EVIDENCE FOR THE PRESENCE OF LOW MOLECULAR WEIGHT ALCOHOLS AND CARBONYL COMPOUNDS IN THE MURCHISON METEORITE†

Alcohols, aldehydes and ketones identified in the Murchison C2 chondrite include: methanol, ethanol, 2-propanol, butyl alcohols, formaldehyde, acetaldehyde, propionaldehyde, acetone, 2-butanone, 3-pentanone and 2-pentanone.     

The influence of minerals on the pyrolysis of kerogens

The effect of mineral matter on the laboratory pyrolysis of sediments, kerogens and coals, and of coal macerals mixed with either alumina, bentonite, kaolinite, or calcium carbonate has been investigated. Some minerals are more active than others in effecting changes in the composition of the pyrolysate. The relative content of low molecular weight pyrolysis products is higher for kerogens pyrolyzed in a mineral matrix than for isolated kerogens. Our limited data suggests that this is due to both condensation and gasification of higher molecular weight constituents in the ‘primary’ pyrolysate. Differences in the content of aromatic versus aliphatic compounds have been noted when pyrograms from coal macerals are compared with pyrograms from coal maceral-mineral mixtures. We conclude that mineralogy is important in controlling the composition of kerogen pyrolysis products.     

Gravity anomaly modeling of sedimentary basins by means of multiple structures and exponential density contrast-depth variations: A space domain approach

An automatic modeling scheme is developed in the space domain to interpret the gravity anomalies of sedimentary basins, among which the density contrast decreases exponentially with depth. Forward modeling is realized in the space domain using a combination of both analytical and numerical approaches. A collage of vertical prisms having equal widths, whose depths are to be estimated, describes the geometry of a sedimentary basin. Initial depths of a sedimentary basin are predicted using the Bouguer slab formula and subsequently updated, iteratively, based on the differences between the observed and theoretical gravity anomalies until the modeled gravity anomalies mimic the observed ones. The validity and applicability of the method is demonstrated with a synthetic and two real field gravity anomalies, one each over the Chintalpudi sub-basin in India and the other over the San Jacinto graben, California. In case of synthetic example, the assumed structure resembles a typical intracratonic rift basin formed by normal block faulting and filled with thick section of sediments. The proposed modeling technique yielded information that is consistent with the assumed parameters in the case of synthetic structure and with the available/drilling depths in case of field examples.     

Geochemical transport modelling of drainage from experimental mine tailings cells covered by capillary barriers

The use of covers with capillary barrier effects (CCBEs) for reducing acid mine drainage (AMD) from sulphidic mine tailings is simulated using the MIN3P finite volume model for coupled groundwater flow, O₂ diffusion and multi-component reactive transport. The model is applied to simulate five pilot-scale in situ test cells containing reactive tailings from the Manitou mine site, Val d’Or, Que., Canada. Four of the cells were constructed with CCBEs over the tailings, while the fifth tailings cell was left uncovered. Observed and simulated discharge from the base of each cell showed that the capillary barrier covers significantly reduced sulphide oxidation and AMD. Compared to acidic discharge from the uncovered cell, discharge from the four CCBE-covered cells had neutral pH levels and 1–7 orders of magnitude lower concentrations of SO₄, Fe, Zn, Cu and Al. The simulations showed that the moisture retaining layer of the CCBEs reduced AMD by inhibiting O₂ diffusion into the underlying reactive wastes. Provided the moisture-retention layer of the CCBE remains close to saturation, its thickness had a relatively minor effect. Under such near-saturated conditions, O₂ availability is limited by its diffusion rate through the bulk porous medium and not by the diffusion rate through the oxidized grain shells. The model is providing important new insights for comparing design alternatives for reducing or controlling AMD.     

Hydrogeophysical investigation and estimation of groundwater potentials of the Lower Palaeozoic to Precambrian crystalline basement rocks in Keffi area, north-central Nigeria, using resistivity methods

