPx), showed significant response to tissue PCB. No significant correlation was found between tissue concentrations of chlorinated hydrocarbons and other enzymatic antioxidants (superoxide dismutase (SOD), catalase (CAT), glutathione reductase (GR) and NADPH DT-diaphorase (DT-d). Oxidative stress, measured as thiobarbituric acid reactive substances, was correlated with chlorinated pesticide concentrations in tissues. This study demonstrated a correlation between GST/GSH and chlorinated hydrocarbons. The apparent lack of correlation between trace organic pollutants and some of the enzymatic antioxidants may be due to the inhibitory effects caused by these chemicals. The above results suggest that more investigations are needed before these enzymes can be used as biomarkers.     

Regulating public space on the beachfronts of Rio de Janeiro

Despite the fortification of buildings, streets, and public squares, Rio de Janeiro's beaches remain widely regarded as democratic spaces of social diversity and accessibility. Our study revisits the question of Rio's “democratic” beachfronts, based on local interviews, field observations, official reports, and newspaper accounts. We focus on historical and contemporary perceptions of planning, privatization, and public-order programs on the city's southern seaside. Institutional discourses have justified increasing regulation to combat threats of disorder and insecurity. While residents value the relative openness of beachfronts, they also acknowledge issues of safety, social segmentation, and subtle forms of bias. The public generally applauds recent “Shock of Order” policing and commercial revitalization, although critics lament the loss of traditional freedoms for informal beach vendors and casual sports. These paradoxes highlight enduring tensions between social order and hierarchy on one hand, and democratic rights and equality on the other.     

根据地震面波衰减讨论大陆地壳与上地幔的滞弹性结构和演化

上地壳和上地幔剪切波固有品质因子Ｑμ的区域性变化是显著的。在古老而稳固的克拉通中的值比构造活动区中的值在两个深度范围都大一个或一个以上的量级。Ｑμ依赖于频率,至少在１Ｈｚ附近是如此,而这种频率相关在上地壳也有区域性变化。它在构造活动区较低而在稳定区较高。由于Ｑμ在各地区有大的变化,对上地壳的Ｑμ和由Ｌｇ尾波（ＱＬｇ＾ｃ）估计得到的Ｑ绘制区域性变化图是容易做到的,尽管这两种方法都可能有很大的不确定性     

厄尔尼诺期间热带温室效应的变化

利用实测晴空射出长波辐射和海表温度研究了１９８５年前期冷拉尼娜到１９８７年晚期厄尔尼诺期间热带温室效应的变化情况。尽管从冷到暖的状态变化中，逐月资料的比较可能得出温室罩作用在减弱，但从４年的观测记录整体考虑，热带平均温室罩有２Ｗ／ｍ２的明显增加，同时热带平均海表温度增温０．４Ｋ。将这种实际观测到的增加与ＧＣＭ模拟的ＥＮＳＯ期间晴空温室效应的变化进行了比较。在ＥＮＳＯ期间，很明显与ＳＳＴ的重新分布有关的动力变化叠加在ＳＳＴ驱动的温室罩变化之上。若能保证ＧＣＭ具有预测温室罩动力和热力变化的能力，那么，ＧＣＭ模拟也能成功地再现这种特征。     

Field validation of antioxidant enzyme biomarkers in mussels (Perna viridis) and clams (Ruditapes philippinarum) transplanted in Hong Kong coastal waters

Green-lipped mussels, Perna viridis, and Manila clams, Ruditapes philippinarum were sourced from “clean” sites in the Hong Kong region, depurated in a laboratory using uncontaminated filtered seawater for 8 days, and transplanted to a suspected gradient of chemically polluted sites in Hong Kong. After 14- and 28-days of field exposure, several antioxidant parameters including glutathione S transferase (GST), catalase (CAT), glutathione peroxidase (GPx), and glutathione (GSH) were quantified in gill and hepatopancreas tissues. Whole body tissue concentrations of polycyclic aromatic hydrocarbons (PAHs), petroleum hydrocarbons (PHCs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCs) were determined in pooled site samples. Chemical analyses indicated that: (a) clams had higher levels of PAHs, PHCs, DDTs and PCBs, whereas mussels had higher hexachlorocyclohexane (HCHs) and there was no difference between species for dieldrin and remaining OCs; (b) Kat O should not be continued as a “clean” reference site for Hong Kong, because of the levels of contaminants measured and (c) PAH concentrations in the current survey were similar to those previously measured. Toxicological conclusions were: (a) antioxidant responses were different between species; (b) CAT and GST have highest utility in clams for field use in Hong Kong, whereas CAT in both gill and hepatopancreas tissue showed most potential in mussels; (c) significant induction of antioxidant responses over day 0 (excluding GPx in both tissues, and GST in mussel hepatic tissue); (d) groups of contaminants do not consistently induce antioxidant responses and (e) organochlorines and PCBs correlated significantly with CAT and GST in clam hepatopancreas and with CAT in mussel gill and hepatic tissue. Multivariate statistical techniques indicated little relationship between the site patterns for antioxidant responses and the contaminant gradients identified in body burden analysis.     

An Asian quandary: where have all of the PBDEs gone?

Polybrominated diphenyl ethers (PBDEs) are widely used fire retardant compounds which, like polychlorinated biphenyls (PCBs), have become ubiquitous in environmental media. Time trend analyses of PBDE levels in sediments and biota generally show an increasing trend. The lower (tetra- and penta-) PBDEs accumulate and predominate in biota, whilst the higher congeners (deca-) are prevalent in aquatic environments and sediments. PBDEs also biomagnify, with highest concentrations of the lower brominated congeners being seen in top predators including birds, marine mammals and humans. Toxicological studies of PBDEs have been limited, although effects mediated via the thyroid gland may be extremely important. Disturbingly, PBDEs may be sequestering in certain Asian environments to a higher degree than in other parts of the world, due to the unregulated disposal of computers and electronic equipment. However, this potential problem remains poorly investigated, to date.