Causes of Geochemical Diversity of Carbon Dioxide Water in Crystalline Rock Masses

The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO₂ (P _CO2).     

Haze Research in Brunei Darussalam During the 1998 Episode

— Brunei Darussalam experienced a severe haze episode between the beginning of February and the end of April 1998 due mainly to local peat and forest fires in Brunei and in neighbouring Sabah and Sarawak. The extensive research studies of the haze carried out in Brunei are outlined together with selected results. Particulate matter (PM₁₀) was the only significant criteria pollutant and it exceeded WHO guidelines and accepted air quality standards on most days during the haze episode. Gaseous criteria pollutants (CO, SO₂, NO₂, O₃) were generally well below WHO guidelines and at these concentrations they are expected to have no significant health or environmental effects. Measurements of volatile organic compounds (VOCs) revealed the presence of benzene, toluene, ethylbenzene, and xylenes (BTEX), aldehydes, phenol, and polynuclear aromatic hydrocarbons (PAHs). Personal exposure monitoring of PM₁₀ revealed significant differences in exposure patterns between different individuals depending on the location, time and activity. Data on outpatient visits showed an increase for some illnesses (e.g., acute respiratory infection) during the months of haze. No significant impacts of haze on rainwater acidity or deposition were noted. Emission factors for some volatile compounds were determined in combustion experiments in which peat was burned at temperatures typical of smouldering.     

Mineralized Microbiota: A Possible Indicator of Hydrocarbon Flows in the Rift Zone of Iceland

Relationships of mineralized microbiota with the content of polycyclic aromatic hydrocarbons in hydrothermal systems are considered. It has been established that the mineralized microbiota can serve as an indicator of hydrothermal hydrocarbon flows in present-day and ancient deposits.     

SENSITIVITY OF MALARIA, SCHISTOSOMIASIS AND DENGUE TO GLOBAL WARMING

Global assessment of the potential impacts of anthropogenically-induced climate change on vector-borne diseases suggests an increase in extent of the geographical areas susceptible to transmission of malarial Plasmodium parasites, dengue Flavivirus and Schistosoma worms. The transmission potential of the three associated vector-borne diseases studied is highly sensitive to climate changes on the periphery of the currently endemic areas and at higher altitudes within such areas. Our findings vis-à-vis the present endemic areas indicate that the increase in the epidemic potential of malaria and dengue transmission may be estimated at 12–27% and 31–47%, respectively, while in contrast, schistosomiasis transmission potential may be expected to exhibit a 11–17% decrease.     

Cation ordering of orthopyroxenes from the Skaergaard Intrusion: implications for the subsolidus cooling rates and permeabilities

 We have determined the quenched cation ordering states of five orthopyroxene crystals collected from the marginal border group and the lower zone a and b of the Skaergaard intrusion, and modeled these data to retrieve their closure temperatures (T _c) of Fe–Mg ordering and cooling rates. According to existing thermal models for the Skaergaard pluton, conductive cooling dominated the high and low temperature regimes, which were separated by an intermediate temperature regime in which the cooling was controlled primarily by convective fluid circulation. The cooling rates retrieved from the quenched cation ordering states of the orthopyroxene crystals strictly apply to temperatures around the closure temperatures of the ordering states, ∼340–400^° C, which fall at the transition from convective to the lower temperature conductive cooling. The cooling rates obtained from the cation ordering states of orthopyroxene vary from ∼1 to 270 K/ka. These results agree well with a thermal model calculated using an assumed average permeability of 10^-12 cm² for the pluton, but not completely with a model calculated on the basis of an average permeability of 10^-13 cm², although both values produced shifts of δ¹⁸O that are comparable to those observed in the pluton. Received: 27 February 1995/Accepted: 20 July 1995     

The first occurrence of platinum group minerals (PGM) in a chromite deposit in the Eastern Desert, Egypt

 The platinum-group mineralogy (PGM) of the chromitite from Gebel Lawi, in the southeastern desert has been investigated. The most abundant base metal sulfides (BMS) associated with the Lawi chromite are pentlandite, millerite and heazlewoodite. The major platinum-group minerals identified were as follows: laurite (IrOsRu)S2, osmian iridium (OsIr), hollingworthite (RhAsS), tellurian arsenopalladinite (PdTeSbAs), potarite (PdHg) besides cuprian palladian gold (CuPdAu), a Pd-Sb-Hg and HgTe phases. Laurite and osmian iridium occur preferentially in chromite. Os-Ir commonly forms composite PGM with laurite. Hollingworthite and tellurian arsenopalladinite are included within serpentine and, close to the base-metal sulfides, the cuprian palladian gold shares boundaries with chromite. Potarite together with the Pd-Sb-Hg and HgTe phases are embedded in serpentine. Palladium is the most abundant PGE in the Gebel Lawi chromite. A paragenetic sequence of PGM formation is described. Textural evidence indicates that Os-, Ir- and Ru-bearing PGM formed early and were followed by Rh- and Pd-bearing PGM. The concentration of all five PGE could be magmatic, but much of the PGE mineralogy except for laurite and osmian iridium in the center of chromite grains, has been modified by subsequent processes. At later stages, the environment became Te-, Sb-, As- and Hg-rich, which finally led to the formation of low-temperature alteration minerals. Received: 24 April 1995 / Accepted: 28 March 1996