The effects of a copper-based antifouling paint on mortality and enzymatic activity of a non-target marine organism

Antifouling paints are used on a wide range of underwater structures in order to protect them from the development of fouling organisms. The leaching of the toxic substances from the matrix of the paint causes toxic effects not only to the fouling organisms but also on other "non-target" biota. The present study addresses the impact of the antifouling paint Flexgard VI-II on brine shrimp nauplii selected as convenient test organisms. The surface to volume (S/V) concept developed by Persoone and Castritsi-Catharios (1989) was used to determine S/V-LC50s for the test biota exposed to PVC test panels of 400-1000 mm2 surface coated with the antifouling paint in test vessels containing 20 ml seawater. Total ATPase and Mg2+-ATPase were also analyzed for coated surface areas inducing less than 50% mortality in the brine shrimp nauplii. The calculated S/V-LC50 (24 h) was 24.6 mm2/ml, which shows the high toxic character of the antifouling paint. Decreased enzymatic activities were noted in the brine shrimp nauplii exposed to test panels of 50 and 100 mm2 in 20 ml seawater. The present study indicates that the "surface to volume" concept is an interesting methodology that can be applied with both lethal and sublethal effect criteria for the determination of toxic stress from leaches of painted surfaces.     

Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.     

Performance analysis of the spaceborne laser ranging system

The Spaceborne Laser Ranging System is a proposed short pulse laser on board an orbiting spacecraft.^1,2,3,4 It measures the distance between the spacecraft and many laser retroreflectors (targets) deployed on the Earth’s surface. The precision of these range measurements is assumed to be about ±2 cm (M. W. Fitzmaurice, private communication). These measurements are then used together with the orbital dynamics of the spacecraft, to derive the relative position of the laser ground targets. Assuming a six day observing period with 50% cloud cover, uncertainties in the baseline for target separations of 50 km to 1200 km were estimated to be on the order of 1 to 3 cm and the corresponding values in the vertical direction, ranged from 1 cm to 12 cm. By redetermining the measurements of the relative target positions, the estimated precision in the baseline for a target separation of 50 km is less than 0.3 cm and for a separation of 1200 km is less than 1 cm. In the vertical direction, the estimated precision ranged from 0.4 cm to 4.0 cm respectively. As a result of the repeated estimation of the relative laser target positions, most of the non-temporal effects of error sources as exemplified by the errors in geopotential are reduced. The Spaceborne Laser Ranging System’s capability of determining baselines to a high degree of precision provides a measure of strain and strain rate as shown byCohen, 1979. These quantities are essential for crustal dynamic studies which include determination and monitoring of strain near seismic zones, land subsidence, and edifice building preceding volcanic eruptions. It is evident that such a system can also be used for geodetic surveys where such precisions are more than adquate.     

A soil chronosequence in Late Glacial and Neoglacial moraines, Humboldt Glacier, northwestern Venezuelan Andes

Late Glacial and Neoglacial (Little Ice Age) deposits on the Humboldt Massif were analyzed for relative-age dating parameters, including geomorphic and weathering characteristics, geochemical and soil properties. The soil chronosequence, formed in chemically uniform parent materials, provides an important database to study soil evolution in a tropical alpine environment. Extractable and total Fe and Al concentrations, examined to assess their use in relative-age determination, and as paleoenvironmental indicators, provide an important measure of the accumulation and downward profile movement over time of organically-bound Al, ferrihydrite and other crystalline forms (hematite and goethite) of extractable Fe. Ferrihydrite is particularly useful in determining former perched water levels in soils with relation to paleoclimate. The ratios of most Fe extracts are time dependent. The Fe_d/Fe_t ratio, within statistical limits, shows a slow increase from LIA (Little Ice Age) to Late Glacial soils, which closely correlates with other alpine soil studies in the middle latitudes and other tropical alpine locales. Values of Al_d (dithionite) and Al_o (oxalate extractable) generally do not correlate with time; however, Al_p (pyrophosphate extractable) measured against Al_t (total) provides insight on the downward translocation over time of organically-bound Al. Low leaching rates in this chronosequence are further supported by clay mineralogy trends and the geochemical data.     

An integrated approach to investigate saline water intrusion and to identify the salinity sources in the Central Godavari delta, Andhra Pradesh, India

The Central Godavari delta is located along the Bay of Bengal Coast, Andhra Pradesh, India, and is drained by Pikaleru, Kunavaram and Vasalatippa drains. There is no groundwater pumping for agriculture as wells as for domestic purpose due to the brackish nature of the groundwater at shallow depths. The groundwater table depths vary from 0.8 to 3.4 m and in the Ravva Onshore wells, 4.5 to 13.3 m. Electrical Resistivity Tomography (ERT) surveys were carried out at several locations in the delta to delineate the aquifer geometry and to identify saline water aquifer zones. Groundwater samples collected and analyzed for major ions for assessing the saline water intrusion and to identify the salinity origin in the delta region. The results derived from ERT indicated low resistivity values in the area, which can be attributed to the existence of thick marine clays from ground surface to 12–15 m below ground level near the coast and high resistivity values are due to the presence of coarse sand with freshwater away from the coast. The resistivity values similar to saline water <0.01 Ω m is attributed to the mixing of the saline water along surface water drains. In the Ravva Onshore Terminal low resistivity values indicated up coning of saline water and mixing of saline water from Pikaleru drain. The SO ₄ ^?2 /Cl^?and Na⁺²/Cl^?ratios did not indicate saline water intrusion and the salinity is due to marine palaeosalinity, dilution of marine clays and dissolution of evaporites.     

Isotope composition of neodymium in neo-Archean banded iron formations of Karelia and Kola Peninsula

Studies of three deposits of neo-Archean banded iron formations from the West Karelian domain (the Kostomuksha deposit) and from the Central Kola block (the Olenegorsk and Kirovogorsk deposits) showed a pronounced difference in the isotope compositions of Nd from quartz and magnetite–hematite interlayers. The less radiogenic Nd of iron-containing layers compared to that of the quartz component may be considered as an indication of the formation mechanism of the treated banded iron formations. Thus, silicon-containing layers are related to submarine volcanism and iron was supplied to the sedimentation zone from other sources.