Fish,Macroinvertebrate and Epifaunal Communities in Shallow Coastal Lagoons with Varying Seagrass Cover of the Northern Gulf of Mexico

Coastal lagoons are ubiquitous along coastlines worldwide. Here, we compare the abundance of epifauna, seagrass-associated macroinvertebrates, and small fish across a gradient of seagrass cover in shallow coastal lagoons of the northern Gulf of Mexico. Two of the lagoons had little or no seagrass cover (0–18.8 %), and four had high cover (83.8–97.5 %). All of the lagoons were partially covered with fringing marsh. We hypothesized that, due to habitat redundancy between seagrass beds and fringing marshes, seagrass-associated fish and macroinvertebrates would not be largely reduced despite the large differences in seagrass cover among the lagoons. Our results support this hypothesis. For most sampling dates, we did not find significant differences in fish and macroinvertebrate abundance among the lagoons and, when we did, several highly vegetated lagoons did not have larger abundances than sparsely vegetated lagoons. The extreme shallowness of the lagoons studied (<1 m) may also provide further protection from large predatory fishes in the absence of seagrasses. Our results also suggest that marsh detritus, by providing habitat for epifauna and helping maintain prey availability, may further temper reductions in seagrass-associated fishes and macroinvertebrates following seagrass decline. The results highlight the importance of marsh-bordered, shallow lagoons as habitat for small fish and macroinvertebrates regardless of seagrass cover. This study contributes to the characterization of habitat redundancy in coastal ecosystems and pinpoints the importance of considering all habitats in concert for the proper understanding and management of coastal ecosystems.     

Order classification of river watershed divides based on processing digital elevation models

The principles and the algorithm of order classification of river watershed divides are outlined. It is shown that a formal application of any available order classification procedures for river watershed divides is not theoretically grounded as well as being impractical, because the physical mechanisms for formation of watershed divide network are different from those operating in the river network. We have formulated the basic principle of determining the watershed divides order on the basis of a serial sequence of sections constituting the travel path of an arbitrary water drop from the watershed divide to the outlet section of the basin. It is suggested that the order N should be assigned to the section of the watershed divide belonging to the full divide line of the N-order basin only if the travel path from it to the N-order stream is “full” in the topological sense, i.e. includes sections of all orders, from 1 to N. Also, we present a variant of determining the order on the basis of so-called higher-order triplets, incomplete sequences of sections of three neighboring orders along the travel path, with the higher of them determining the watershed divide order. The use of triplets is a subjective procedure of generalization that eliminates the influence of recent random erosional incisions on the forms of stable high-order watersheds. We outline the variants of the technique for identifying the network of watershed divides and calculating their orders, based on processing the digital elevation models (DEM) through the use of standard GIS ArcMap tools. Results are obtained in the form of a correlated classification of river and watershed networks which are rationally interpreted and hold promise for investigating the structure, functioning and evolution of river systems. The study revealed the existence of formation “cores” of river systems, i.e. regions within which the system reaches a higher stream order and which are bounded by watersheds of the same order.     

Sources and formation conditions of ferromanganese mineralization of the Bureya and Khanka massifs,Russian Far East

The geochemical features of typical representatives of ferromanganese deposits are studied in the eastern Bureya and Khanka massifs (Russian Far East). Based on the major-, trace-, and rare-earth element distribution, the hydrothermal–sedimentary (with hydrogenic component) nature of their mineralization is established and the geodynamic setting and depth of ore formation are estimated. The differences in the depth and redox conditions of ore formation resulted in the metallogenic zonation of the Khingan block (Bureya Massif), which is expressed in a westward change in ore composition from the magnetite ores of the Kosten’ga–Kimkan zone to the hematite–magnetite and iron–manganese ores of the South Khingan zone. The conclusions about the participation of hydrothermal sources in the formation of ore mineralization of the studied deposits and the specifics of their localization require revision of the strategy of exploration and evaluation of ferromanganese ores in the southern Far East.     

Tectonics and metallogeny of the junction zone between the North Asian craton and Pacific tectonic belt

The tectonics and metallogeny of the junction zone between the North Asian craton and Pacific tectonic belt are considered. This zone is characterized by a wide variety of structures superposed on the metamorphic basement, which was formed in the course of a multistage geologic development of the craton from the Precambrian to the Cenozoic. They are related to the craton evolution and its response to the collision and subduction processes in the adjacent orogenic belt, processes in the passive and active continental margins, and plume magmatism. The geological structure of the region includes blocks of metamorphic rocks of the Aldan–Stanovoi shield, Paleoproterozoic volcanogenic troughs, Mesoproterozoic–Neoproterozoic and Early Paleozoic structures of the platform cover, Late Paleozoic volcanic and terrigenous troughs, structures of the Late Mesozoic Okhotsk–Chukotka volcanic belt of the active continental margin, and Late Cretaceous riftogenic structures formed in response to plume magmatism. In total, six metallogenic epochs are recognized in the development of ore mineralization: Archean–Early Paleoproterozoic, Late Paleoproterozoic, Mesoproterozoic, Neoproterozoic, Late Paleozoic, and Late Mesozoic. The minerageny of the junction zone between the craton and Pacific belt is highly diversified, being characterized by distinct evolution in time and space. Each development stage features its own set of mineral resources.     

