Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO₃ with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L^− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L^− 1 and 0.1 nmol L^− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO₃ + HCl, followed by H₂O₂, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used.     

Stratigraphic relations and habitat of the Bende fish teeth,southeastern Nigeria

The age and habitat of the Bende fish fossils have remained a matter of controversy with interpretations ranging between the Paleocene Imo Formation and the Eocene Ameki Formation. Outcrop-based sequence stratigraphic analysis presented in this work shows that the Imo and Ameki Formations together include three laterally extensive estuarine central basin/offshore mud rock units that are associated with the 59.7, 58.1, and the 56.8 ma maximum flooding surfaces, respectively. Field evidence and stratigraphic analysis show that the Bende fossil bones are hosted by the mud rock unit containing the 58.1 ma maximum flooding surface, while the Ameke bone fossils are contained within the condensed section associated with the 56.8 ma maximum flooding surface. Apart from highlighting the relevance of sequence stratigraphy in paleobiological interpretations, this study shows that the Bende fish fauna which Arua first assigned to the Eocene Ameki Formation indeed belongs to the Paleocene Imo Formation.     

Spatial and temporal variability of mesozooplankton and tintinnid ciliates in a seasonally hypersaline estuary

The zooplankton community of Mission Bay, San Diego, California, was monitored over two years, to study spatial and temporal patterns and the response of zooplankton species composition to environmental variation. Data were collected every two weeks from six stations and included hydrographic parameters, dissolved nutrient concentrations, and phytoplankton and zooplankton species composition. Hydrography varied seasonally, along a spatial gradient from the mouth to the back of the bay, and between the two years around the influence of rainfall. Spatially, Mission Bay could be divided into three regions during this study based on hydrography and zooplankton species composition. Zooplankton species composition followed a predictable seasonal progression, with different groups of species being characteristic to particular times of the year. Variability in zooplankton species composition was also evident between years, as certain species were more common in one or the other year of the study. Spatial patterns were more consistent than temporal ones, and related to distance from the mouth of the bay during much of the year and distance from freshwater inlets during the relatively short rainy season. Multivariate analysis revealed that variation in zooplankton species composition was best related to measured abiotic factors (temperature, salinity, rainfall, and tidal velocity).     

Morphology and structure of the Galapagos Rise

Geophysical data collected on three U.S. Naval Oceanographic Office cruises to the Galapagos Rise are presented. These data allow definition of the morphology and structure of the Galapagos Rise.A postulated “hot spot” beneath the Galapagos platform is suggested as the cause of: (1) decreased seismicity along the spreading center for a 400 km E—W distance from the islands; (2) distinctive petro-chemistry of tholeiites from the islands and adjacent oceanic crust generated by the Galapagos Rise; (3) high-amplitude magnetic anomalies in a 1,000 km E—W band including and just north of the Galapagos platform; and (4) morphologic shape and the regionally elevated sea floor of the Galapagos Rise as it approaches the insular platform.     

32Si dating of sediments from Lake Baikal

We applied the ³²Si dating technique to a sediment core from Lake Baikal to obtain the sediment chronology for the last millennium. The core was recovered about 4 km offshore from the north slope of the South Basin in 1,366 m water depth. The sediment material consisted of continuously accumulated diatom-rich geogenic-terrigenous mud, intercalated with a number of dark olive-grey turbidite layers. The sediment layers containing the turbidites were excluded from ³²Si sampling to obtain the chronology that is representative of the continuous sedimentation. The initial ³²Si activity of 31.3 dpm kg^?1 SiO₂, measured in sediment trap samples, confirms the trend of ³²Si specific activities of biogenic silica found in other Northern Hemisphere lakes. The four sediment core samples from depth 0–48 cm have ³²Si specific activities between 23.5 and 0.5 dpm kg^?1 SiO₂, with corresponding ages between 60 and 860 years and constant sedimentation rate of 0.036 ± 0.004 cm year^?1 over the most recent 800 years. ³²Si allowed us for the first time to date the uppermost turbidites in the South Basin of Lake Baikal, to 1030, 1310 and 1670 ad. Given these dates, the last long-distance turbidity current triggered by slope instabilities had occurred 330 years before 2000 ad, and the intervals between the 1310 and 1670 ad event and between the 1030 and 1310 ad event were 360 and 280 years, respectively. The ³²Si ages allow unprecedented time resolution for reconstruction of the former environmental and climatic conditions during the past millennium.     

