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991.
The results of comprehensive geological and metallogenic studies of the Greater Altai are presented. This project has been carried out since 1997 under the guidance of Academician G.N. Shcherba. The importance of these investigations is determined by the need to enhance and further develop mineral resources of nonferrous, noble, rare, and other metals for operating mining and metallurgical enterprises of Kazakhstan. The great body of information on the geology, geophysics, and metallogeny of the region obtained over many years has been integrated on the basis of new global tectonics. The Greater Altai embraces the Hercynides of the Rudny Altai, Qalba-Narym, West Qalba, Zharma-Saur, and the adjacent territories of Russia and China. The present-day tectonic units are considered to be detached blocks of ancient continental massifs that drifted in the Paleoasian ocean and then amalgamated into the structure of the Greater Altai during the Hercynian collision. The tectonic and metallogenic demarcation of the studied territory made possible the recognition of the Rudny Altai, Qalba-Narym, West Qalba, and Zharma-Saur ore belts, different in geology, geodynamic evolution, and metallogeny. The formation conditions and localization of volcanic-hosted massive sulfide, gold, and rare-metal deposits pertaining to certain ore-bearing geochronological levels were specified, and the potential of the region for various mineral resources was estimated. 相似文献
992.
Rajesh Sharma Prabha Joshi P. D. Pant 《Journal of the Geological Society of India》2009,73(2):237-248
Talc deposits of Rema area in the Kumaun Inner Lesser Himalaya are hosted within high magnesium carbonates of the Proterozoic
Deoban Formation. These deposits occur as irregular patches or pockets mainly within magnesite bodies, along with impurities
of magnesite, dolomite and clinochlore. Textures represent different phases of reactions between magnesite and silica to produce
talc. Petrography, XRD and geochemistry reveal that the talc has primarily developed at the expense of magnesite and silica,
leaving dolomite largely un-reacted. Early fluid inclusions in magnesite and dolomite associated with talc are filled with
H2O+NaCl+KCl ± MgCl2 ± CaCl2 fluids, which represent basin fluid system during diagenesis of carbonates. Their varied degree of re-equilibration was although
not pervasive but points to increased burial, and hence requires careful interpretation. H2O-CO2 fluid with XCO2 between 0.06 and 0.12 was equilibrated with talc formation. The reaction dolomite+quartz → talc was not extensive because
T-XCO2 was not favourable, and talc was developed principally after magnesite+quartz. 相似文献
993.
Yu. N. Zanin G. M. Pisareva A. G. Zamirailova V. G. Eder 《Lithology and Mineral Resources》2009,44(3):267-269
Weathering of pyrite in the core recovered from black shales of the Bazhenovo Formation (Upper Jurassic-Lower Cretaceous) in the West Siberian marine basin promoted the successive formation of melanterite (FeSO4 · 7H2O) and szomolnokite (FeSO4 · H2O). Szomolnokite was detected in West Siberia for the first time. 相似文献
994.
B. G. Pokrovskii 《Lithology and Mineral Resources》2009,44(3):258-266
Dolomites from the productive Osa horizon (upper subformation of the Lower Cambrian Bilir Formation) in the Talakan petroleum field show a prominent 1–2‰ decrease in δ18O (from 23–24 to 21–22‰), which presumably marks a zone of relatively high water/rock ratios. Productive boreholes are characterized by moderate δ34S values (from 25.1 to 30.6‰) and negative correlation between δ34S in anhydrite and δ18O in associated dolomite, which points to a partial sulfate reduction during catagenesis. In nonproductive borehole, δ34S values increase significantly (from 31.4 to 35.6‰) and show positive correlation with δ18O in dolomite. Rocks recovered by nonproductive borehole possibly recrystallized during early diagenesis, and, correspondingly lost their permeability and capacity to form pores. Limestones and dolomites of the Osa horizon have a carbon isotopic composition within the range of normal marine carbonates (δ13C = 0 ± 1 ‰), which does not indicate a significant role of organic matter in postsedimentary recrystallization of carbonate sediments. A positive δ13C excursion up to 4.5‰ recorded in the lower subformation of the Bilir Formation presumably occurred at the sedimentation stage under conditions of high rates of bioproductivity and organic matter burial in sediments. 相似文献
995.
