Underwater sounds near a fuel receiving facility in western Hong Kong: relevance to dolphins

Western Hong Kong is home to two species of marine mammals: Indo-Pacific humpbacked dolphins (Sousa chinensis) and finless porpoises (Neophocaena phocaenoides). Both are threatened in many parts of their range in southeast Asia [for example, International Biological Research Institute Reports 9 (1997), 41; Asian Marine Biology 14 (1997) 111]. In 1998, when the new Hong Kong International Airport opened in western Hong Kong, small tankers (about 100 m long, cargo capacity about 6300 metric tons) began delivering fuel to the Aviation Fuel Receiving Facility (AFRF) just off Sha Chau Island, north of the airport. Calibrated sound recordings were taken over a 4-day period from a quiet, anchored boat at distances 80-2000 m from aviation fuel delivery activities at the AFRF. From the recordings, 143 sections were selected for analysis. Narrowband spectral densities on the sound pressures were computed, and one-third octave band levels were derived for center frequencies from 10 to 16,000 Hz. Broadband levels, viz. 10-20,000 Hz. were also computed. The results showed that the Sha Chau area is normally noisy underwater, with the lowest broadband levels measured corresponding to those expected during a storm at sea (sea state 6). This background noise is believed to come largely from heavy vessel traffic in the Urmston Road to the north and east of Sha Chau and from vessels in the Pearl River Estuary to the West. The sound levels from the AFRF tankers are comparable to the levels measured from similar- and smaller-sized supply vessels supporting offshore oil exploration. The strongest sounds recorded were from a tanker leaving the AFRF at distance 100 m from the hydrophone, for which the one-third octave band level at 100 Hz was 141 dB re 1 microPa (spectrum level 127 dB re 1 microPa2/Hz) and the 10-20,000 Hz broadband level was 146 dB. At distances of 100 m or more and frequencies above 300 Hz, the one-third octave band levels were less than 130 dB (spectrum level 111 dB re 1 microPa2/Hz) and decreased with increasing frequency and distance. At distances greater than about 500 m, AFRF-associated sounds were negligible, masked by the generally high noise level of the area and attenuated by poor transmission in the very shallow water (<10 m). Because it is believed that humpbacked dolphins and finless porpoises are not very sensitive to sounds below 300 Hz, the Airport Authority Hong Kong (AA) stipulated that dedicated terminal vessels not radiate underwater sounds at spectrum levels greater than 110 dB re 1 microPa2/Hz at frequencies above 300 Hz and distances greater than 300 m. The spectrum levels at 300 Hz and higher frequencies of sounds from the tankers arriving, departing, or off-loading at AFRF were less than 110 dB re 1 microPa2/Hz even at distances of 200 m or less. The AA stipulation was met. However, it is presently unknown whether the generally strong noise levels of western Hong Kong inhibit acoustically based feeding and communication, or result in increased stress or permanent shifts in hearing thresholds.     

Hydrosulfide/sulfide complexes of zinc to 250 °C and the thermodynamic properties of sphalerite

The solubility of synthetic ZnS_(cr) was measured at 25–250 °C and P = 150 bars as a function of pH in aqueous sulfide solutions (~ 0.015–0.15 m of total reduced sulfur). The solubility determinations were performed using a Ti flow-through hydrothermal reactor. The solubility of ZnS_(cr) was found to increase slowly with temperature over the whole pH range from 2 to ~ 10. The values of the Zn–S–HS complex stability constant, β, were determined for Zn(HS)₂⁰_(aq), Zn(HS)₃^?, Zn(HS)₄^2?, and ZnS(HS)^?. Based on the experimental values the Ryzhenko–Bryzgalin electrostatic model parameters for these stability constants were calculated, and the ZnS_(cr) solubility and the speciation of Zn in sulfide-containing hydrothermal solutions were evaluated. The most pronounced solubility increase, about 3 log units at m(S_total) = 0.1 for the temperatures from 25 to 250 °C, was found in acidic solutions (pH ~ 3 to 4) in the Zn(HS)₂⁰_(aq) predominance field. In weakly alkaline solutions, where Zn(HS)₃^? and Zn(HS)₄^2? are the dominant Zn–S–HS complexes, the ZnS_(cr) solubility increases by 1 log unit at the same conditions. It was found that ZnS(HS)^? and especially Zn(HS)₄^2? become less important in high temperature solutions. At 25 °C and m(S_total) = 0.1, these species dominate Zn speciation at pH > 7. At 100 °C and m(S_total) = 0.1, the maximum fraction of Zn(HS)₄^2? is only 20% of the total Zn concentration (i.e. at pH_t ~ 7.5), whereas at 350 °C and 3 <pH_t <10, the fraction of Zn(HS)₄^2? and ZnS(HS)^? is less than 0.05% and 2.5% respectively, of the total Zn concentration and Zn(HS)₂⁰ and Zn(HS)₃^? predominate. The measured equilibrium formation constants were combined with the literature data on the stability of Zn–Cl complexes in order to evaluate the concentration and speciation of Zn in chloride solutions. It was found that at acidic pH, and in more saline fluids having total chloride > 0.05 m, Zn–Cl complexes are responsible for hydrothermal Zn transport with no significant contribution of Zn–S–HS complexes. The hydrosulfide/sulfide complexes will play a more important role in lower salinity (< 0.05 m chloride) hydrothermal solutions which are characteristic of many epithermal ore depositing environments. The value of Δ_fG° (β-ZnS_(cr)) = ? 198.6 ± 0.2 kJ/mol at 25 °C was determined via solubility measurements of natural low-iron Santander (Spain) sphalerite.     

