Investigation of natural and anthropogenic hydrocarbon inputs in sediments using geochemical markers. I. Santos, SP--Brazil

A study on the inputs of organic matter to marine sediments of Santos Bay and Estuary, located in southeastern S?o Paulo State, Brazil, is presented here. The following geochemical markers were identified and quantified: aliphatic hydrocarbons (normal and isoprenoid alkanes), petroleum biomarkers, linear alkylbenzenes (LABs) and polycyclic aromatic hydrocarbons (PAHs). Sediment samples, collected at 15 sites in the bay and surrounding channels, were extracted and analyzed by gas chromatography with flame ionization and mass spectrometer detectors. Total concentrations varied from 0.17 to 107.80 microg g(-1) for aliphatics, from 47.2 to 2560.1 ng g(-1) for petroleum biomarkers, from 16.9 to 430.6 ng g(-1) for LABs and from 79.6 to 15389.1 ng g(-1) for PAHs. Anthropogenic contributions were apparent, indicating the influences of the Cubatao industrial complex, sewage outfalls along the area, the waste deposit of Santos city and storage facilities for petroleum and derivatives, based on the higher concentrations of geochemical markers detected.     

Crude oil bioremediation in sub-Antarctic intertidal sediments: chemistry and toxicity of oiled residues

The effectiveness of fertilizers for crude oil bioremediation in sub-Antarctic intertidal sediments was tested over a one-year period in a series of ten (10) experimental enclosures. Chemical, microbial and toxicological parameters demonstrated the effectiveness of various fertilizers in a pristine environment where hydrocarbon degrading bacteria (HDB) had not been stimulated by previous accidental spills or human activities. The low temperature of seawater (3-4 degrees C) had no obvious effects on the HDB community and the bioremediation process. Over 90% of n-alkanes were degraded in the first six months and most light aromatics (2-3 rings) disappeared during the first year of observation. The toxicity of oiled residues (Microtox(R) SP) was significantly reduced in the first 6 months of the process, but it increased again in the last months of the experiment. One of the fertilizers containing fishbone compost enriched with urea, inorganic phosphorus and a lipidic surfactant reduced significantly the toxicity of oil residues in the last 3 months of the experiment. Interstitial waters collected below the oil slicks during the remediation showed no toxicity, and even stimulated Vibrio fischeri. When comparing all fertilizers to the control plots, a good correlation (r(2)=0.82) was found between the growth rate of HDB and the degradation rate of n-alkanes in the first 90 days of the experiment only indicating that fertilizers were efficient for at least 3 months but their beneficial effects were lost after 6 months.     

Depth-related influences on biodegradation rates of phenanthrene in polluted marine sediments of Puget Sound, WA

A whole-core injection method was used to determine depth-related rates of microbial mineralization of (14)C-phenanthrene added to both contaminated and clean marine sediments of Puget Sound, WA. For 26-day incubations under micro-aerobic conditions, conversions of (14)C-phenanthrene to (14)CO(2) in heavily PAH-contaminated sediments from two sites in Eagle Harbor were much higher (up to 30%) than those in clean sediments from nearby Blakely Harbor (<3%). The averaged (14)C-phenanthrene degradation rates in the surface sediment horizons (0-3 cm) were more rapid (2-3 times) than in the deeper sediment horizons examined (>6 cm), especially in the most PAH polluted EH9 site. Differences in mineralization were associated with properties of the sediments as a function of sediment depth, including grain-size distribution, PAH concentration, total organic matter and total bacterial abundance. When strictly anaerobic incubations (in N(2)/H(2)/CO(2) atmosphere) were used, the phenanthrene biodegradation rates at all sediment depths were two times slower than under micro-aerobic conditions, with methanogenesis observed after 24 days. The main rate-limiting factor for phenanthrene degradation under anaerobic conditions appeared to be the availability of suitable electron acceptors. Addition of calcium sulfate enhanced the first order rate coefficient (k(1) increased from 0.003 to 0.006 day(-1)), whereas addition of soluble nitrate, even at very low concentration (<0.5 mM), inhibited mineralization. Long-term storage of heavily polluted Eagle Harbor sediment as intact cores under micro-aerobic conditions also appeared to enhance anaerobic biodegradation rates (k(1) up to 0.11 day(-1)).     

