Elemental (C,N, H and P) and stable isotope (δ<Superscript>15</Superscript>N and δ<Superscript>13</Superscript>C) signatures in sediments from Zeekoevlei,South Africa: a record of human intervention in the lake

We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ¹³C and δ¹⁵N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ¹³C_organic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle (18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant, rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent with this, measured δ¹⁵N_organic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are evident from the low δ¹⁵N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high TP (100–2,200 mg l⁻¹) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation in the upper mid-section (12–14 cm) of the core.     

A sedimentary record of the rise and fall of the metal industry in Bergslagen,south central Sweden

Detailed stratigraphic analyses of sediments deposited in Lake Botjärnen, a small boreal forest lake in the shield terrain of central Sweden, clearly reflect progressively increasing human impact on terrestrial and aquatic ecosystems following settlement and establishment of an iron industry in the 17th century. Rising frequencies of pollen and spores from light-demanding plants provide evidence of extensive forest clearance for charcoal and timber production, which peaked in the early 20th century. An associated increase in catchment erosion is reflected by changing carbon and nitrogen elemental content and carbon–isotope composition of sediment organic matter and by increased magnetic susceptibility of the sediments. Records of air-borne pollutants (lead, zinc and sulphur) can be correlated to the development of local and regional mining and metal industry as inferred from historical accounts. Rapid recession of the iron industry led to re-forestation and recovery of the aquatic nutrient status to pre-industrial conditions over the past 100 years. The chronology of the sediment succession, which is based on ²¹⁰Pb and ¹³⁷Cs radionuclide data in combination with radiocarbon dating, is confirmed by historical lead pollution trends established for the region.     

Progress in isotope paleohydrology using lake sediment cellulose

Recent advances in sample preparation techniques and mass spectrometry have fostered more routine oxygen isotope analysis of aquatic cellulose in lake sediment cores, a proxy for lake water oxygen isotope history. These methodological developments have significantly increased the feasibility of incorporating this approach into high-resolution, multi-site, and multi-proxy studies, which are frequently necessary to answer complex hydrological, hydroecological and hydroclimatic questions requiring a paleoenvironmental perspective. Direct translation of lake sediment aquatic cellulose oxygen isotope composition into lake water oxygen isotope composition offers appreciable opportunity for quantitative paleohydrological reconstructions, as evidenced by studies conducted over the past 15 years that span Holocene and pre-historical timescales.     

Late Quaternary paleoenvironments of an ephemeral wetland in North Dakota,USA: relative interactions of ground-water hydrology and climate change

This study of fossils (pollen, plant macrofossils, stomata and fish) and sediments (lithostratigraphy and geochemistry) from the Wendel site in North Dakota, USA, emphasizes the importance of considering ground-water hydrology when deciphering paleoclimate signals from lakes in postglacial landscapes. The Wendel site was a paleolake from about 11,500 ¹⁴C yr BP to 11,100 ¹⁴C yr BP. Afterwards, the lake-level lowered until it became a prairie marsh by 9,300 ¹⁴C yr BP and finally, at 8,500 ¹⁴C yr BP, an ephemeral wetland as it is today. Meanwhile, the vegetation changed from a white spruce parkland (11,500 to 10,500 ¹⁴C yr BP) to deciduous parkland, followed by grassland at 9,300 ¹⁴C yr BP. The pattern and timing of these aquatic and terrestrial changes are similar to coeval kettle lake records from adjacent uplands, providing a regional aridity signal. However, two local sources of ground water were identified from the fossil and geochemical data, which mediated atmospheric inputs to the Wendel basin. First, the paleolake received water from the melting of stagnant ice buried under local till for about 900 years after glacier recession. Later, Holocene droughts probably caused the lower-elevation Wendel site to capture the ground water of up-gradient lakes.     

Paleolimnological assessment of human impacts on an urban South African lake

North End Lake is a polluted and eutrophic freshwater system located in Port Elizabeth, South Africa. Since the lake is expected to be used for recreational/tourist purposes by 2010, a rehabilitation program will have to be designed. For this reason, we retrieved a sediment core from the central region of the lake to decipher the effect of historical human impacts on the water body. Pre-disturbance paleolimnological inferences indicate that the lake was likely mesotrophic. After ∼1831, when sheep farming activities were undertaken in the catchment, increases in trophic state and changes in sediment composition were observed. After ∼1937, increases in trace metal levels, organic matter, spheroidal carbonaceous particles (SCP) and changes in sediment composition were recorded. The system became eutrophic as indicated by the dominance of the diatom Actinocyclus normanii, a cosmopolitan species often observed in systems where water quality has been dramatically degraded. The conditions worsened after 1986 because of the construction of a storm-water retention system, which intentionally channeled storm-water runoff into the lake. Because of this, extremely high values of fecal coliforms (i.e. 2 × 10⁶ every 100 ml) have been measured in the water column. The paleolimnological information identified the sharp increase in organic content in the uppermost section of the core, and this could be correlated to the operation of the storm-water retention system. Therefore, as an immediate management measure, we suggest that the storm-water retention system should either no longer be utilized, or the storm-water runoff should be treated before disposal into the lake. In addition, an effective sewage system has to be constructed.     