The use of resistivity sounding and two-dimensional (2-D) resistivity imaging was investigated with the aim of delineating and estimating the groundwater potential in Keffi area. Rock types identified are mainly gneisses and granites. Twenty-five resistivity soundings employing the Schlumberger electrode array were conducted across the area. Resistivity sounding data obtained were interpreted using partial curve matching approach and 1-D inversion algorithm, RESIST version 1.0. The 2-D resistivity imaging was also carried out along two traverses using dipole–dipole array, and the data obtained were subjected to finite element method modeling using DIPRO inversion algorithm to produce a two-dimensional subsurface geological model. Interpretation of results showed three to four geoelectrical layers. Layer thickness values were generally less than 2 m for collapsed zone, and ranged from 5 to 30 m for weathered bedrock (saprolite). Two major aquifer units, namely weathered bedrock (saprolite) aquifer and fractured bedrock (saprock) aquifer, have been delineated with the latter usually occurring beneath the former in most areas. Aquifer potentials in the area were estimated using simple schemes that involved the use of three geoelectrical parameters, namely: depth to fresh bedrock, weathered bedrock (saprolite) resistivity and fractured bedrock (saprock) resistivity. The assessment delineated the area into prospective high, medium and low groundwater potential zones.     

Non-static conformally flat spherically symmetric perfect fluid distribution in Einstein-Cartan theory

In this paper we have obtained general solution representing conformally-flat, non-static spherically-symmetric perfect fluid distribution in Einstein-Cartan theory. In particular, the solution has been also discussed in co-moving coordinates. The explicit expressions for pressure, density, expansion, rotation, shear and non-vanishing components of flow vector have also been found.     

Studies of sodar‐observed dot echo structures

Abstract

During moist weather under stably stratified and light wind conditions very often “dot” shaped echoes, either distributed randomly or arranged in a stratified layer, have been observed on sodar echograms. They last from a couple of hours to ten hours. Their horizontal widths are up to 200 m while their vertical sizes are up to 40 m. It is argued that dot echoes represent clusters of water vapour translated by the wind in the boundary layer, the back‐scattered acoustic energy being the contribution of correlated fluctuations in temperature and humidity (turbulent mixing) in the inertial subrange.     

Global plasmaspheric TEC and its relative contribution to GPS TEC

The plasmaspheric electron content is directly estimated from the global positioning system (GPS) data onboard JASON-1 Satellite for the first time. Similarly, the ground-based GPS total electron content (TEC) is estimated using about 1000 GPS receivers distributed around the globe. The relative contribution of the plasmaspheric electron content to the ground-based GPS TEC is then estimated globally using these two independent simultaneous measurements; namely ground-based GPS TEC and JASON-1 GPS TEC. Results presented here include data from 3 months of different solar cycle conditions (October 2003, May 2005, and December 2006). The global comparison between the two independent measurements was performed by dividing the data into three different regions; equatorial, mid- and high-latitude regions. This division is essential as the GPS raypaths traverse different distances through the plasmasphere at different latitudes. The raypath length through the plasmasphere decreases as latitude increases. The relative contribution of the plasmaspheric electron content exhibits a diurnal variation that depends on latitude with minimum contribution (10%) during daytime and maximum (up to 60%) at night. The contribution is also maximum at the equatorial region where the GPS raypath traverses a long distance through the plasmasphere compared to its length in mid- and high-latitude regions. Finally, the solar cycle variation of plasmaspheric contribution is also reported globally.     

Solar coronal heating by magnetic cancellation – III. Thermodynamics

We present two-dimensional numerical magnetohydrodynamics simulations of a coronal X-ray bright point (XBP) caused by a cancelling magnetic feature (CMF). Cancellation is driven by converging motions of two magnetic bipolar sources. These sources are initially disconnected from each other so that both, the CMF and the associated reconnection/heating event (i.e. the XBP), are modelled in a self-consistent way. In the initial state, there is no X-point but two separatrices are present. Hence, the reconnection/heating and the cancellation phases have not yet started. Our numerical experiments end shortly after the converging magnetic bipole has fully cancelled. By this time, reconnection in the inner domain has ceased and occurs only at the base. Solving the energy equation with various heating and cooling terms included, and considering different bottom boundary conditions, reveals that the unrealistically high temperatures produced by Ohmic heating are reduced to more moderate temperatures of 1.5–2 MK consistent with observations of XBPs, if thermal conduction is included and density and temperature are fixed at the base.     

Baryon loading and the Weibel instability in gamma-ray bursts

The dynamics of two counter-streaming electron–positron–ion unmagnetized plasma shells with zero net charge is analysed in the context of magnetic field generation in gamma-ray burst internal shocks due to the Weibel instability. The effects of large thermal motion of plasma particles, arbitrary mixture of plasma species and space charge effects are taken into account. We show that, although thermal effects slow down the instability, baryon loading leads to a non-negligible growth rate even for large temperatures and different shell velocities, thus guaranteeing the robustness and the occurrence of the Weibel instability for a wide range of scenarios.