Crystallinity and metamorphism of illite from Triassic strata in Henan County of Qinghai Province

In order to verify the Triassic stratum metamorphism in this area, the crystallinity of illite in mudstone (shale) of Triassic stratum was analyzed and tested during the 1:50 000 regional mineral geological survey (I47E007023, I47E008023, I47E009023,1I47E009024)in Tuoyema area of Henan Mongolian Autonomous County in Qinghai Province. According to the experimental results of 30 samples, the crystallinity index of Triassic mudstone (shale) illite Kübler in Zongwulong-Zeku stratigraphic division in the north is 0.312-0.537, and the cell parameter b₀ is 0.898-0.903 2 nm. The metamorphic temperature is less than 350 ℃, with the grape-chlorite and zeolite facies. The crystallinity index of Triassic mudstone (shale) illite Kübler in the western inclined mountain stratigraphic division in the south is 0.21-0.318, and the b₀ value is 0.898 1-0.901 4 nm. The metamorphic temperature is mainly between 200 and 350 ℃, with the local temperature above 350 ℃ and grape-chlorite and greenschist facies. It is considered that the regional metamorphism grade in this area is very low or has no regional metamorphism. The metamorphism degree of the western dipping mountain stratum in the south is slightly higher than that of Zongwulong-Zeku stratum in the north. The measured metamorphic facies belts are not consistent with the previous thought, that is "regional low temperature dynamic metamorphism and low greenschist facies metamorphic belts", and the degree of metamorphism is relatively lower. It is confirmed that there is no large area regional metamorphism in the Triassic strata of Henan County in Qinghai Province, but only very low-level regional metamorphism.     

A New Intergrowth Consisting of FeO and SiO_2 Phases from Lower Mantle

1. IntroductionIn order to confirm the presence or absence of diamonds in the Luobusa ophiolitic chromitite in Tibet, about 1500 kg chromitite sample was collected for separating its associated minerals, in which diamond, moissanite, octahedral pseudomorphic serpentine and chlorite, native silicon, native chromium, some alloys and other minerals were found. A wide variety of minerals, including about 70-80 types of mantle minerals from the Luobusa ophiolite, were identified by energy dispersi…     

记录地幔中存在氧元素的自然铁-方铁矿组合

笔者在西藏蛇绿岩的铬铁矿石中发现了十分复杂的地幔矿物群,其中包括自然铁-方铁矿的共生组合,它们被认为是外地核和下地幔的物质通过地幔柱作用携带到上地幔的。新发现的自然铁-方铁矿组合表明,外地核液态铁溶解有部分氧,当液态铁由外地核上升时,氧从液态铁中析出并呈不混溶状态存在于液态铁中。随着乳滴状自然铁球粒向上运移,在降压条件下液态铁和氧元素发生化学反应生成方铁矿(包括NI AS结构)。当氧耗尽时,在方铁矿中遗留下氧耗尽的空洞,形成眼球状构造。因此,眼球构造可能是外地核向地幔释放氧,下地幔内存在氧元素的历史记录。     

韩城台倾斜异常特征及其与地震关系分析

通过对陕西韩城台倾斜资料的整理、分析与研究,指出了存在的干扰源;并在排除干扰的基础上采用21点斯宾塞平滑滤波方法探讨该台资料变化与周边地震活动的关系。     

南海北部神狐海域细粒储层矿物组分对天然气水合物储集赋存的影响

为了探明矿物类型对于天然气水合物成藏的影响,笔者等利用南海北部神狐海域W07站位样品及其水合物饱和度数据,进行XRD全岩和黏土矿物测试分析、比表面积分析以及束缚水能力综合分析。结果表明,海床下110~127 m（即110~127 mbsf,meters below sea floor, 海床以下深度）为水合物储层段,海床下127~156 m为非水合物储层段。通过XRD分析可知,高石英及长石含量,低伊蒙混层含量的层段,比表面积与束缚水能力较低,说明其具有相对较好的孔渗条件,为水合物的运移与储集提供了良好的空间条件,因此形成水合物储层段;而在高伊蒙混层的层段中,比表面积较大,束缚水能力较强,其对甲烷气体及流体的吸附和束缚能力较强,对水合物成藏起到潜在的封隔作用,成为非储层段,储层与非储层段纵向叠置序列有利于优质水合物储层的形成。本次研究总结了矿物组分与优质水合物储层之间的关系,并揭示两者存在的潜在成因联系,以期丰富水合物富集成藏的基础理论,对未来南海北部天然气水合物的商业化开发提供支持。     

贵州金沙制陶用粘土岩矿床特征及开发利用应用前景

由于制陶原料近于枯竭,寻找和开发新的制陶原料资源基地十分必要。因此,本次在金沙县境内开展寻找制陶用矿产资源普查工作。经样品测试分析、制陶工业试验(小试),基本确定了下石炭统九架炉组中部分粘土岩可作为制陶用矿产资源。通过普查工作,初步查明了普查区矿石物质组分、赋存状态、矿石类型、矿石质量及其分布规律;试制的陶器样品化学特征、性能均能符合相关标准要求,陶器制作工艺简单,其造型、外观颜色也符合当前社会对陶器审美要求。通过本次工作提高了含铝土矿九架炉组的综合利用价值,亦对我省其它含铝土矿地层的综合利用具有重要指导意义,并对制陶用粘土岩的利用前景进行分析研究。     