Spatial Analysis Techniques as Successful Mineral-Potential Mapping Tools for Orogenic Gold Deposits in the Northern Fennoscandian Shield,Finland

Geoscientific Information Systems (GIS) provide tools to quantitatively analyze and integrate spatially referenced information from geological, geophysical, and geochemical surveys for decision-making processes. Excellent coverage of well-documented, precise and good quality data enables testing of variable exploration models in an efficient and cost effective way with GIS tools. Digital geoscientific data from the Geological Survey of Finland (GTK) are being used widely as spatial evidence in exploration targeting, that is ranking areas based on their exploration importance. In the last few years, spatial analysis techniques including weights-of-evidence, logistic regression, and fuzzy logic, have been increasingly used in GTK’s mineral exploration and geological mapping projects. Special emphasis has been put into the exploration for gold because of the excellent data coverage within the prospective volcanic belts and because of the increased activity in gold exploration in Finland during recent years. In this paper, we describe some successful case histories of using the weights-of-evidence method for the Au-potential mapping. These projects have shown that, by using spatial modeling techniques, exploration targets can be generated by quantitatively analyzing extensive amounts of data from various sources and to rank these target areas based on their exploration potential.     

Mesozoic interaction of the Kula plate and the western margin of north america

Oceanic crust west of North America at the beginning of the Jurassic belonged to the Kula plate. The development of the western margin of North America since the Jurassic reflects interaction with the Kula plate, the Kula-Farallon spreading center and the Farallon plate. The Kula plate ceased to exist in the Paleocene and later developments were caused by interaction of the Farallon plate and, subsequently, collision with the East Pacific Rise.At the beginning of the Jurassic, when spreading between North and South America began, the Kula-Farallon-Pacific triple junction moved to the north relative to North America, and the eastern end of the Kula-Farallon spreading center swept northwards along the continental margin.During the Paleocene, Kula-Pacific spreading ceased and the Kula plate fused to the Pacific plate. Throughout the Mesozoic, subduction of the Kula plate took place along the Alaskan continental margin. When the Kula plate joined the Pacific plate a new subduction zone formed along the line of the present Aleutian chain.Wrangellia and Stikinia, anomalous terrains in Alaska and northwestern Canada respectively, were emplaced by transport on the Kula plate from lower latitudes. Hypotheses which require transport of these plates in the Mesozoic from the “far reaches of the Pacific” ignore the problem of transport across either the Kula-Pacific or Kula-Farallon spreading centers. The interaction of the Kula plate and western North America throughout the Jurassic and the Cretaceous should result in emplacement of these terrains by motion oblique to the continental margin. Tethyan faunas in Stikinia must come from the western end of Tethys between North and South America, not the Indonesian region at the eastern end of Tethys.As the northeastern end of the Kula-Farallon ridge moved northward, the sense of motion changed from right lateral shear between the Kula and North American plates to collision or left lateral shear between the Farallon and North American plates. Left lateral shear along zones analogous to the Mojave-Sonora megashear may have been the means by which anomalous terrains were transported to the southeast into the gap between North and South America forming present day Central America. Such a model overcomes the overlap difficulties suffered in previous attempts to reconstruct the Mesozoic paleogeography of Central America.     

Fission tracks in minerals: Annealing kinetics,track structure and age correction

It is shown that the annealing kinetics of fission tracks in apatite can be described by a sum of exponential decay functions. From an analysis of the temperature dependence of this annealing law it is concluded that the etchability of fission tracks is due to extended defects, i.e. systems of dislocation loops. The multiexponential annealing law is also applied to prove that the plateau correction method is basically correct, but rather as a method for determining a lower limit than the “true” fission track age.     

Quantitative studies of weathering in saprolitized charnockites associated with a landslip zone at the porthimund dam,India

Studies on saprolitized charnockites associated with a landslip observed in the Blue Mountains in close proximity of the Porthimund Dam (11°22'E 76°34′30″N), Nilgiris District, Tamilnadu State, South India, are reported.Laboratory investigations of the geotechnical properties were carried out to evaluate the nature and degree of weathering quantitatively for estimating the soundness of the charnockites constituting the slip zone. The results of per cent decomposed product of the crest, scarp and toe portions of the slip denote positive correlations with porosity and compressibility; and negative correlations against density, wave velocity, Young's modulus, compressive strength and tensile strength. It is also seen that in the absence of the information on decomposed product, weatherability could still be evaluated considering the per cent change of any physical parameter.Such studies should prove valuable in the mapping of weatherability zones and the assessment and determination of foundation conditions.