Composition of brines in halite‐hosted fluid inclusions in the Upper Ordovician,Canning Basin,Western Australia: new data on seawater chemistry

Analyses of primary and early diagenetic fluid inclusions in the halite from the Late Ordovician Mallowa Salt, Canning Basin, Western Australia indicate a Ca‐rich composition and high concentration of parent brines in the basin which were close to sylvite and carnallite precipitation. The salt‐bearing series in the sampled interval was overheated up to 62 °C. The recorded differences in gas compositions result from the input of several gas sources including dispersed organic matter in the salt series and hydrocarbon deposits in the underlying rocks. The high concentration of the brines in fluid inclusions does not allow quantitative reconstruction of the chemical composition of Late Ordovician parent seawater. Using the information from Early Cambrian and Late Silurian basins as a proxy, however, the new data indicate that Late Ordovician seawater was undoubtedly Ca‐rich and, in comparison with modern seawater, had a similar K content, considerably lower Mg content (c. 30%), approximately three times the Ca content and one‐third the SO₄ content.     

Intercomparison of the seasonal cycle of tropical surface stress in 17 AMIP atmospheric general circulation models

 The mean state of the tropical atmosphere is important as the nature of the coupling between the ocean and the atmosphere depends nonlinearly on the basic state of the coupled system. The simulation of the annual cycle of the tropical surface wind stress by 17 atmospheric general circulation models (AGCMs) is examined and intercompared. The models considered were part of the Atmospheric Model Intercomparison Project (AMIP) and were integrated with observed sea surface temperature (SST) for the decade 1979–1988. Several measures have been devised to intercompare the performance of the 17 models on global tropical as well as regional scales. Within the limits of observational uncertainties, the models under examination simulate realistic tropical area-averaged zonal and meridional annual mean stresses. This is a noteworthy improvement over older generation low resolution models which were noted for their simulation of surface stresses considerably weaker than the observations. The models also simulate realistic magnitudes of the spatial distribution of the annual mean surface stress field and are seen to reproduce realistically its observed spatial pattern. Similar features are observed in the simulations of the annual variance field. The models perform well over almost all the tropical regions apart from a few. Of these, the simulations over Somali are interesting. Over this region, the models are seen to underestimate the annual mean zonal and meridional stresses. There is also wide variance between the different models in simulating these quantities. Large model-to-model variations were also seen in the simulations of the annual mean meridional stress field over equatorial Indian Ocean, south central Pacific, north east Pacific and equatorial eastern Pacific oceans. It is shown that the systematic errors in simulating the surface winds are related to the systematic errors in simulating the Inter-Tropical Convergence Zone (ITCZ) in its location and intensity. Weaker than observed annual mean southwesterlies simulated by most models over Somali is due to weaker than observed southwesterlies during the Northern Hemisphere summer. This is related to the weaker than observed land precipitation simulated by most models during the Northern Hemisphere summer. The diversity in simulation of the surface wind over Somali and equatorial Indian ocean is related to the diversity of AGCMs in simulating the precipitation zones in these regions. Received: 2 August 1996 / Accepted: 7 February 1997     

Radon variations in a Hungarian village

 A steady radon exhalation is assumed in most publications. In a village of North-East Hungary, however, high radon concentrations have been measured, differing strongly in neighbouring houses and varying in time, due to the interplay of geochemical phenomena. Received: 20 November 1995 · Accepted: 18 June 1996     

A technique for calibration of monostatic echosounder systems

A calibration technique has been adapted to render complete system calibrations of high-frequency acoustical instrumentation. This is based on standard targets; specifically, precisely manufactured spheres composed of tungsten carbide with 6% cobalt binder. The use of multiple sphere sizes was found to be advantageous, both as an independent check of the calibrations, and so that resonances in the sphere responses at certain frequencies could be avoided. Complete system gains and beam patterns, which include effects of bandpass filters and finite-pulse lengths, were determined by moving the spheres individually in the transducer far-fields. Use of this procedure ensures control over the acoustical characteristics of transducers, which may change from the time of manufacture and first testing due, for example, to platform mounting. It also provides a direct means of measuring the sampling volume at relatively high and constant signal-to-noise ratios. Implementation of this technique is discussed using a multifrequency sonar system as an example     