High-resolution climate simulation of the last glacial maximum

The climate of the last glacial maximum (LGM) is simulated with a high-resolution atmospheric general circulation model, the NCAR CCM3 at spectral truncation of T170, corresponding to a grid cell size of roughly 75 km. The purpose of the study is to assess whether there are significant benefits from the higher resolution simulation compared to the lower resolution simulation associated with the role of topography. The LGM simulations were forced with modified CLIMAP sea ice distribution and sea surface temperatures (SST) reduced by 1°C, ice sheet topography, reduced CO₂, and 21,000 BP orbital parameters. The high-resolution model captures modern climate reasonably well, in particular the distribution of heavy precipitation in the tropical Pacific. For the ice age case, surface temperature simulated by the high-resolution model agrees better with those of proxy estimates than does the low-resolution model. Despite the fact that tropical SSTs were only 2.1°C less than the control run, there are many lowland tropical land areas 4–6°C colder than present. Comparison of T170 model results with the best constrained proxy temperature estimates (noble gas concentrations in groundwater) now yield no significant differences between model and observations. There are also significant upland temperature changes in the best resolved tropical mountain belt (the Andes). We provisionally attribute this result in part as resulting from decreased lateral mixing between ocean and land in a model with more model grid cells. A longstanding model-data discrepancy therefore appears to be resolved without invoking any unusual model physics. The response of the Asian summer monsoon can also be more clearly linked to local geography in the high-resolution model than in the low-resolution model; this distinction should enable more confident validation of climate proxy data with the high-resolution model. Elsewhere, an inferred salinity increase in the subtropical North Atlantic may have significant implications for ocean circulation changes during the LGM. A large part of the Amazon and Congo Basins are simulated to be substantially drier in the ice age—consistent with many (but not all) paleo data. These results suggest that there are considerable benefits derived from high-resolution model regarding regional climate responses, and that observationalists can now compare their results with models that resolve geography at a resolution comparable to that which the proxy data represent.     

LA-ICP-MS heavy metal analyses of fish scales from sediments of the Oxbow Lake Certak of the Morava River (Czech Republic)

Heavy metal concentrations were studied in the scales of recent and subrecent (2–25 years old) fish buried in the oxbow lake sediments of the Morava River. The samples were taken from two cores up to 4-m deep and analysed using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and an electron microprobe analysis (EMPA). The results were compared with heavy metal concentrations of bulk samples of the embedding sediment. The study has revealed substantial differences in heavy metal contents existing between the recent and subrecent fish scales documenting an extreme rapidity of the diagenesis/fossilization processes. The most apparent features of the early fossilization include the quick loss of the mucous envelope, collagen and magnesium and an enormous increase in the heavy metal concentrations in particular iron, which is connected with a colour change. The variations in heavy metal contents in fish scales within a sample are attributed to variations in heavy metal content in the environment and variable amounts of organic matter in the embedding sediment. In contrast to the contamination of the embedding sediment, no general increase in heavy metal concentrations in fish scales was observed down to the cores. It is inferred that the rapid sorption stabilizes the biologic hydroxyapatite of the fish scales, which thus rapidly attain a thermodynamic equilibrium with the embedding water-saturated sediment. The results show that the processes of sorption, fossilization and stabilization of hydroxyapatite can act very quickly over a time scale of several years and represent thus a great advantage in the preservation of the original signals of the ancient environments.     