Thomas M. Soniat Eileen E. Hofmann John M. Klinck Eric N. Powell 《International Journal of Earth Sciences》2009,98(1):99-114
The eastern oyster (Crassostrea virginica) is affected by two protozoan parasites, Perkinsus marinus which causes Dermo disease and Haplosporidium nelsoni which causes MSX (Multinucleated Sphere Unknown) disease. Both diseases are largely controlled by water temperature and salinity and thus are potentially sensitive to climate variations resulting from the El Niño-Southern Oscillation (ENSO), which influences climate along the Gulf of Mexico coast, and the North Atlantic Oscillation (NAO), which influences climate along the Atlantic coast of the United States. In this study, a 10-year time series of temperature and salinity and P. marinus infection intensity for a site in Louisiana on the Gulf of Mexico coast and a 52-year time series of air temperature and freshwater inflow and oyster mortality from Delaware Bay on the Atlantic coast of the United States were analyzed to determine patterns in disease and disease-induced mortality in C. virginica populations that resulted from ENSO and NAO climate variations. Wavelet analysis was used to decompose the environmental, disease infection intensity and oyster mortality time series into a time–frequency space to determine the dominant modes of variability and the time variability of the modes. For the Louisiana site, salinity and Dermo disease infection intensity are correlated at a periodicity of 4 years, which corresponds to ENSO. The influence of ENSO on Dermo disease along the Gulf of Mexico is through its effect on salinity, with high salinity, which occurs during the La Niña phase of ENSO at this location, favoring parasite proliferation. For the Delaware Bay site, the primary correlation was between temperature and oyster mortality, with a periodicity of 8 years, which corresponds to the NAO. Warmer temperatures, which occur during the positive phase of the NAO, favor the parasites causing increased oyster mortality. Thus, disease prevalence and intensity in C. virginica populations along the Gulf of Mexico coast is primarily regulated by salinity, whereas temperature regulates the disease process along the United States east coast. These results show that the response of an organism to climate variability in a region is not indicative of the response that will occur over the entire range of a particular species. This has important implications for management of marine resources, especially those that are commercially harvested. 相似文献
996.
Monitoring and methods to analyse the groundwater quality degradation risk in coastal karstic aquifers (Apulia,Southern Italy) 总被引:1,自引:0,他引:1
A multi-methodological approach based on monitoring and spatio-temporal analysis of groundwater quality changes is proposed.
The presented tools are simple, quick and cost-effective to give service to all sorts of users. The chief purpose of the monitoring
network is the detection of the piezometric or potenziometric level in the aquifer. The spatial and multi-temporal analysis
of usual chemical and physical data provides both an assessment of the spatial vulnerability of the aquifer to seawater intrusion,
defining a salinity threshold between fresh groundwater and brackish groundwater and of the water quality trend in terms of
salinity. The evaluation of the salinity trend or of salinity-correlated parameters highlights the effects of groundwater
mismanagement. The multiparameter logging provides a rapid groundwater quality classification for each well. The whole approach
allows evaluating the effects of current management criteria and designing more appropriate management targets. The Apulian
karstic coastal aquifers have been selected as a case study (Southern Italy). Three types of aquifer zones can be distinguished:
(1) areas with low vulnerability to seawater intrusion, (2) areas with high vulnerability and (3) areas with variable vulnerability
in which the salt degradation largely depends on the ability to manage the well discharge. The water quality degradation caused
by seawater intrusion appears to be a combined effect of an anomalous succession of drought periods observed from about 1980
onwards and increased groundwater pumping, particularly during drought periods. A management criterion based on aquifer zones
is proposed. 相似文献
997.
Geochemical characterization of karst groundwater in the cradle of humankind world heritage site,South Africa 总被引:1,自引:0,他引:1
The karst of the Cradle of Humankind World Heritage Site plays a major role in the assimilation or carrying of acid mine drainage,
sewage effluent return flow and agricultural run-off. Infiltration of contaminated water has altered the chemical composition
of the natural waters of the karst system. A multivariate statistical method in combination with conventional geochemical
and spatial analysis was applied on groundwater and surface water quality samples to determine the spatial extent of hydrochemical
impacts from different anthropogenic sources. The application of hierarchical cluster analysis of the major ions (148 samples)
recognised three distinct hydrochemical regimes. Cluster 1 is moderately mineralized, especially with regard to chloride,
nitrate and sulphate, cluster 2 has a low mineralization with all elements well within the recommended drinking water limits
of South Africa and cluster 3 represents highly mineralized samples taken in the vicinity of decanting mineshafts. The cluster
solution is confirmed by a simple mixing model, indicating varying contributions of three identified end members (acid mine
drainage, treated sewage effluents and pristine dolomitic groundwater) to the groundwater quality in the catchment. The combination
of statistical, geochemical and spatial methods in conjunction with end-member mixing analysis provides a reliable method
to understand the processes responsible for the groundwater quality variations and to assist in the identification of anthropogenic
impacts. 相似文献
998.
