Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Upper Oligocene-Lower Miocene shallowing-upwardlacustrine sequences controlled by periodic and non-periodic processes(Ebro Basin, northeastern Spain)

The lacustrine facies from two sections (Candasnos and Fraga) ofthe Oligocene-Miocene Torrente de Cinca lithostratigraphic Unit in thecentral part of the Ebro Basin (Spain) have been analysed to determine theinfluence of orbital parameters in lacustrine sedimentation. The unit ispredominantly composed of limestones and marls, and represents a shallowlacustrine freshwater system. The sedimentological features of the faciesstudied demonstrate that the lower part of the Candasnos section representsoffshore lacustrine subenvironments whereas the upper part, and the whole ofthe Fraga section, characterise marginal lacustrine areas. Series of stratalthickness variations of limestone, marl, and limestone/marl couplets fromboth sections have been analysed using spectral analysis. This shows thatinformation corresponding to periodic cycles only appears in the offshorefacies, that is to say, in the lower part of Candasnos section, and disappearsin the marginal facies where non-periodic cycles exist. Furthermore, thespectral analysis of the offshore facies highlights the existence of a peak inthe power spectrum with a period of around 7 (6.8 to 7.8) that can berecognised in the field as shallowing-upward lacustrine sequences.Magnetostratigraphic data from the Candasnos section allow us to establish atime span of 2,808 years for the limestone/marl couplet from the lower partof this section, and between 19,000 and 22,000 years for the periodic cycleidentified, thus representing the climatic precession cycle. Shallowingsequences from marginal areas do not correspond with any periodiccycle.     

Estimates of lichen growth–rate in northern Sweden

Two lichenometric techniques were compared in a study of lichen growth–rate in northern Sweden. The first technique, based on the maximum lichen diameter on glacier moraines, was identical to the technique used in the 1970s, whereas the other utilized the lichen diameter measured on 100 randomly selected boulders. The results indicate that it does not matter which technique is chosen, as long as the technique is used consistently on both the calibration surfaces and the surfaces to be dated. The use of data from both the 1970s and the 2000s increased the number of calibration surfaces available. The new calibration curve indicates that the age of Little Ice Age moraines was underestimated by up to about 30 years in the study conducted in the 1970s.     

Study of weathering processes developed on old piedmont surfaces in Western Spain: new contributions to the interpretation of the “Raña” profiles

The Hercynian basement of the Iberian Peninsula was uplifted by the Alpine orogeny during the Tertiary. It gave rise to a set of block mountains and tectonic grabens, one of which is the Ciudad Rodrigo Basin. It is located in Western Spain and forms a westward extension of the great Tertiary Duero Basin. The sediments filling this graben are of continental origin, their ages ranging from Palaeogene to Quaternary. Morphologically, the southern part of this basin forms a set of piedmont surfaces (the “Raña” surfaces) appearing above the terrace system of the present rivers. This paper examines the weathering processes developed over these old piedmont surfaces using micromorphological, XR diffraction, scanning electron microscopy (SEM) and microporosity techniques.The Raña sediments are rich in quartzite pebbles and gravel within a clayey matrix. Once deposited, these materials underwent important in situ weathering processes under somewhat hydromorphic conditions, of which hydrolysis, ferrolysis and xerolysis were the most important. All these processes gave rise to: (1) transformation of most of the clasts of shists and slates into a matrix causing the destruction of the original sedimentary structures and a relative concentration of the resistant lithologies (quartzites and quartz); (2) important changes in the clay fraction, leading to a predominance of kaolinite in the upper levels of the profiles, (3) release of elements from primary minerals, Fe being one of the most important, and (4) redistribution of matter, mainly clay and Fe oxyhydroxides, within the profiles.The coexistence of seasonal periods with pF higher than 4.2 repeated over a long time, together with poor internal and external drainage conditions, are the cause of the special features displayed by Raña deposits.     

