Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment

Indirect nitrous oxide (N₂O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N₂O emissions from soils. In this study, dissolved N₂O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N₂O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N₂O emissions to the atmosphere. Soil texture was found to significantly influence field drain N₂O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L^?1) being greater than drains in sandy loam soils (4.0 μg N L^?1). Soil texture also impacted upon the relationships between field drain N₂O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO₃) and nitrite (NO₂) concentrations), highlighting possible differences in N₂O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N₂O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N₂O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N₂O concentrations, whereas higher N₂O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N₂O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.     

Depositional environments and facies of the Late Triassic Abu Ruweis Formation, Jordan

The Abu Ruweis Formation is composed of carbonates, evaporites, and mudstones, with some locally developed pelletic, oolitic and stromatolitic limestones. The lateral persistence of bedding, the purity of the evaporite rocks, the alternating arrangement of marine carbonates and evaporites indicates periodic deposition in subaqueous conditions (salina). Petrographic investigations, X-ray diffraction analysis as well as chemical analysis have shown that the outcropping evaporite beds are mainly composed of secondary gypsum, with rare anhydrite relics. Five microfacies of gypsum were recognized according to their fabrics: porphyroblastic and granoblastic gypsum showing polarization texture, gypsum pseudomorph after anhydrite laths, and satin spar gypsum. The textures they display indicate a hydration origin of precursor anhydrite, which is in turn rehydrated from primary gypsum. Some of these anhydrites were formed as a result of replacement processes of the carbonate sediments associated with the evaporites, as evidenced from the textural relationships of the carbonate and sulfate minerals. The O¹⁸ content ranges from 1.45 to 8.38% PDB and the C¹³ content ranges from −1.52 to 4.73% PDB. Trace elements analysis has shown that the Abu Ruweis dolomites are rich in strontium (up to 600 ppm), and sodium (up to 835 ppm). The isotope composition and trace elements content, as well as the petrographic characteristics point to a penecontemporaneous hypersaline dolomitization origin for the Abu Ruweis dolomites. The evaporites were deposited during a regressive lowstand systems tract, whereas the carbonates were deposited under shallow water marine conditions during a highstand systems tract. The Abu Ruweis succession represents a relatively stable arid climate within a rapidly subsiding basin. Restricted conditions were provided by the development of beach barriers.     

A Comparative Study of Landsat‐7 and Landsat‐8 Data Using Image Processing Methods for Hydrothermal Alteration Mapping

Comparing spaceborne satellite images of Landsat‐8 Operational Land Imager (OLI) and Landsat‐7 Enhanced Thematic Mapper plus (ETM+) was undertaken to investigate the relative accuracy of mapping hydrothermal alteration minerals. The study investigated the northern part of Rabor, which contains copper mineralization occurrences, and is located in the Kerman Cenozoic magmatic assemblage (KCMA), Iran. Image processing methods of band ratio, principal component analysis (PCA), and spectral angle mapper (SAM) were used to map the distribution of hydrothermally altered rocks associated with the porphyry copper mineralization. The band ratio combination of both sensors for mapping altered areas showed similar outcomes. PCA exposed variations in the spatial distribution of hydroxyl‐bearing minerals. The representation of hydrothermal areas using OLI data was more satisfactory than when using ETM+ data. SAM analysis found similar results for mapping hydroxyl‐bearing zones. Verification of the results came through ground investigation and laboratory studies. Rock samples (n = 56) were collected to validate results using thin sections, X‐ray diffraction (XRD) and spectral analyses. Field observations and laboratory analysis revealed that phyllic and propylitic alterations dominate the alteration zones in the study area. Argillic and iron oxides/hydroxides alterations were observed to a lesser degree. The results indicate that alteration maps prepared by OLI data using PCA for visual interpretation are more suitable than those of ETM+ due to a higher radiometric resolution and lower interference between vegetation and altered areas. As the spectral bandwidth of ETM+ band 7 covers absorption feature of propylitic alteration, better mapping of propylitic alterations is achieved using ETM+ data.     