Atmospheric lead fallout over the last century recorded in Gulf of Lions sediments (Mediterranean Sea)

Six marine sediment cores from the Gulf of Lions continental slope (700-1700 m water depth) were analyzed for stable lead isotopes and (210)Pb geochronology in order to reconstruct lead atmospheric fallout pattern during the last century. The detrital lead contribution is 25 microg g(-1) and the mean sediment anthropogenic inventory is 110+/-7 microg cm(-2), a little bit higher than atmospheric deposition estimate. Anthropogenic lead accumulation in sediments peaked in early 1970s (1973+/-2) in agreement with lead emissions features. For the period 1986-1997, the sediment signal also reflect the decrease of atmospheric lead described by independent atmospheric fallout investigations. The anthropogenic Pb deposition in the late 1990s was similar to the 1950s deposition, attesting thus of the output of European environmental policies.     

基于分类回归树分析的遥感影像土地利用／覆被分类研究

以专家知识和经验为基础,综合影像光谱信息和其他辅助信息进行分类的基于知识的遥感影像解译方法,是提高遥感影像分类精度,实现自动解译的有效途径之一。然而,知识的获取一直是其得以广泛应用的“瓶颈”问题。以江苏省江宁试验区土地利用/覆被分类为例,利用分类回归树分析(CART)从训练样本数据集中发现分类规则,集成遥感影像的光谱特征、纹理特征和空间分布特征进行分类实验,并与传统的监督分类和逻辑通道分类方法进行比较。结果表明,基于CART的分类方法的精度基本在80%以上,与另两种方法相比,有了较大的提高,而且该算法复杂性低,效率高。由此说明,利用CART算法构建决策树获取的分类规则是合理的。它可以快速、有效地获取大量分类规则,是促进基于知识的遥感影像分类方法在土地利用/覆被分类中广泛应用的一项有效手段。     

基于植被状态指数的全国干旱遥感监测试验研究(Ⅰ)--资料分析与处理部分

在收集处理了了1981～1994年连续504旬的由NOAA AVHRR第1、2通道的反射率计算得的NDVI时间系列数据,以及1980～1994年全国102个固定农气观测站的旬土壤湿度资料(-20cm)和相应测站的田间持水量资料基础上,分析了全国NDVI及植被状态指数VCI的时空变化特征,发现NDVI值随季节(旬)分别表现为“双峰型”和“单峰型”的变化,在第17～27旬之间达到极大值,并与作物生长有关,VCI的变化与NDVI的变化呈相反趋势;对资料因站点的分布和密度以及时序位相等差异可能影响资料代表性的探讨认为：因旱情发展有一个过程,故NDVI、SHI的时空特性应该不会影响其分析结果的代表性。综合分析了资料的时空代表性,为干旱遥感监测模型的建立作准备。     

岛弧橄榄岩包体从地幔楔到地壳的旅行

岛弧岩浆作为俯冲作用的产物不仅可以理解大陆地壳的形成,而且对指示大陆地壳的循环作用具有重要的意义。目前关于岛弧岩浆的源区交代作用和分异深度等相关问题一直存在争议。其中,弧岩浆的结晶分异究竟发生在莫霍面附近并伴随着堆晶岩的拆沉,还是发生在更浅的地壳深度?     

植物挥发性有机物的初步研究

2000年1～6月期间,美国国家大气研究中心(NCAR)和中国科学院大气物理研究所的科学家发展了一套自动的气相色谱系统和分析方法,用于分析大气中的挥发性有机物.此系统性能稳定,重复性好,对美国大气研究中心附近的大气进行了采样分析.作者简单介绍了此自动系统以及采样分析结果.     

GEOLOGICAL STUDY OF THE DEPOSITS OF THE SANGKANHO BASIN.

This paper offers a preliminary statement of the results of investigations carried out in the South Sangkanho basin, in the mountains some 80 miles to the NW of Peking. Important fossiliferous deposits found in this area throw light on the conditions ruling in N. China during the transition from Pliocene