The Ediacaran radiogenic Sr isotope excursion in the Doushantuo Formation in the Three Gorges area,South China

The Ediacaran period was one of the most important times for the evolution of life. However, the scarcity of well-preserved outcrops of Ediacaran rocks still leaves ambiguity in decoding ambient surface environmental changes and biological evolution.The Ediacaran strata in South China are almost continuously exposed, comprise mainly carbonate rocks with subordinate black shales and sandstones, and they contain many fossils, suitable for study of environmental and biological changes in the Ediacaran. We conducted drilling through the Doushantuo Fm at four sites in the Three Gorges area to obtain continuous, fresh samples without surface alteration and oxidation. We analyzed ⁸⁷Sr/⁸⁶Sr and ⁸⁸Sr/⁸⁶Sr ratios of the fresh carbonate rocks, selected on the basis of microscopic observations and the geochemical signatures of Sr contents, Mn/Sr and Rb/Sr ratios, and δ¹⁸O values, with a multiple collector-inductively coupled plasma-mass spectrometer (MC-ICP-MS).The chemostratigraphy of the ⁸⁷Sr/⁸⁶Sr ratios of the drilled samples displays a smooth curve and two large positive shifts during Ediacaran time. The combination of the detailed chemostratigraphies of δ¹³C, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr values and Mn and Fe contents enables us to decode the surface environmental changes and their causes in the Ediacaran. The first large positive excursion of ⁸⁷Sr/⁸⁶Sr occurred together with negative δ¹³C and positive δ¹⁸O excursions. The higher ⁸⁷Sr/⁸⁶Sr values indicate an enhancement of continental weathering, whereas the positive δ¹⁸O excursion suggests global cooling. Global regression due to global cooling enhanced the oxidative decay of exposed marine organic sediments and continental weathering. Accelerated influx of nutrients promoted primary productivity, resulting in oxidation of dissolved organic carbon (DOC), whereas active sulfate reduction due to a higher sulfate influx from the continents caused remineralization of the large DOC, both of which caused a negative δ¹³C anomaly. The 580 Ma Gaskiers glaciation accounts for the close correlation among the positive ⁸⁷Sr/⁸⁶Sr, negative δ¹³C and positive δ¹⁸O excursions.The second large positive shift of ⁸⁷Sr/⁸⁶Sr firstly accompanied a positive δ¹³C excursion, and continued through the Shuram δ¹³C negative excursion. The positive correlation of δ¹³C and ⁸⁷Sr/⁸⁶Sr values is consistent with an enhanced continental weathering rate due to continental collisions that built Trans-Gondwana mountain chains, and with a higher primary activity due to the enhancement of continental weathering and consequent higher nutrient contents in seawater. The accompanied increase in Mn and Fe contents implies a gradual decline of the seawater oxygen content due to more active aerobic respiration and oxidation of reductive materials flowing in the oceans. In the Shuram excursion, higher ⁸⁷Sr/⁸⁶Sr values and a transition from increase to decrease in Mn and Fe contents were accompanied by the large negative δ¹³C excursion. The higher ⁸⁷Sr/⁸⁶Sr values are the first compelling evidence for enhanced continental weathering, which was responsible for the large δ¹³C anomaly through the remineralization of the DOC by more active sulfate reduction due to a higher sulfate influx. Higher Mn and Fe contents in the early and middle stages of the excursion suggest a decline in the oxygen content of seawater due to oxidative decay of the DOC, whereas in the late stages the decrease in Mn and Fe contents is consistent with oceanic oxygenation.The emergence of Ediacara biota after the Gaskiers glaciation and the prosperity of the latest Ediacaran is concomitant with the formation of more radiogenic seawater with high ⁸⁷Sr/⁸⁶Sr values, suggesting that enhanced continental weathering, and the consequent higher influx of nutrients, played an important role in biological evolution.     