Luxury Tourism and Regional Economic Development in Mexico

This article argues that little attention has been paid to the territorial and socioeconomic impact of consumer–service globalization on Third World countries. It specifically examines the economic role of tourism in Mexico and its limited effect on the country's regional development. Despite governmental support in order to enhance economic growth, currency receipts, and employment, tourism contributes less than 5 percent to the gross domestic product, and the majority of tourism–related jobs are precarious and low–skilled. The promotion of luxury resorts in coastal areas has led to highly concentrated and fast–growing enclaves of mainly foreign investment. However, this strategy has failed to stimulate productive links between tourist centers and their hinterlands and has led to large–scale urbanization characterized by a considerable lack of basic services for the resident population.     

An experimental study of nominally symmetric and asymmetric structures isolated with the FPS

This experimental investigation deals with the earthquake behaviour of a nominally symmetric and a mass‐asymmetric three‐storey structural model isolated with the frictional pendulum system (FPS). Both accidental and natural torsion are evaluated in the structure by using recorded accelerations in all building floors and measured deformations at the isolation level. A 3D‐shaking table was used to subject the model to five different ground motions, including impulsive as well as far‐field subduction‐zone type earthquakes. Results show that the analytical predictions of the earthquake behaviour of the isolated structure, as obtained from a physical model of the FPS, are in close agreement with the true complex inelastic measured behaviour of the FPS. Besides, experimental results also validate previous observations about the importance of accounting for the variability of the normal loads in modelling the earthquake behaviour of FPS isolators. Measured torsional deformation amplifications at the base of the building vary, in the mean, from 2.5% to 6% for the symmetric and asymmetric structural configurations, respectively. In relation to the fixed base structure, the reduction factors for the base shear of the isolated structure are, in the mean, about 3.9 for both configurations. Finally, it is concluded that the FPS is capable of controlling the lateral–torsional motions of mass‐asymmetric structures quite effectively by aligning the centre of mass of the superstructure with the centre of pendular and frictional resistance of the isolation system. Copyright © 2003 John Wiley & Sons, Ltd.     

Physical model for dynamic analysis of structures with FPS isolators

This article presents a physical model for frictional pendulum isolators (FPS) that is ready to be implemented in most commercial software. The model is capable of accounting for effects such as large deformations, sticking, and uplift and impact by sensing the normal loads in the isolators through a gap element. Sticking has been incorporated into the model by extending the Park–Wen hysteretic model to the case of large deformations. The proposed model has been tested against a theoretically ‘exact’ formulation leading to essentially identical results. To facilitate its use, the physical FPS model has been cast into a typical non‐linear structural element format, i.e. with deformation as input and restoring force as output. Examples of a building and a bridge have been chosen to show the potential of the element and to provide further insight into the earthquake response of structures with FPS isolators; in particular, in aspects such as the orientation in placement of the isolator, sticking, P? Δ, and other large deformation effects. Copyright © 2003 John Wiley & Sons, Ltd.     

Pre-Caving, Drilling and Blasting in the Esmeralda Sector of the El Teniente Mine

El Teniente Mine has developed the method of panel caving as an innovative pre-conditioning caving alternative for traditional mining of sectors located in primary rock. In applying this method, caving speed and area incorporation are the most relevant parameters to establish a desired production level in a specified sector. This is the context in which continuous improvements to several design alternatives have been developed and applied to optimize mine caving. Mine caving, by drilling and blasting, results in a narrow base cut of ore columns not larger than the height of the caving galleries, which usually measure 3.6 m. These confined blasting operations require drilling parallel blastholes that extend from the floor to the roof of the caving gallery. Panel caving aims at mitigating subvertical field stress transmission to the lower levels of the caving gallery. This improves the stability and helps maintain the advancement of the caved zone at the caving level, with respect to the development, preparation and ore mining activities in the production level. This paper analyzes and evaluates different panel caving alternatives. The result is the identification of the most adequate panel caving alternative for conditions in the Esmeralda Mine given safety, technical, operational and economic considerations.