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41.
Lin-gun Liu C.-C. Lin Y. J. Yung T. P. Mernagh T. Irifune 《Physics and Chemistry of Minerals》2009,36(3):143-149
K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of
the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric
pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing
temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands
appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition
is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed
earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase,
microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure. 相似文献
42.
Nicola Nocilla Aldo Evangelista Anna Scotto di Santolo 《Rock Mechanics and Rock Engineering》2009,42(5):815-833
In recent years, rock fall phenomena in Italy have received considerable attention for risk mitigation through in situ observations
and experimental data. This paper reports the study conducted at Camaldoli Hill, in the urban area of Naples, and at Monte
Pellegrino, Palermo, Italy. The rocks involved are volcanic Neapolitan yellow tuff (NYT) in the former area and dolomitic
limestone in the latter. Both rocks, even though with different strength characteristics, have shown a significant tendency
towards rock fragmentation during run out. This behavior was first investigated by comparing the volumes of removable blocks
on the cliff faces (V
0) and fallen blocks on the slopes (V
f). It was assumed that the ratio V
f/V
0 decreases with the distance (x
f) from the detachment area by an empirical law, which depends on a coefficient α, correlated with the geotechnical properties of the materials involved in the rock fall. Finally, this law was validated
by observation of well-documented natural rock falls (Palermo) and by in situ full-scale tests (Naples). From the engineering
perspective, consideration of fragmentation processes in rock fall modeling provides a means for designing low-cost mitigation
measures. 相似文献
43.
The climate–population relationship has long been conceived. Although the topic has been repeatedly investigated, most of
the related works are Eurocentric or qualitative. Consequently, the relationship between climate and population remains ambiguous.
In this study, fine-grained temperature reconstructions and historical population data sets have been employed to statistically
test a hypothesized relationship between temperature change and population growth (i.e., cooling associated with below average
population growth) in China over the past millennium. The important results were: (1) Long-term temperature change significantly
determined the population growth dynamics of China. However, spatial variation existed, whilst population growth in Central
China was shown to be responsive to both long- and short-term temperature changes; in marginal areas, population growth was
only sensitive to short-term temperature fluctuations. (2) Temporally, the temperature–population relationship was obscured
in some periods, which was attributable to the factors of drought and social buffers. In summary, a temperature–population
relationship was mediated by geographic factors, the aridity threshold, and social factors. Given the upcoming threat posed
by climate change to human societies, this study seeks to improve our knowledge and understanding of the climate–society relationship. 相似文献
44.
María Charco José Fernández Francisco Luzón Kristy F. Tiampo John B. Rundle 《Pure and Applied Geophysics》2007,164(4):865-878
Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic,
elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While
elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic
relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater
extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in
the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method
to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography
has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic
signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in
areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation
and gravity changes depend on such effects. 相似文献
45.
UV attenuation in the cloudy atmosphere 总被引:1,自引:0,他引:1
Jianhui Bai 《Journal of Atmospheric Chemistry》2009,62(3):211-228
Ultraviolet (UV) energy absorption plays a very important role in the Earth–atmosphere system. Based on observational data
for Beijing, we suggest that some atmospheric constituents utilize or transfer UV energy in chemical and photochemical (C&P) reactions, in addition to those which absorb UV energy directly. These constituents are primarily volatile organic compounds
(VOCs) emitted from both vegetative and anthropogenic sources. The total UV energy loss in the cloudy atmosphere for Beijing
in 1990 was 78.9 Wm−2. This attenuation was caused by ozone (48.3 Wm−2), other compounds in the atmosphere (26.6 Wm−2) and a scattering factor (4.0 Wm−2). Our results for a cloudy atmosphere in the Beijing area show that the absorption due to these other compounds occurs largely
through the mediation of water vapor. This fraction of energy loss has not been fully accounted for in previous models. Observations
and previous models results suggest that 1) a cloudy atmosphere absorbs 25∼30 Wm−2 more solar shortwave radiation than models predict; and 2) aerosols can significantly decrease the downward mean UV-visible
radiation and the absorbed solar radiation at the surface by up to 28 and 23 Wm−2, respectively. Thus, quantitative study of UV and visible absorption by atmospheric constituents involved in homogeneous
and heterogeneous C&P reactions is important for atmospheric models. 相似文献
46.
José Luís Argaín Miguel A. C. Teixeira Pedro M. A. Miranda 《Boundary-Layer Meteorology》2017,165(1):145-160
A method is proposed for estimating the surface-layer depth \((z_s)\) and the friction velocity \((u_*)\) as a function of stability (here quantified by the Obukhov length, L) over the complete range of unstable flow regimes. This method extends that developed previously for stable conditions by Argaín et al. (Boundary-Layer Meteorol 130:15–28, 2009), but uses a qualitatively different approach. The method is specifically used to calculate the fractional speed-up \((\varDelta S)\) in flow over a ridge, although it is suitable for more general boundary-layer applications. The behaviour of \(z_s \left( L\right) \) and \(u_*\left( L\right) \) as a function of L is indirectly assessed via calculation of \(\varDelta S\left( L\right) \) using the linear model of Hunt et al. (Q J R Meteorol Soc 29:16–26, 1988) and its comparison with the field measurements reported in Coppin et al. (Boundary-Layer Meteorol 69:173–199, 1994) and with numerical simulations carried out using a non-linear numerical model, FLEX. The behaviour of \(\varDelta S\) estimated from the linear model is clearly improved when \(u_*\) is calculated using the method proposed here, confirming the importance of accounting for the dependences of \(z_s\left( L \right) \) and \(u_*\left( L \right) \) on L to better represent processes in the unstable boundary layer. 相似文献
47.
