An inventory of factors that affect polysaccharide production by Phaeocystis globosa

Phaeocystis material contains polysaccharides that are built from at least eight different monosaccharides. Differences have been reported between the carbohydrate composition of different Phaeocystis species, and also between samples taken from Phaeocystis globosa blooms in different areas. In order to elucidate factors that could play a role in determining variation in carbohydrate composition and production, a number of Phaeocystis globosa strains were studied under laboratory conditions. Although there was a clear distinction of a northern and a southern cluster in the Phaeocystis globosa strains based on RAPD analysis, the differences in the composition of the mucopolysaccharides were relatively small. The contribution of glucose, however, ranged from 7–85% of total sugars. A strain that was cultured in seawaters of diverse origin produced polysaccharides of a different composition, suggesting the effect of environmental factors. The presence of bacteria affected neither the amount, nor the composition of the carbohydrates that were produced by Phaeocystis globosa. Glucose is part of both the intracellular polysaccharide pool and of the mucopolysaccharides in the colony matrix. Using specific digestion of the intracellular chrysolaminaran by laminarinase, the distribution of polysaccharides over different pools could be assessed. During growth of an axenic, mucus-producing strain, the portion of glucose present as chrysolaminaran appeared to increase. The polyglucose that was not digested by laminarinase remains unidentified. This study shows that environmental factors rather than strain differences determine differences in the sugar composition of Phaeocystis globosa, especially with respect to the glucose content of the material. A difference in the contribution of glucose could be correlated to the portion of cells in the culture that are not in the colonies. Our study emphasises that for studying polysaccharide dynamics in Phaeocystis globosa it is important to be able to discriminate between the different polysaccharide pools. Preliminary results of an enzymatic approach were promising     

Large bio-geographical shifts in the north-eastern Atlantic Ocean: From the subpolar gyre, via plankton, to blue whiting and pilot whales

Pronounced changes in fauna, extending from the English Channel in the south to the Barents Sea in the north-east and off Greenland in the north-west, have occurred in the late 1920s, the late 1960s and again in the late 1990s. We attribute these events to exchanges of subarctic and subtropical water masses in the north-eastern North Atlantic Ocean, associated with changes in the strength and extent of the subpolar gyre. These exchanges lead to variations in the influence exerted by the subarctic or Lusitanian biomes on the intermediate faunistic zone in the north-eastern Atlantic. This strong and persistent bottom-up bio-physical link is demonstrated using a numerical ocean general circulation model and data on four trophically connected levels in the food chain – phytoplankton, zooplankton, blue whiting, and pilot whales. The plankton data give a unique basin-scale depiction of these changes, and a long pilot whale record from the Faroe Islands offers an exceptional temporal perspective over three centuries. Recent advances in simulating the dynamics of the subpolar gyre suggests a potential for predicting the distribution of the main faunistic zones in the north-eastern Atlantic a few years into the future, which might facilitate a more rational management of the commercially important fisheries in this region.     

Further improvements to the higher-order Boussinesq equations: Bragg reflection

Enhancements for the Bragg reflection are introduced for three sets of 2D higher order Boussinesq equations to improve the prediction of the Bragg reflection. The extension of the approach to other sets of Boussinesq equations is discussed. The analytical solutions for the Bragg reflection over an infinite number of sinusoidal bars are derived for these Boussinesq models and compared to the exact theoretical solution in order to determine the optimized values of the parameters in the new enhancement terms. Numerical simulations are also carried out for the Bragg reflection over a finite number of sand bars and compared with corresponding measurements to validate the enhancements. Comparisons with other forms of Boussinesq models are made to discuss the applicability of different forms of Boussinesq models to rapidly varying topography with sand bars. The effects of the mild slope assumption on the prediction of Bragg reflection and of wave reflection on a plane self are also discussed.     

The Hormuz Strait Dam Macroproject—21st Century Electricity Development Infrastructure Node (EDIN)?

ABSTRACT

Ocean gulfs offer a means of artificially creating a depression, which can be used for a regionally significant hydroelectric macroproject. We examine here the case for a dam at the Strait of Hormuz that blocks a large gulf situated in an arid region. A 35 m evaporation of this concentration basin will reduce its watery surface area by ～53% and allow generation of ～2.050 MW (or possibly ～2.500 MW) of electricity. Our conclusion is that the proposed Electricity Development Infrastructure Node (EDIN) is a feasible and desirable macroproject. If the macroproject starts in the near-term future, it would require a significant change in the logistics of oil and gas transport from this region. Alternatively, it can be considered as an attractive future solution for the energy requirements of the region after exhaustion of its oil and gas reserves.     