Calcite U–Pb age of the Cretaceous vertebrate‐bearing Bayn Shire Formation in the Eastern Gobi Desert of Mongolia: Usefulness of caliche for age determination

To verify the usefulness of calcite U–Pb measurement for vertebrate‐bearing strata in the Eastern Gobi, Mongolia, we performed laser ablation‐inductively coupled plasma‐mass spectrometry calcite U–Pb and trace element analyses of three caliche (calcrete) of the Bayn Shire Formation. The trace element analysis demonstrates high concentration of U in the calcites. Two meaningful calcite U–Pb ages were obtained; 95.9 ± 6.0 and 89.6 ± 4.0 Ma, which are consistent with published ages from the Bayn Shire Formation. Our results demonstrate that the calcite U–Pb method can be powerful tool for age determination of vertebrate‐bearing strata in the Gobi that do not contain index fossils or beds, but do contain caliches. This would make it possible for a comparison of biostratigraphy between the Gobi and other areas yielding abundant vertebrate fossils in Asia, North America and Europe, based on chronological data.     

Origin of sapphirine-bearing garnet-orthopyroxene granulites: possible hydrothermally altered ocean floor

Sapphirine is a metamorphic mineral that forms in the deep crust in rocks with distinctive bulk compositions, in particular high concentrations of Mg and Al. This study investigates a thin, discontinuous layer of sapphirine-bearing garnet-orthopyroxene (SGO) granulite within a Palaeoproterozoic mafic granulite together with metamorphosed mafic and ultramafic rocks, micaceous rocks rich in magnetite and pyrite, and marble. All of these rocks occur within a low-strain zone in the Lewisian complex of South Harris, NW Scotland. Data on mineral compositions and major, trace, and rare earth element (REE) patterns provide evidence for the origin of the precursor of the SGO granulite. The host mafic granulite has a trace element signature and REE pattern comparable with that of E-type MORB. The chemical abundances of Nb, Ta, La, Ce, Nd, Zr, Hf, Ti, and V in the SGO granulite, except for one sample that records total element loss, are similar to those of the host mafic granulite; however, in terms of whole-rock element abundances, the former is relatively enriched in MgO and depleted in CaO, Na₂O, MnO, Sr, and Eu. Elements within the SGO granulite that were apparently unaffected by hydrothermal alteration—V, Y, Zr, and Cr—are within the range of values observed in the host mafic granulite. Sm–Nd whole-rock isotope systematics suggest that both the host mafic granulite and SGO granulite were metamorphosed at 1.9 Ga, and the Nd initial ratio is consistent with a MORB source at that time. There is no significant difference in the Nd values of the two rock types, suggesting that they originally belonged to the same protolith. Chemical trends within a narrow zone between the SGO and host rock granulite suggest that the former was derived from a basaltic precursor of the latter by a process of infiltration metasomatism, comparable with the chemical exchange that takes place when hydrothermal fluids in present-day oceanic crust pass through vents in a “recharge zone.” The geological and chemical relations observed in the South Harris rocks are consistent with the following model: hydrothermally altered oceanic basaltic crust was trapped in an accretionary wedge and subducted, followed by granulite-facies metamorphism in a deep continental environment during arc–continent collision. This is the first report of hydrothermally altered oceanic crust that was converted to sapphirine-bearing granulite deep in the continental crust.     

End-Permian to mid-Triassic termination of the accretionary processes of the southern Altaids: implications for the geodynamic evolution,Phanerozoic continental growth,and metallogeny of Central Asia

The Altaids is one of the largest accretionary orogenic collages in the world with the highest rate of Phanerozoic continental growth and significant metallogenic importance. It is widely accepted that subduction-related orogenesis of the Altaids started in the late Precambrian and gradually migrated southward (present coordinates). However, it is uncertain when and how the building of the Altaids was finally completed. Based on structural geology, geochemical, geochronological, and paleomagnetic data, this paper presents late Paleozoic to early Mesozoic accretionary tectonics of two key areas, North Xinjiang in the west and Inner Mongolia in the east, together with neighboring Mongolia. The late Paleozoic tectonics of North Xinjiang and adjacent areas were characterized by continuous southward accretion along the wide southern active margin of Siberia and its final amalgamation with the passive margin of Tarim, which may have lasted to the end-Permian to early/mid-Triassic. In contrast, in Inner Mongolia and adjacent areas two wide accretionary wedges developed along the southern active margin of Siberia and the northern active margin of the North China craton, which may have lasted to the mid-Triassic. The final products of the long-lived accretionary processes in the southern Altaids include late Paleozoic to Permian arcs, late Paleozoic to mid-Triassic accretionary wedges composed of radiolarian cherts, pillow lavas, and ophiolitic fragments, and high-pressure/ultrahigh-pressure metamorphic rocks. Permian Alaskan-type zoned mafic-ultramafic complexes intruded along some major faults of the Tien Shan. We define a new Tarim suture zone immediately north of the Tarim craton that is probably now buried below the Tien Shan as a result of northward subduction of the Tarim block in the Cenozoic. The docking of the Tarim and North China cratons against the southern active margin of Siberia in the end-Permian to mid-Triassic resulted in the final closure of the Paleoasian Ocean and terminated the accretionary orogenesis of the southern Altaids in this part of Central Asia. This complex geodynamic evolution led to formation of giant metal deposits in Central Asia and to substantial continental growth.     