Investigation of Various Parameters Effect on Cerchar Abrasivity Index with PFC3D Modeling

The Cerchar test is one of the appropriate and routine tests for determining the rock abrasion; but as for the costs and pin wear measurement errors in laboratory procedures and lack of access to laboratory equipment, using of numerical modeling can lead to use of greater number of samples required during the course of mechanized excavation and reduce the costs and errors in the laboratory test. In this study, the Cerchar abrasivity test was modeled using PFC3D (Particle Flow Code in 3 Dimensions) software. In order to verify the simulation results, Cerchar laboratory test results obtained by Rostami (Rock Mech Rock Eng 47(5):1905–1919, 2014) were compared with the numerical modeling results. In modeling studies, the effects of some parameters such as apply load, test speed, pin hardness and scratching distance on pin wear were investigated. As a conclusion of the study, good agreement between modeling and experimental results was obtained for a given condition. As in the experiment with various loads in both laboratory tests and modeling, with increasing applied load the Cerchar abrasivity index also increased in the experiment with Rockwell hardness HRC (An abbreviation for Rockwell Hardness measured on the C scale. The Rockwell test determines the hardness by measuring the depth of penetration of an indenter under a large load compared to the penetration made by a preload, that on the C scale use from a indenter with 120° cone and 150 kgf load) 42.     

The effectiveness of the very low frequency electromagnetic method (VLF-EM) in the exploration of sulphide mineralization in arid environments,case study from South Sinai Peninsula,Egypt

Very low frequency electromagnetic (VLF-EM) measurements were carried out in Wadi Isbayia area, south Sinai Peninsula, to test the efficiency of the VLF-EM method in the exploration of sulphide mineralization in arid environments. The VLF-EM field measurements, including tilt angle, real and imaginary components of the received VLF field, were carried out along fifteen profiles covering a quartz monzonite bedrock. Interpretation of the VLF measurements, in the light of geological information, has showed that sulphide minerals in the Wadi Isbayia area extend from the ground surface to a depth of about 200 m. However, the structural lineaments, especially faults, have controlled the distribution of the sulphide mineralization. A few of polished sections for rock samples, collected from the sites of the VLF-EM anomalies in the study area, have been prepared and examined by ore microscopy which confirmed the presence of pyrite and chalcopyrite as well as iron oxides, disseminated in the quartz monzonite bedrock. These results showed that the VLF-EM method is an effective tool in the exploration of sulphide minerals in the arid environments.     

Optimization of a Photo‐assisted Fenton Oxidation Process: A Statistical Model for MDF Effluent Treatment

In the present study, the effects of initial COD (chemical oxygen demand), initial pH, Fe²⁺/H₂O₂ molar ratio and UV contact time on COD removal from medium density fiberboard (MDF) wastewater using photo‐assisted Fenton oxidation treatment were investigated. In order to optimize the removal efficiency, batch operations were carried out. The influence of the aforementioned parameters on COD removal efficiency was studied using response surface methodology (RSM). The optimal conditions for maximum COD removal efficiency from MDF wastewater under experimental conditions were obtained at initial COD of 4000 mg/L, Fe²⁺/H₂O₂ molar ratio of 0.11, initial solution pH of 6.5 and UV contact time of 70 min. The obtained results for maximum COD removal efficiency of 96% revealed that photo‐assisted Fenton oxidation is very effective for treating MDF wastewater.     

MAROS: a decision support system for optimizing monitoring plans

The Monitoring and Remediation Optimization System (MAROS), a decision-support software, was developed to assist in formulating cost-effective ground water long-term monitoring plans. MAROS optimizes an existing ground water monitoring program using both temporal and spatial data analyses to determine the general monitoring system category and the locations and frequency of sampling for future compliance monitoring at the site. The objective of the MAROS optimization is to minimize monitoring locations in the sampling network and reduce sampling frequency without significant loss of information, ensuring adequate future characterization of the contaminant plume. The interpretive trend analysis approach recommends the general monitoring system category for a site based on plume stability and site-specific hydrogeologic information. Plume stability is characterized using primary lines of evidence (i.e., Mann-Kendall analysis and linear regression analysis) based on concentration trends, and secondary lines of evidence based on modeling results and empirical data. The sampling optimization approach, consisting of a two-dimensional spatial sampling reduction method (Delaunay method) and a temporal sampling analysis method (Modified CES method), provides detailed sampling location and frequency results. The Delaunay method is designed to identify and eliminate redundant sampling locations without causing significant information loss in characterizing the plume. The Modified CES method determines the optimal sampling frequency for a sampling location based on the direction, magnitude, and uncertainty in its concentration trend. MAROS addresses a variety of ground water contaminants (fuels, solvents, and metals), allows import of various data formats, and is designed for continual modification of long-term monitoring plans as the plume or site conditions change over time.     