The Preboreal climate reversal and a subsequent solar‐forced climate shift

Accurate chronologies are essential for linking palaeoclimate archives. Carbon‐14 wiggle‐match dating was used to produce an accurate chronology for part of an early Holocene peat sequence from the Borchert (The Netherlands). Following the Younger Dryas–Preboreal transition, two climatic shifts could be inferred. Around 11 400 cal. yr BP the expansion of birch (Betula) forest was interrupted by a dry continental phase with dominantly open grassland vegetation, coeval with the PBO (Preboreal Oscillation), as observed in the GRIP ice core. At 11 250 cal. yr BP a sudden shift to a humid climate occurred. This second change appears to be contemporaneous with: (i) a sharp increase of atmospheric ¹⁴C; (ii) a temporary decline of atmospheric CO₂; and (iii) an increase in the GRIP ¹⁰Be flux. The close correspondence with excursions of cosmogenic nuclides points to a decline in solar activity, which may have forced the changes in climate and vegetation at around 11 250 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.     

Geochronological evidence for late‐Grenvillian magmatic and metamorphic events in central Taimyr,northern Siberia*

U–Th–Pb analyses of zircons from six granites and one metasediment collected in the accretionary Central belt of Taimyr, Arctic Siberia, demonstrate that Neoproterozoic (c. 900 Ma) granites intrude late Mesoproterozoic/early Neoproterozoic amphibolite facies metamorphic rocks. This is the first time in the Mamont–Shrenk region that Neoproterozoic ages have been recognized for these lithologies, previously thought to be Archaean/Palaeoproterozoic in age. The Mamont–Shrenk Terrane (MST) represents a Grenvillian age (micro?) continent intercalated with younger Neoproterozoic ophiolites during thrusting and accreted to the northern margin of the Siberian craton sometime before the late Vendian. Basement to the MST may have been derived from the Grenvillian belt of east Greenland. Viable tectonic reconstructions must allow for an active margin along northern Siberia (modern day coordinates) in the middle Neoproterozoic.     

Kinematic wave modelling in water resources: a historical perspective

The history of the kinematic wave theory and its applications in water resources are traced. It is shown that the theory has found its niche in water resources and its applications are so widespread that they may well constitute what may be termed ‘kinematic wave hydrology’. Few theories have been applied in hydrology and water resources as extensively as the kinematic wave theory. This theory, however, is not without limitations and when it is applied they must be so recognized. Copyright © 2001 John Wiley & Sons, Ltd.     

The Leonard Award Address Presented 1996 July 25, Berlin,Germany: The elemental composition of stony cosmic spherules

Abstract— Five hundred stony cosmic spherules collected from deep-sea sediments, polar ice, and the stratosphere have been analyzed for major and some minor element composition. Typical spherules are products of atmospheric melting of millimeter sized and smaller meteoroids. The samples are small and modified by atmospheric entry, but they are an important source of information on the composition of asteroids. The spherules in this study were all analyzed in an identical manner, and they provide a sampling of the solar system's asteroids that is both different and less biased than provided by studies of conventional meteorites. Volatile elements such as Na and S are depleted due to atmospheric heating, while siderophiles are depleted by less understood causes. The refractory nonsiderophile elements appear not to have been significantly disturbed during atmospheric melting and provide important clues on the elemental composition of millimeter sized meteoroids colliding with the Earth. Typical spherules have CM-like composition that is distinctively different than ordinary chondrites and most other meteorite types. We assume that C-type asteroids are the primary origin of spherules with this composition. Type S asteroids should also be an important source of the spherules, and the analysis data provide constraints on their composition. A minor fraction of the spherules are melt products of precursor particles that did not have chondritic elemental compositions. The most common of these are particles that are dominated by olivine. The observed compositions of spherules are inconsistent with the possibility that an appreciable fraction of the spherules are simply chondrules remelted during atmospheric entry.