Early Cretaceous wedge extrusion in the Indo-Burma Range accretionary complex: implications for the Mesozoic subduction of Neotethys in SE Asia

International Journal of Earth Sciences - The Indo-Burma Range (IBR) of Myanmar, the eastern extension of the Yarlung-Tsangpo Neotethyan belt of Tibet in China, contains mélanges with...     

Geochemistry of mylonitic gneisses from the Cycladic Basement Unit (Paros and Serifos,Aegean Sea): implications for protoliths of the high-grade gneisses

International Journal of Earth Sciences - The nature of the protolith(s) of high-grade gneisses from the Aegean Cycladic Basement Unit of the islands of Paros and Serifos is investigated using...     

Subaqueous early eruptive phase of the late Aptian Rajmahal volcanism,India: Evidence from volcaniclastic rocks,bentonite, black shales,and oolite

The late Aptian(118-115 Ma) continental flood basalts of the Rajmahal Volcanic Province(RVP) are part of the Kerguelen Large Igneous Province,and constitute the uppermost part of the Gondwana Supergroup on the eastern Indian shield margin.The lower one-third of the Rajmahal volcanic succession contains thin layers of plant fossil-rich inter-trappean sedimentary rocks with pyroclasts,bentonite,grey and black shale/mudstone and oolite,whereas the upper two-thirds consist of sub-aerial fine-grained aphyric basalts with no inter-trappean material.At the eastern margin and the north-central sector of the RVP,the volcanics in the lower part include rhyolites and dacites overlain by enstatite-bearing basalts and enstatite-andesites.The pyroclastic rocks are largely felsic in composition,and comprise ignimbrite as well as coarse-grained tuff with lithic clasts,and tuff breccia with bombs,lapilli and ash that indicate explosive eruption of viscous rhyolitic magma.The rhyolites/dacites(68 wt.%) are separated from the andesites( 60 wt.%) by a gap in silica content indicating their formation through upper crustal anatexis with only heat supplied by the basaltic magma.On the other hand,partially melted siltstone xenoliths in enstatite-bearing basalts suggest that the enstatite-andesites originated through mixing of the upper crust with basaltic magma,crystallizing orthopyroxene at a pressure-temperature of ~3 kb/1150℃.In contrast,the northwestern sector of the RVP is devoid of felsic-intermediate rocks,and the volcaniclastic rocks are predominantly mafic(basaltic) in composition.Here,the presence of fine-grained tuffs,tuff breccia containing sideromelane shards and quenched texture,welded tuff breccia,peperite,shale/mudstone and oolite substantiates a subaqueous environment.Based on these observations,we conclude that the early phase of Rajmahal volcanism occurred under predominantly subaqueous conditions.The presence of grey and black shale/mudstone in the lower one-third of the succession across the entire Rajmahal basin provides unequivocal evidence of a shallow-marine continental shelf-type environment.Alignment of the Rajmahal eruptive centers with a major N—S mid-Neoproterozoic lineament and the presence of a gravity high on the RVP suggest a tectonic control for the eruption of melts associated with the Kerguelen plume that was active in a post-Gondwana rift between India and Australia-Antarctica.     

Carboniferous rifted arcs leading to an archipelago of multiple arcs in the Beishan–Tianshan orogenic collages (NW China)

International Journal of Earth Sciences - The Beishan and East Tianshan Orogenic Collages in the southernmost Central Asian Orogenic Belt (CAOB) record the final stages of evolution of the...