Damage Estimation in Masonry Buildings Based on Excavation-Induced Ground Movements

Excavation-induced ground movements and the resulting damages to adjacent structures and facilities is a source of concern for excavation projects in urban areas. The concern will be even higher if the adjacent structure is old or has low strength parameters like masonry building. Frame distortion and crack generation are predictors of building damage resulted from excavation-induced ground movements, which pose challenges to projects involving excavations. This study is aimed to investigate the relation between excavation-induced ground movements and damage probability of buildings in excavation affected distance. The main focus of this paper is on masonry buildings and excavations stabilized using soil nail wall method. To achieve this purpose, 21 masonry buildings adjacent to 12 excavation projects were studied. Parametric studies were performed by developing 3D FE models of brick walls and excavations stabilized using soil nail wall. Finally, probability evaluations were conducted to analyze the outputs obtained from case studies. Based on the obtained results, simple charts were established to estimate the damage of masonry structures in excavation affected distance with two key parameters including “Displacement Ratio” and “Normalized Distance”. The results also highlight the effects of building distance from excavation wall on its damage probability.

     

The impact of neighborhood services on land values: an estimation through the hedonic pricing model

A strong need exists to increase the knowledge and recognize the values of neighborhood services. This paper makes an attempt to examine the impact of neighborhood services on land values, through analysis based on results obtained from multi linear regression analysis. This case study was done in area of dense urban settlement to check the consequence of neighborhood services through the hedonic pricing model base variables which include the structural, locational, community and neighborhood services. The regression coefficient was checked at (p?<?0.05) level of significance for each variable. The primary data was collect through the questionnaire filling by random sampling and Punjab Urban Gazette was used for the verification of land values in study area. The results found a valuable potential on land and property values of neighborhood services through the regression analysis results express through R (0.926), R² (0.856) and coefficient tables to represent the effect of each individual variable on property and land values. Every individual variable play role in defining the values of land and property based upon its utilization such as larger the structure of a property, more the covered area, larger size of a property more the land area higher price. Similarly, for locational factor study in geography, a piece of land adjacent to the road have high land values 50–70% compare to those located at distance. Very less attention has been paid on such issues in the world due to lack of effective urban planning and research on such crucial issues. If empirical studies on such issue has been done, effective way can be obtained for urban planning.

     

Synthesis of biochar from sugarcane filter-cake and its impacts on physiological performance of lettuce (<Emphasis Type="Italic">Lettuce sativa</Emphasis>) grown on cadmium contaminated soil

Soil contamination with cadmium has become major concern all over the world because of its adverse impacts on ecosystem health and agricultural land. Soil amendment with biochar may have varied effects on physical and chemical properties of soil. The objective of the study was to explore the impact of sugarcane filter-cake biochar on physiological performance and growth of lettuce in an aged soil. Four different doses (0, 1.5%, 3%, and 5%) of biochar were used in the soil and conditioned for 1 month. After this, lettuce seedlings were grown in the soil. The results showed that the biochar treatment improved the fresh and dry biomass of leaves and roots as well as plant height while diminished the bioavailability of cadmium from the soil. As compared to control, biochar significantly enhanced the chlorophyll content in lettuce leaves. Due to the biochar amendment, the oxidative stress decreased in lettuce shoots over the control. As compared to control, concentration of cadmium in lettuce significantly decreased after the application of biochar. It was concluded that biochar could mitigate the toxicity of cadmium in lettuce by altering the biochemical and physiological processes in cadmium contaminated soil.