Interaction of the Atmosphere and Lithosphere in the Minute Range of Periods

Doklady Earth Sciences - The interaction between the atmosphere and the lithosphere in the minute range of periods is considered. The technique of assessment of the influence of atmospheric...     

Geochemical Indicators of “Camouflaged” Pyroclastic Material in the Upper Jurassic–Lower Cretaceous Deposits of the Eastern Russian Platform

Doklady Earth Sciences - Based on the results of studying the lithological–geochemical features of the Upper Jurassic–Lower Cretaceous mudrocks and black shales in the Eastern Russian...     

A new type of noble metal mineralization in the Northern Caucasus

The weathering crust of the Beden ultrabasite massif (the basin of Big Laba River) is identified and studied. Anomalously high contents of noble metals (Au, Pt, Pd) are revealed in the basal horizon of the Jurassic part of the weathering crust. For this reason we suspect an existence of a belt of noble metal miner-alization in the Paleozoic ultrabasites in the Peredovoi Range of the Northern Caucasus.     

Pb isotope composition of granitoids from the Hercynides of the Central Asian orogenic Belt: Evidence for growth of the juvenile crust

Based on study of the Middle Paleozoic (Hercynian) structures of the Central Asian Fold Belt located in Southwest Mongolia, the problem of the sources of juvenile crust growth registered in the Pb isotope composition of postaccretional granitoids is considered. Our study shows that the Pb isotope system of Late Paleozoic granitoids from the Hercynides of the Central Asian Fold Belt provides evidence for the juvenile nature of the continental crust in this region. The evolution of the Pb isotope composition in the Hercynides of Mongolia corresponds to the model parameter μ = 9.25, according to the Stacey–Kramers twostage model. The juvenile source of the Hercynian crust should be characterized by a lower μ value. In addition, according to the Stacey–Kramers two-stage model, the Th/U value in this crust is 3.58.     

Long-Term Changes in the Extreme Significant Wave Heights on the Western North Pacific: Impacts of Tropical Cyclone Activity and ENSO

Seasonal extreme wave statistics were reproduced by using the 25-km-grid global wave model of WAVEWATCH-III. The results showed that the simulated wave dataset for the present climate (1979-2009) was similar to Climate Forecast System Reanalysis (CFSR) wave data. Statistics such as the root mean squared error (RMSE) and correlation coefficient (CC) over the western North Pacific (WNP) basin were 0.5 m and 0.69 over the analysis domain. The largest trends and standard deviation were around the southern coast of Japan and western edge of the WNP. Linear regression analysis was employed to identify the relationship between the leading principal components (PCs) of significant wave heights (SWHs) in the peak season of July to September and sea surface temperature (SST) anomalies in the equatorial Pacific. The results indicated that the inter-annual variability of SWH can be associated with the El Niño-Southern Oscillation in the peak season. The CC between the first PC of the SWH and anomalies in the Nino 3.4 SST index was also significant at a 99% confidence level. Significant variations in the SWH are affected by tropical cyclones (TCs) caused by increased SST anomalies. The genesis and development of simulated TCs can be important to the variation in SWHs for the WNP in the peak season. Therefore, we can project the variability of SWHs through TC activity based on changes in SST conditions for the equatorial Pacific in the future.     

The political-geographical aspects of problematic statehood (exemplified by Somalia)

We examine the phenomenon of “collapsed” states by using, as an example, Somalia that is being faced with a vast array of problems: collapse of state institutes, civil war, separatism, terrorism, radical Islamism, and piracy. It is found that clannishness and tribalism of Somali society are complicating the process of political settlement and national reconciliation. It is pointed out that some of the tribes and groups, including under the action of external forces, are actually forming the country’s political space. It is shown that the pseudo-state entities in Somalia are unstable, and their boundaries of “flowing” so that they are incapable of exercising a full control over the territory. It is emphasized that the problem of Islamic extremism can be treated as deriving from failure of the state institutes; the peak of activity and territorial expansion of Islamist groups in the country is now in the past, and the area of their activity is bounded by the area inhabited by the Somali ethnos. It is found that the piracy problem is determined by the geographical location of Somalia, and its solution is impossible without the reestablishment of the state institutes and the economic system of the country. Two potential cores of reestablishment of Somali statehood have been revealed: Federal Government in Mogadishu as well as the Autonomous Republic of Puntland. It is forecasted that the international community will be gradually recognizing the Republic of Somaliland. It is concluded that the federalization of the country as declared by authorities is formal in character but yields first results implying that the negotiation process between the groups of clans has been led into a political channel.     

Seismicity and isostasy

Both a theoretical treatment and observed data show that the isostatic gravity field and the seismicity are closely related. The equation for harmonic loading shows that large deviations from isostatic equilibrium lead to large shear stresses in the crust. High seismic activity correlates well with large isostatic gravity anomalies and with large horizontal gradients of isostatic gravity anomalies. Studies of seismicity should consider the isostatic gravity field.     

Periodic Hartree-Fock study of minerals: Tetracoordinated silica polymorphs

Periodic Hartree-Fock STO-3G calculations have been performed on several tetracoordinated silica polymorphs: low and high quartz, low and idealized high cristobalite and prototype tridymite. The optimized structural parameters are in overall good agreement with experimental data. In the particular case of -quartz, the SiO₄ tetrahedra are found to be irregular. The optimized values of the two different SiO bond lengths are respectively 1.608 Å and 1.613 Å. The potential energy versus tilt angle curves suggest a picture of the high temperature phases in terms of delocalized oxygen atoms which is consistent with a disordered structure. Finally, the bonding in silica polymorphs is discussed from electron density maps and Mulliken population analysis.