Juan Huang Yanli Feng Jian Li Bin Xiong Jialiang Feng Sheng Wen Guoying Sheng Jiamo Fu Minghong Wu 《Journal of Atmospheric Chemistry》2008,61(1):1-20
The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering
winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls
were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of
19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m−3 respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with
peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer
and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed
obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected
in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution
of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher
concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants
from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou,
the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in
Shanghai was even worse than expected. 相似文献
48.
General purpose Computational Fluid Dynamics (CFD) solvers are frequently used in small-scale urban pollution dispersion simulations
without a large extent of ver- tical flow. Vertical flow, however, plays an important role in the formation of local breezes,
such as urban heat island induced breezes that have great significance in the ventilation of large cities. The effects of
atmospheric stratification, anelasticity and Coriolis force must be taken into account in such simulations. We introduce a
general method for adapting pressure based CFD solvers to atmospheric flow simulations in order to take advantage of their
high flexibility in geometrical modelling and meshing. Compressibility and thermal stratification effects are taken into account
by utilizing a novel system of transformations of the field variables and by adding consequential source terms to the model
equations of incompressible flow. Phenomena involving mesoscale to microscale coupled effects can be analyzed without model
nesting, applying only local grid refinement of an arbitrary level. Elements of the method are validated against an analytical
solution, results of a reference calculation, and a laboratory scale urban heat island circulation experiment. The new approach
can be applied with benefits to several areas of application. Inclusion of the moisture transport phenomena and the surface
energy balance are important further steps towards the practical application of the method. 相似文献
49.
Mark Anglin Harris 《Environmental Geology》2009,56(8):1517-1522
Several years (7) after incidental lithification by added gypsum, the effect of crushing and phyto-organics on some physical
properties of red mud wastes (RMW) was examined under laboratory conditions. It was hypothesized that mechanically breaking
up the hardened masses would increase their permeability. However, on the contrary, crushing these rock-hard masses into <2-mm
particles did not increase permeability. A phyto-organic treatment on the other hand greatly improved permeability of the
crushed entities such that infiltration rates increased from 0 to 10 cm/h. After 24 weeks of incubation, the structure of
the newly formed phyto-organically treated gypsum-hardened RMW aggregates was also substantially improved over that of the
controls, as a >3-fold increase in resistance to disintegration during wet sieving was exhibited by the phyto-organically
treated samples. The increase in water infiltration by combining crushing with phyto-organic applications was ascribed to
a decrease in particle dispersion, creating more stable clay clusters, which in turn stabilized channels and pores. Conversely,
it was concluded that the singular crushing of gypsum-hardened bauxite waste in the waste dumps is potentially wasteful and
ineffective. 相似文献
50.
Characteristics of dry-wet abrupt alternation events in the middle and lower reaches of the Yangtze River Basin and the relationship with ENSO 总被引:1,自引:0,他引:1
During recent decades, more frequent flood-drought alternations have been seen in China as a result of global climate change and intensive human activities, which have significant implications on water and food security. To better identify the characteristics of flood-drought alternations, we proposed a modified dry-wet abrupt alternation index (DWAAI) and applied the new method in the middle and lower reaches of the Yangtze River Basin (YRB-ML) to analyze the long-term spatio-temporal characteristics of dry-wet abrupt alternation (DWAA) events based on the daily precipitation observations at 75 rainfall stations in summer from 1960 to 2015. We found that the DWAA events have been spreading in the study area with higher frequency and intensity since 1960. In particular, the DWAA events mainly occurred in May and June in the northwest of the YRB-ML, including Hanjiang River Basin, the middle reaches of the YRB, north of Dongting Lake and northwest of Poyang Lake. In addition, we also analyzed the impact of El Niño Southern Oscillation (ENSO) on DWAA events in the YRB-ML. The results showed that around 41.04% of DWAA events occurred during the declining stages of La Niña or within the subsequent 8 months after La Niña, which implies that La Niña events could be predictive signals of DWAA events. Besides, significant negative correlations have been found between the modified DWAAI values of all the rainfall stations and the sea surface temperature anomalies in the Nino3.4 region within the 6 months prior to the DWAA events, particularly for the Poyang Lake watershed and the middle reaches of the YRB. This study has significant implications on the flood and drought control and water resources management in the YRB-ML under the challenge of future climate change. 相似文献