The economic mineral potential of the mid-Proterozoic Waterberg Group, northwestern Kaapvaal craton, South Africa

The 1900–1700 Ma Waterberg Group in the main Waterberg fault-bounded basin consists of dominantly coarse siliciclastic red beds with minor volcanic rocks. The sedimentary rocks were deposited mainly by alluvial fans, fluvial braidplains and transgressive shallow marine environments, with lesser lacustrine and aeolian settings. Uplifted, largely granitic source areas were located along the Thabazimbi-Murchison lineament (TML) fault system in the south, and along the Palala shear zone in the northeast. Palaeoplacer titanomagnetite-ilmenite-zircon heavy mineral deposits, best developed in the Cleremont Formation in the centre of the basin, reflect initial fluvial reworking and subsequent littoral marine concentration. Coarse alluvial cassiterite placer deposits are found in the Gatkop area in the southwest of the basin, and appear to have been derived from stanniferous Bushveld Complex lithologies south of the TML. Hydrothermal zinc and U-Cu mineralisation in the Alma lithologies in the same area appears to be related to the TML fault system. Small manganese deposits and anomalous tungsten values occur in the south of the basin, where they are again closely spatially associated with the TML. Copper-barium mineralisation is found associated with dolerite dykes, and in stratigraphically controlled, inferred syngenetic settings. The most interesting of these apparently syngenetic occurrences is found within green coloured reduced mudrocks and inferred volcanic rocks, at an unconformity developed within the overall red bed sequence of the Waterberg Group, adjacent to the TML in the southwest of the basin. The most important potential mineralisation in the main Waterberg basin thus encompasses shoreline placer Ti and the possibility of substantial sediment-hosted copper deposits. Received: 31 May 1996 / Accepted: 17 February 1997     

Diffusion of tetravalent cations in zircon

Diffusion rates for the three tetravalent cations U, Th and Hf have been measured in synthetic zircon. Diffusant sources included oxide powders and ground pre-synthesized silicates. Rutherford backscattering spectrometry (RBS) was used to measure depth profiles. Over the temperature range 1400–1650 °C, the following Arrhenius relations were obtained (diffusion coefficients in m²sec⁻¹): log D _Th = (1.936 ± 0.9820) + (− 792 ± 34 kJ mol⁻¹ /2.303 RT) log D _U = (0.212 ± 2.440) + (− 726 ± 83 kJ mol⁻¹ /2.303 RT) log D _Hf = (3.206 ± 1.592) + (− 812 ± 54 kJ mol⁻¹ /2.303 RT) The data show a systematic increase in diffusivity with decreasing ionic radius (i.e., faster diffusion rates for Hf than for U or Th), a trend also observed in our earlier study of rare earth diffusion in zircon. Diffusive fractionation may be a factor in the Lu-Hf system given the much slower diffusion rates of tetravalent cations when compared with the trivalent rare earths. The very slow diffusion rates measured for these tetravalent cations suggest that they are essentially immobile under most geologic conditions, permitting the preservation of fine-scale chemical zoning and isotopic signatures of inherited cores. Received: 12 July 1996 / Accepted: 2 December 1996     

Effect of tunnel depth on modulus of deformation of rock mass

Summary Deformability of rock mass significantly influences its behaviour and is, therefore, an important consideration for the design of underground openings. The modulus of deformation of rock mass is, however, normally obtained from expensive and time-consuming uniaxial jacking tests, whose results often have a large scatter. An empirical correlation has, therefore, been proposed for a quick and inexpensive preliminary estimation of the modulus of deformation of rock mass on the basis of field instrumentation carried out in tunnels in India.     

Solar modulation of cosmogenic nuclide production over the last millennium: comparison between C and Be records

For about the last 30 years it has been recognized that the high frequency component of the tree rings ¹⁴C/¹²C record is dominated by the modulation of the cosmic ray flux by the solar wind. In particular, it has been demonstrated that the three most recent periods of low sunspot occurrence were characterized by high values of atmospheric ¹⁴C/¹²C. During the last millennium other periods of high ¹⁴C/¹²C values were observed but their solar origin is still debatable. In the present work we compare these fluctuations with an independent record of cosmogenic ¹⁰Be measured in ice from the South Pole to check the solar origin of the observed ¹⁴C/¹²C variations. In order to compare quantitatively the results obtained on ¹⁰Be and ¹⁴C, it is necessary to take into account the different behaviour of these two cosmogenic isotopes, and especially the damping effect of the carbon cycle in the case of ¹⁴C. As an input to a 12-box numerical model we used the relative fluctuations of the ¹⁰Be concentrations record measured in South Pole ice and converted it into a synthetic ¹⁴C record. We took into account the fact that ¹⁰Be modulation is enhanced in polar regions due to the orientation of the geomagnetic field. As expected, the fluctuations of the modelled ¹⁴C record are much smaller (a factor of 20) than those observed for the raw ¹⁰Be record. In addition, the variations are smoother and shifted in time by a few decades. The ¹⁰Be-based ¹⁴C variations closely resemble the ¹⁴C measurements obtained on tree rings (R = 0.81). In particular, it is easy to identify periods of maximal ¹⁴C/¹²C which correspond to solar activity minima centred at about 1060, 1320 (Wolf), 1500 (Spörer), 1690 (Maunder) and 1820 (Dalton) yr A.D. Cross-correlation calculations suggest that there is no significant lag between the ¹⁰Be-based ¹⁴C and the tree-ring ¹⁴C records. Our study strongly suggests the dominance of the solar modulation on the cosmonuclide production variations during the last millennium.     