Late Cainozoic geology,soils, and landscape evolution of the Torrens Creek area,North Queensland

The major features of the geology and geomorphology of the semi‐arid, tropical Torrens Creek area of North Queensland are described. The evolution of the landscape through the late Cainozoic is discussed with reference to three phases of landscape instability and erosion, each separated by phases of stability during which weathering and soil formation proceeded. These erosional periods were probably initiated by episodic uplift of the Great Divide region. Tentative correlations with landscape events in the nearby Nulla Basalt Province suggest that soil profile development probably occurred during late Pliocene (2.3–2.0 m.y. ago), mid‐Pleistocene (1.3–1.1 m.y. ago), and in Quaternary (less than 0.1 m.y. ago) times.     

A New Approach to ID-TIMS U–Pb Dating of Cassiterite by the Example of the Pitkäranta Tin Deposit

Doklady Earth Sciences - A new technique for the complete dissolution of cassiterite, which makes it possible to determine the age of this mineral by U–Pb isotope dilution (ID-TIMS), has been...     

Flow and transport predictions during multi-borehole tests in fractured chalk using discrete fracture network models

Multi-borehole pumping and tracer tests on the 10 to 100-m scale were conducted in a fractured chalk aquitard in the Negev Desert, Israel. Outcrop and core fracture surveys, as well as slug tests in packed-off intervals, were carried out at this site to obtain the parameters needed for construction of a stochastic discrete fracture network (DFN). Calibration of stochastic DFNs directly to the multiple borehole test data was inadequate. Instead, two equivalent deterministic DFN flow models were used: the vertical-fractures (VF) model, consisting of only vertical fractures, and the fractures’ intersections (INT) model, consisting of vertical and horizontal fractures with enhanced transmissivity at their intersections. Both models were calibrated against the multi-borehole response of one pumping test and their predictions were tested against three other independent pumping tests. The average accuracies of all transient drawdown predictions of the VF and INT models were 65 and 66%, respectively. In contrast to this equality in average drawdown predictions of both models, the INT model predicted better important breakthrough curve features (e.g., first and peak arrival times), than the VF model. This result is in line with previously assumed channeled flow, derived from analytical analysis of these pumping and tracer tests. Ronit Nativ, deceased, may her memory be blessed.     

A cost–benefit appraisal of coastal managed realignment policy

European coasts are coming under increasing threat as a result of climate change from erosion and flooding. While coastal defences such as sea walls have been constructed since Roman times to protect human settlements from the sea, it is now increasingly recognised that these defences are unsustainable. The security provided by ‘hard’ engineered defences has encouraged development on the coast, and the defences themselves have led to the loss of intertidal habitat and the natural protection it provides.An alternative to maintaining ‘hard’ defences (hold-the-line) to protect land from increasing sea levels is managed realignment, where the engineered defences are deliberately breached. By allowing the coastline to recede to a new line of defence further inland, intertidal habitat is created providing natural protection from flooding and erosion.The study evaluates the economic efficiency—using cost–benefit analysis—of various managed realignment scenarios compared to a strategy of holding-the-line within the Humber estuary in North-east England. The results of this analysis show that managed realignment can be more economically efficient than holding-the-line over a sufficiently long time period—generally greater than 25 years. Sensitivity analysis demonstrates that results are more sensitive to the amount and value of intertidal habitat generated than they are to the amount and value of carbon stored by this habitat. Cost–benefit analysis is viewed as one component of a wider policy appraisal process within integrated coastal management.     

Naming undersea features of the Sea of Japan: History and modern problems

This communication is dedicated to the investigation history and naming of the undersea morphostructures of the Sea of Japan for the last 50 years. Many of them were first described and studied during long-term geological-geophysical investigations in this basin carried out by Russian scientists. The analysis of 60 names of its undersea feature names revealed that only approximately half of them are cited in the GEBCO Gazetteer some of the undersea morphostructures are known under two or more names, the origin of their names is unknown, or their names were chosen voluntarily. For maintaining the priority of Russian investigations, the nomenclature and names of the undersea features should be adjusted in accordance with the national and international principles and regulations.