Uncertainty in dam safety risk analysis

The character and importance of uncertainty in dam safety risk analysis drives how risk assessments are used in practice. The current interpretation of uncertainty is that, in addition to the aleatory risk which arises from presumed uncertainty in the world, it comprises the epistemic aspects of irresolution in a model or forecast, specifically model and parameter uncertainty. This is true in part but it is not all there is to uncertainty in risk analysis. The physics of hazards and of failure may be poorly understood, which goes beyond uncertainty in its conventional sense. There may be alternative scenarios of future conditions, for example non-stationarity in the environment, which cannot easily be forecast. There may also be deep uncertainties of the type associated with climate change. These are situations in which analysts do not know or do not agree on the system characterisation relating actions to consequences or on the probability distributions for key parameters. All of these facets are part of the uncertainty in risk analysis with which we must deal.     

Mechanistic evaluation and reaction pathway of UV photo-assisted Fenton-like degradation of progesterone in water and wastewater

The mechanisms and reaction pathway of UV photo-assisted Fenton-like degradation of progesterone in water and wastewater were investigated. The reaction followed the pseudo-first-order kinetics for both the dark Fenton-like and UV photo-Fenton-like processes. The reaction kinetics of the UV photo-assisted process improved with the presence of humic acid (HA) in wastewater, due to the formation of Fe(III)-HA complexes which enhanced Fe(II) production by a ligand-to-metal charge transfer. The UV photo-assisted process reduced the amount of ferric required to completely degrade progesterone by 60 % and lowered the activation energy to 42 kJ/mol compared to 104 kJ/mol for the dark Fenton-like process. Complete degradation of progesterone was achieved through a multi-step process involving several intermediate compounds.     

Vermiculite bio-barriers for Cu and Zn remediation: an eco-friendly approach for freshwater and sediments protection

The increase in heavy metal contamination in freshwater systems causes serious environmental problems in most industrialized countries, and the effort to find eco-friendly techniques for reducing water and sediment contamination is fundamental for environmental protection. Permeable barriers made of natural clays can be used as low-cost and eco-friendly materials for adsorbing heavy metals from water solution and thus reducing the sediment contamination. This study discusses the application of permeable barriers made of vermiculite clay for heavy metals remediation at the interface between water and sediments and investigates the possibility to increase their efficiency by loading the vermiculite surface with a microbial biofilm of Pseudomonas putida, which is well known to be a heavy metal accumulator. Some batch assays were performed to verify the uptake capacity of two systems and their adsorption kinetics, and the results indicated that the vermiculite bio-barrier system had a higher removal capacity than the vermiculite barrier (+34.4 and 22.8 % for Cu and Zn, respectively). Moreover, the presence of P. putida biofilm strongly contributed to fasten the kinetics of metals adsorption onto vermiculite sheets. In open-system conditions, the presence of a vermiculite barrier at the interface between water and sediment could reduce the sediment contamination up to 20 and 23 % for Cu and Zn, respectively, highlighting the efficiency of these eco-friendly materials for environmental applications. Nevertheless, the contribution of microbial biofilm in open-system setup should be optimized, and some important considerations about biofilm attachment in a continuous-flow system have been discussed.     

Evaluation of rainfall and wetland water area variability at Thirlmere Lakes using Landsat time-series data

Thirlmere Lakes is a group of five freshwater wetlands in the southwest fringe of Sydney, Australia, that is subject to cyclic wetting and drying. The lakes are surrounded by activities that have led to increasing pressure on the local surface and groundwater supply including farming and mining. The mine has been operating for more than 30 years, and in recent times, there has been speculation that the surface subsidence and underground pumping may have some impact on surface water and groundwater hydrology. A study was undertaken using satellite imagery to examine the relation between water area changes and rainfall variability. The study utilised Landsat time-series data during the period 1982–2014 to calculate changes in the lake water area (LA), through the normalised difference water index (NDWI) threshold. High classification accuracy was achieved using NDWI against high-resolution data that are available for the years 2008 (88.4 %), 2010 (92.8 %), and 2013 (96.9 %). The LA measurement was correlated against 11 historic observations that occurred in 2009, 2010, and 2011 during drier wetland conditions. Correlation analysis of the LA with the residual rainfall mass spread across the past 30 years has found that rainfall variability is a major dominant factor associated with the wetland changes. The underground mining operations, if verified by independent investigations, probably play a minor or negligible contributor to variations in total wetland area during the study period. This study has demonstrated that remote sensing is a technique that can be used to augment limited historic data.     

Activated sludge acclimation for toluene and DEHP degradation in a two-phase partitioning bioreactor

The effect of activated sludge acclimation on the biodegradation of toluene in the presence of a biodegradable non-aqueous phase liquid, di (2-ethylhexyl) phthalate (DEHP), in a two-phase partitioning bioreactor was characterized. The influence of the presence of DEHP, at a ratio of 0.1 % (volume ratio), and of the acclimation of activated sludge (AS) on the biodegradation of hydrophobic VOC was studied. AS was acclimated to both toluene and DEHP simultaneously. Using acclimated cells, 73 and 96 % improvement of the mean biodegradation rates was recorded for toluene and the organic solvent (DEHP), respectively, if compared to the values recorded in the absence of acclimation, during tests performed in Erlenmeyer flasks. Degradation rates were further improved by the use of acclimated AS in a reactor with a large head space; degradation yields for toluene and DEHP were above 99 and 89 %, respectively.