Estimation of groundwater evaporation and salt flux from Owens Lake, California, USA

Groundwater evaporation and subsequent precipitation of soluble salts at Owens Lake in eastern California have created one of the single largest sources of airborne dust in the USA, yet the evaporation and salt flux have not been fully quantified. In this study, we compare eddy correlation, microlysimeters and solute profiling methods to determine their validity and sensitivity in playa environments. These techniques are often used to estimate evaporative losses, yet have not been critically compared at one field site to judge their relative effectiveness and accuracy. Results suggest that eddy correlation methods are the most widely applicable for the variety of conditions found on large playa lakes. Chloride profiling is shown to be highly sensitive to thermal and density-driven fluxes in the near surface and, as a result, appears to underestimate yearly groundwater evaporation. Yearly mean groundwater evaporation from the playa surface estimated from the three study areas was found to range from 88 to 104 mm year⁻¹, whereas mean evaporation from the brine-covered areas was 872 mm year⁻¹. Uncertainties on these mean rates were estimated to be ±25%, based on comparisons between eddy correlation and lysimeter estimates. On a yearly basis, evaporation accounts for approximately 47 × 10⁶ m³ of water loss from the playa surface and open-water areas of the lake. Over the playa area, as much as 7.5 × 10⁸ kg (7.5 × 10⁵ t) of salt are annually concentrated by evaporation at or near the playa surface, much of which appears to be lost during dust storms in area.     

The separation of the influence of nutrients and climate on the varve time-series of baldeggersee, Switzerland

The varve data-set from a freeze-core taken in the deepest part of Baldeggersee was subjected to different multivariate statistical analyses in order to estimate the amount of variance in the varve thickness measures explicable by past climate and by the trophic state of the lake. A comparison of two different time-periods (1902 to1992 versus 1920 to 1980) revealed that the lake restoration programme since 1982 has had a significant impact on the formation of the seasonal layers. Results of the partitioning of the variance in the varve thickness measures showed that about two thirds of the variance are unexplained by a climate and trophic state model and that trophic state explains 6%, whereas climate accounts for about 28% of the variance before the effect of lake restoration had a strong impact on the varves. Among the climate parameters the amount of annual precipitation is a strong predictor for explaining the thickness of both dark layer and total couplet thickness, whereas summer precipitation is important for the thickness of the light layer.     

Characteristics of VHF radiowave scintillations over a solar cycle (1983–1993) at a low-latitude station: Waltair (17.7°N, 83.3°E)

The characteristics of VHF radiowave scintillations at 244 MHz (FLEETSAT) during a complete solar cycle (1983–93) at a low-latitude station, Waltair (17.7°N, 83.3°E), are presented. The occurrence of night-time scintillations shows equinoctial maxima and summer minima in all the epochs of solar activity, and follows the solar activity. The daytime scintillation occurrence is negatively correlated with the solar activity and shows maximum occurrence during the summer months in a period of low solar activity. The occurrence of night-time scintillations is inhibited during disturbed days of high solar activity and enhanced during low solar activity.     

The sunspot cycle, the QBO, and the total ozone over Northeastern Europe: a connection through the dynamics of stratospheric circulation

The interaction between the factors of the quasi-biennial oscillation (QBO) and the 11-year solar cycle is considered as an separate factor influencing the interannual January–March variations of total ozone over Northeastern Europe. Linear correlation analysis and the running correlation method are used to examine possible connections between ozone and solar activity at simultaneous moment the QBO phase. Statistically significant correlations between the variations of total ozone in February and, partially, in March, and the sunspot numbers during the different phases of QBO are found. The running correlation method between the ozone and the equatorial zonal wind demonstrates a clear modulation of 11-y solar signal for February and March. Modulation is clearer if the QBO phases are defined at the level of 50 hPa rather than at 30 hPa. The same statistical analyses are conducted also for possible connections between the index of stratospheric circulation C₁ and sunspot numbers considering the QBO phase. Statistically significant connections are found for February. The running correlations between the index C₁ and the equatorial zonal wind show the clear modulation of 11-y solar signal for February and March. Based on the obtained correlations between the interannual variations of ozone and index C₁, it may be concluded that a connection between solar cycle – QBO – ozone occurs through the dynamics of stratospheric circulation.