松辽盆地营城组火山岩成岩作用类型、特征及其对储层物性的影响

通过野外剖面观察、钻井岩心描述、薄片鉴定和扫描电镜分析,松辽盆地营城组火山岩的成岩作用阶段分为早期和晚期。早期成岩作用类型有挥发分逸出、熔蚀作用、等容冷凝结晶、准同生期热液沉淀结晶、熔结作用、冷凝收缩、分熔冷凝结晶和早期压实胶结作用;晚期成岩作用类型为充填作用、脱玻化作用、交代作用、机械压实压溶作用、胶结作用和溶解作用。早期成岩作用主要影响原生孔隙的发育,晚期成岩作用影响次生孔隙的发育。准同生期热液沉淀结晶、早期压实胶结作用、充填作用、机械压实压溶作用和胶结作用是使松辽盆地营城组火山岩储层物性降低的主要成岩作用;挥发分逸出、等容冷凝结晶、冷凝收缩和溶解作用是产生孔隙空间使储层物性变好的主要成岩作用。     

东昆仑河尔格头地区晚三叠世花岗岩成因：年代学、地球化学及Sr- Nd- Pb同位素约束

河尔格头地区位于东昆仑造山带西段,发育大量花岗岩岩石组合,对该地区晚三叠世花岗岩的研究不仅有助于认识东昆仑造山带印支期构造- 岩浆演化历史,还可为古特提斯洋俯冲及洋盆闭合时限提供约束。本文报道了对河尔格头地区花岗岩的LA- MC- ICP- MS锆石U- Pb定年、地球化学、Sr- Nd- Pb同位素的研究结果,为建立完善的年代学格架和构造演化提供了新资料。本次在河尔格头英云闪长岩中获得了230. 9±0. 7Ma的锆石U- Pb 年龄,结合野外接触关系,可以确定该期花岗岩为晚三叠世岩浆活动的产物。全岩地球化学分析结果显示,河尔格头晚三叠世花岗岩为准铝到弱过铝质岩石,属中- 高钾钙碱性系列,富集轻稀土和Rb、Th等大离子亲石元素,不同程度亏损Nb、Ta、P、Ti等高场强元素,具负铕异常,属I型花岗岩。从Sr- Nd- Pb同位素分析结果可以看出河尔格头晚三叠世花岗岩具有较高的 I Sr 值(0. 705058~0. 707582)和负的ε Nd ( t )值(-2. 05~-5. 14),双阶段模式年龄 t DM2 为1170~1422Ma,表明岩浆主要来源于地壳。经校正后的 ( 206 Pb/ 204 Pb) i 值为18. 37949~18. 58525,( 207 Pb/ 204 Pb) i 值为15. 56543~15. 59755,( 208 Pb/ 204 Pb) i 值为37. 79668~38. 27230,Pb同位素组成图解显示其物质来源与壳幔相互作用有关。综合岩体岩石地球化学特征及前人研究成果,河尔格头地区花岗岩显示板块俯冲阶段的特征,可能为阿尼玛卿洋壳消减过程中的产物,古特提斯洋的闭合时限或可推迟至晚三叠世。     

北山地区辉长岩类的地球化学特征及其深部信息

据稀土元素配分曲线可将北山辉长岩类分为3组,第1组∑REE较大,LREE富集且发生了较大程度的分馏;第2组轻稀土未发生明显的分馏,曲线较为平坦,∑REE较低;第3组LREE亏损,∑REE较低.Nb亏损,指示北山辉长岩类形成于俯冲相关的构造环境,εNd(0)及εNd(t)均大于0,指示来源于亏损型地幔源区.本文认为北山地区辉长岩产出于活动大陆边缘的不同次一级构造环境;原始岩浆在上升途中遭受了陆壳混染;Sm-Nd模式年龄不代表岩石的形成年龄.     

First Record of Petalodus Owen, 1840(Chondrichthyes,Petalodontidae) in the Lower Permian(Cisuralian) of China

The Petalodontiformes are a small intriguing group of Permo–Carboniferous chondrichthyans. Petalodus is the longest known petalodont genus generally considered representative of the order. The first definite fossil record of seven well-preserved Petalodus teeth has been found in the Qianshi limestone in the Lower Permian(Cisuralian) middle–upper Taiyuan Formation in Yangquan City, Shanxi Province, North China. The specimens are characterized by petal-shaped teeth with a spade-like crown, and a long, tongue-shaped root; the crown is circled with a band or cingulum composed of imbricated ridges at the base. All seven teeth are assigned to the species P. ohioenesis because of their vertically narrow cingulum and much longer root. Petalodus is a worldwide genus, with fossil localities mainly concentrated in the Laurussia supercontinent. The occurrence of Petalodus teeth in Yangquan not only is the first fossil record in China, but also only the second record in Asia. The Yangquan fossil site was part of the paleoequatorial North China Craton during the Early Permian, and was isolated from Laurusia and East Gondwana by the Paleo-Tethys Ocean. The successful dispersal of Petalodus from Laurusia to the North China Block along Paleo-Tethys may support the possibility that Petalodus taxa were active free-swimmers rather than bottom dwellers. The new finding increases the petalodont diversity in eastern Asia, and also sheds new light on the distribution and stratigraphic range.