U-Pb systems were examined in samples (ranging from 4 to 10 cm3 in volume) of ore material taken from along a 3.5-m profile across a zone of U mineralization exposed in an underground mine at the Strel’tsovskoe U deposit in eastern Transbaikalia. The behaviors of two isotopic U-Pb systems (238U-206Pb and 235U-207Pb) are principally different in all samples from our profile. While the individual samples are characterized by a vast scatter of their T(206Pb/238U) age values (from 112 to 717 Ma), the corresponding T(207Pb/235U) values vary much less significantly (from 127 to 142 Ma) and are generally close to the true age of the U mineralization. The main reason for the distortion of the U-Pb system is the long-lasting (for tens of million years) migration of intermediate decay products in the 238U-206Pb(RD238U) in the samples. This process resulted in the loss of RD238U from domains with high U concentrations and the subsequent accommodation of RD238U at sites with low U concentrations. The long-term effect of these opposite processes resulted in a deficit or excess of 206Pb as the final product of 238U decay. The loss or migration of RD238U are explained by the occurrence of pitchblende in association with U oxides that have higher Si and OH concentrations than those in the pitchblende and a higher +6U/+4U ratio. The finely dispersed character of the mineralization and the loose or metamict texture of the material are the principal prerequisites for RD238U loss and an excess of 206Pb in adjacent domains with low U concentrations. Domains with low U contents in the zone with U mineralization serve as geochemical barriers (because of sulfides contained in them) at which long-lived RD238U(226Ra, 210Po, 210Bi, and 210Pb) were accommodated and subsequently caused an excess of 206Pb. The 235U-207Pb system remained closed because of the much briefer lifetime of the 235U decay products. This may account for the significant discrepancies between the T(206Pb/238U) and T(207Pb/235U) age values. RD238U was most probably lost via the migration of radioisotopes at the middle part and end of the 238U family (starting with 226Ra). The heavy Th, Pa, and U radioisotopes (234Th, 234Pa, 234U, and 230Th) that occur closer to the beginning of 238U decay, before 226Ra, only relatively insignificantly participated in the process. Our results show that the loss and migration of RD238U are, under certain conditions, the main (or even the only) process responsible for the distortion of the U-Pb system. 相似文献
999.
Steven Creighton Thomas Stachel Sergei Matveev Heidi Höfer Catherine McCammon Robert W. Luth 《Contributions to Mineralogy and Petrology》2009,157(4):491-504
The oxidation state, reflected in the oxygen fugacity (fO2), of the subcratonic lithospheric mantle is laterally and vertically heterogeneous. In the garnet stability field, the Kaapvaal
lithospheric mantle becomes progressively more reducing with increasing depth from Δlog fO2 FMQ-2 at 110 km to FMQ-4 at 210 km. Oxidation accompanying metasomatism has obscured this crystal-chemical controlled depth-fO2 trend in the mantle beneath Kimberley, South Africa. Chondrite normalized REE patterns for garnets, preserve evidence of
a range in metasomatic enrichment from mild metasomatism in harzburgites to extensive metasomatism by LREE-enriched fluids
and melts with fairly unfractionated LREE/HREE ratios in phlogopite-bearing lherzolites. The metasomatized xenoliths record
redox conditions extending up to Δlog fO2 = FMQ, sufficiently oxidized that magnesite would be the stable host of carbon in the most metasomatized samples. The most
oxidized lherzolites, those in or near the carbonate stability field, have the greatest modal abundance of phlogopite and
clinopyroxene. Clinopyroxene is modally less abundant or absent in the most reduced peridotite samples. The infiltration of
metasomatic fluids/melts into diamondiferous lithospheric mantle beneath the Kaapvaal craton converted reduced, anhydrous
harzburgite into variably oxidized phlogopite-bearing lherzolite. Locally, portions of the lithospheric mantle were metasomatized
and oxidized to an extent that conversion of diamond into carbonate should have occurred.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
1000.
Environmental isotopic and hydrochemical study of groundwater in the Ejina Basin,northwest China 总被引:5,自引:0,他引:5
The study investigates the groundwater evolution and its residence time in the Ejina Basin, northwest China according to isotope
and hydrochemical analyses results. The groundwater chemistry is mainly controlled by the dissolution of halite, Glauber’s
salt, gypsum, dolomite and calcite, also influenced by other processes such as evaporation, ion exchange, and deposition.
Based on tritium content in atmospheric precipitation and by adopting a model with exponential time distribution function,
the mean residence time of the unconfined aquifer groundwater with fairly high tritium activities (21–49 TU) is evaluated.
The results show that these groundwaters have low residence time (5–120 years) and are renewable. In contrast, the deep confined
groundwaters are tritium-free and radiocarbon values range from 18.3 to 26.7 pmc. According to the most commonly used 14C correction models, the radiocarbon groundwater ages were calculated which yield ages of approximately 4,087–9,364 years
BP. Isotopic signatures indicate formation of deep confined groundwaters in a colder and wetter climate during the late Pleistocene
and Holocene. It is suggested that long-term, rational water usage guide should be set up for the Heihe River Basin as a whole
to permit a considerable discharge to the Ejina Basin. 相似文献