Modeling Water and Heat Balance Components for Large Agricultural Region Utilizing Information from Meteorological Satellites

The method has been developed to evaluate water and heat balance components for vegetation covered area of regional scale based on the refined physical-mathematical model of vertical water and heat exchange between land surface and atmosphere (Land Surface Model, LSM) for vegetation season adapted to satellite information on land surface and meteorological conditions. The LSM is accommodated for utilizing satellite-derived estimates of vegetation and meteorological characteristics as model parameters and input variables. Estimates of these characteristics presented as distributions of their values over the study area have been obtained from AVHRR/NOAA, MODIS/EOS Terra and Aqua, SEVIRI/Meteosat-9, -10 data. To build such estimates methods and technologies have been developed and refined using results of thematic processing measurement data from these sensors. Among them the original Multi Threshold Method (MTM) has been developed and tested to calculate daily precipitation sums using rainfall intensity estimates retrieved from AVHRR and SEVIRI data with subsequent replacement of ground-measured rainfall amounts by these daily rainfalls. All technologies have been adapted to the study area with square of 227300 km² being the part of the Central Black Earth Region of European Russia. Developed earlier procedures of utilizing satellitederived estimates of vegetation and meteorological characteristics (including precipitation) in the model have been refined and verified. Final result of modeling is the fields of soil water content, evapotranspiration and other water and heat balance components of the region under study for years 2012–2014 vegetation seasons.     

Seismic refraction studies of the upper igneous crust in the North Atlantic and porosity estimates for Layer 2

A number of unreversed refraction profiles up to 40 km long and with closely spaced shots has been interpreted to provide the structure of oceanic Layer 2. Different velocity/depth models based on a homogeneous layered structure and on a gradient structure have been obtained for each profile. The gradient models are believed to be a better representation of the real earth. They are all remarkably similar with a predominant velocity gradient of 0.85–1.35 km s^?1 km^?1 ending with a slowly downward increasing velocity of about 6 km s^?1 at about 2 km depth. The positive gradient can be reasonably explained by the reduction downwards of bulk porosity, particularly due to the closure of cracks, in a simple two-component, basalt plus voids, model. The model takes account of weathering but not of metamorphism. A theory, based on oversimplified assumptions about the rocks in Layer 2, allows rough estimates of porosity at different depths to be made.     

Hydrogen incorporation into forsterite in Mg2SiO4–K2Mg(CO3)2–H2O and Mg2SiO4–H2O–C at 7.5–14.0 GPa

Experiments on water solubility in forsterite in the systems Mg₂SiO₄–K₂Mg(CO₃)₂–H₂O and Mg₂SiO₄–H₂O–C were conducted at 7.5–14.0 GPa and 1200–1600 °C. The resulting crystals contain 448 to 1480 ppm water, which is 40–70% less than in the forsterite–water system under the same conditions. This can be attributed to lower water activity in the carbonate-bearing melt. The water content of forsterite was found to vary systematically with temperature and pressure. For instance, at 14 GPa in the system forsterite–carbonate–H₂O the H₂O content of forsterite drops from 1140 ppm at 1200 °C to 450 ppm at 1600 °C, and at 8 GPa it remains constant or increases from 550 to 870 ppm at 1300–1600 °C. Preliminary data for D-H-bearing forsterite are reported. Considerable differences were found between IR spectra of D-H- and H-bearing forsterite. The results suggest that CO₂ can significantly affect the width of the olivine-wadsleyite transition, i.e., the 410-km seismic discontinuity, which is a function of the water content of olivine and wadsleyite.     

Illite/smectite transformation in detrital glaucony during burial diagenesis of sandstone: A study from Siri Canyon – Danish North Sea

Detrital glaucony in the Palaeogene glauconitic sandstones in Siri Canyon, Danish North Sea, has been analysed from 15 exploration wells by X‐ray diffraction, electron microprobe and scanning electron microscopy. These sandstones consist of mixed‐layer illite/smectite and have a large variability in chemical composition and structure. In the most shallow wells (ca 1700 m), the glaucony is rich in Fe and consists of mixed‐layer illite/smectite with random‐interstratification (R = 0). In the depth interval from 1700 to 2000 m, the composition changes as Si is incorporated. The structure changes to ordered R = 1. Further increase in burial leads to the loss of Fe. Ordered R = 3 mixed‐layer illite/smectite is recognized from burial depths of 2200 m. The proportion of illite in illite/smectite mixed layers increases only slightly with depth and temperature. Although the structural changes generally are associated with chemical changes, they can also take place isochemically when the detrital glaucony is tightly embedded in earlier cement, which prevented chemical exchange. The glaucony transformation in the Siri Canyon sandstones partly reflects a supply of Si and partly significant loss of Fe. Thus, the glaucony transformation relates to the general diagenesis of the host sandstone. These sandstones are cemented by microquartz at an early stage, followed by precipitation of Fe‐rich grain‐coating berthierine or chlorite.