Geomorphology of coal seam fires

Coal fires occur in underground natural coal seams, in exposed surface seams, and in coal storage or waste piles. The fires ignite through spontaneous combustion or natural or anthropogenic causes. They are reported from China, India, USA, South Africa, Australia, and Russia, as well as many other countries. Coal fires lead to loss of a valuable resource (coal), the emission of greenhouse-relevant and toxic gases, and vegetation deterioration. A dangerous aspect of the fires is the threat to local mines, industries, and settlements through the volume loss underground. Surface collapse in coal fire areas is common. Thus, coal fires are significantly affecting the evolution of the landscape. Based on more than a decade of experience with in situ mapping of coal fire areas worldwide, a general classification system for coal fires is presented. Furthermore, coal seam fire geomorphology is explained in detail. The major landforms associated with, and induced by, these fires are presented. The landforms include manifestations resulting from bedrock surface fracturing, such as fissures, cracks, funnels, vents, and sponges. Further manifestations resulting from surface bedrock subsidence include sinkholes, trenches, depressions, partial surface subsidence, large surface subsidence, and slides. Additional geomorphologic coal fire manifestations include exposed ash layers, pyrometamorphic rocks, and fumarolic minerals. The origin, evolution, and possible future development of these features are explained, and examples from in situ surveys, as well as from high-resolution satellite data analyses, are presented. The geomorphology of coal fires has not been presented in a systematic manner. Knowledge of coal fire geomorphology enables the detection of underground coal fires based on distinct surface manifestations. Furthermore, it allows judgments about the safety of coal fire-affected terrain. Additionally, geomorphologic features are indicators of the burning stage of fires. Finally, coal fire geomorphology helps to explain landscape features whose occurrence would otherwise not be understood. Although coal fire-induced thermal anomalies and gas release are also indications of coal fire activity, as addressed by many investigators, no assessment is complete without sound geomorphologic mapping of the fire-induced geomorphologic features.     

Long term variations in the mesospheric mean flow observed at Grahamstown (South Africa) and Adelaide (Australia)

The seasonal and interannual behaviour of monthly mean winds at a height of 90 km recorded at Grahamstown (33.3°S, 26.5°E) and Adelaide (34.5°S, 138.5°E) between 1987 and 1994 are compared. The zonal wind is found to be consistently stronger at Grahamstown and is always eastward, whereas at Adelaide it sometimes reverses. Maxima tend to occur near the solstices, the primary maximum during summer at Grahamstown, in agreement with satellite results, and during winter at Adelaide. The meridional wind also tends to be stronger at Grahamstown, but at both stations is predominantly northward with a maximum in summer and generally not as strong as the zonal component. This seasonal behaviour is reasonably well understood in terms of the interaction of the mean flow with gravity waves propagating up from below, with coriolis forces also playing an important role in the case of the meridional wind. Satellite observations do not generally support the idea that longitudinal differences between the stations could be attributed to the presence of a tropospheric/stratospheric stationary wave. It is suggested that these differences are more probably associated with local effects. Interannual zonal wind patterns at the two sites are similar over the summer months but are less well correlated during the rest of the year. The underlying causes of this variability are not well understood but are most probably global in nature, at least during the summer.     

Recruitment patterns of Serpula vermicularis L. (Polychaeta, Serpulidae) in Loch Creran, Scotland

This study aimed to contribute to conservation management of reefs of Serpula vermicularis by increasing understanding of the factors influencing larval settlement. The study was carried out in Loch Creran, which supports the most extensive known development of S. vermicularis reefs in the world. Settlement plates were deployed to examine the influence of season, depth, reef density, substrate type and orientation. Monthly deployment of plates revealed settlement of S. vermicularis to occur predominantly from mid-June to mid-October, peaking in late August to early September. Settlement of Pomatoceros spp. peaked much earlier, in late May to early June. Deployment of plates at different depths revealed a marked reduction in S. vermicularis settlement intensity between 6 and 12 m. As this corresponds with the deeper limit of the peripheral fringe of serpulid reefs in the loch, it is suggested that this limit is imposed by a depth-correlated settlement response, rather than reduction in available substrata. Comparisons of various substrata showed a preference by S. vermicularis larvae for a slate over a scallop substrate and no evidence of enhanced recruitment to occupied or unoccupied tubes of S. vermicularis, suggesting that gregarious attraction is unlikely to be a factor causing reef formation. Settlement onto the upper side of a horizontal scallop substrate was found to be insignificant in comparison with the underside or a vertically orientated scallop. Evidence for the role of light in controlling the depth and substrate-orientation preferences of S. vermicularis larvae is discussed. Based on the results of this study, recommendations are made regarding remediation of areas suffering reef damage.