The geochemistry of Archaean shales derived from a Mafic volcanic sequence, Belingwe greenstone belt, Zimbabwe: provenance, source area unroofing and submarine versus subaerial weathering

Shales of the ∼2.7 Ga Zeederbergs Formation, Belingwe greenstone belt, Zimbabwe, form thin (0.2-2 m) horizons intercalated with submarine lava plain basalts. Shales of the overlying Cheshire Formation, a foreland basin sedimentary sequence, form 1-100 m thick units intercalated with shallow-water carbonates and deep-water, resedimented basalt pebble conglomerates. Zeederbergs shale is characterized by high contents of MgO and transition metals and low concentrations of K₂O and LILE as compared to average Phanerozoic shale, indicative of an ultramafic to mafic source terrain. Cheshire shales have similar major and trace element contents, but MgO and transition metals are less enriched and the LILE are less depleted. Zeederbergs shales have smoothly fractionated REE patterns (La_N/Yb_N = 2.84-4.45) and no significant Eu anomaly (Eu/Eu* = 0.93-0.96). REE patterns are identical to those of the surrounding basaltic rocks, indicating local derivation from submarine reworking. Cheshire shales have rather flat REE patterns (La_N/Yb_N = 0.69-2.19) and a small, negative Eu anomaly (average Eu/Eu* = 0.85), indicative of a mafic provenance with minor contributions of felsic detritus. A systematic change in REE patterns and concentrations of transition metals and HFSE upwards in the sedimentary succession indicates erosion of progressively more LREE-depleted basalts and ultramafic volcanic rocks, followed by unroofing of granitoid crust. Weathering indices confirm the submarine nature of Zeederbergs shale, whereas Cheshire shale was derived from a source terrain subjected to intense chemical weathering.     

中国西南山区蒸散发能力的季节和空间变化

从全球范围来看，中国西南山区位地热带与亚热带，印度洋季风与中国季风的过渡带，属于季风气候。5－9月的降水占全年平均降水量的70％，整个山区随海拔高度的变化形成了很多气候带，与中国东部相比，中国西南山区旱季（冬季）温暖，光照充足，天空晴郎。根据中国西南山区36个（主要是云南的）气象站观测资料，利用彭曼修正式估算了中国西南山蒸散发能力（PET）。观测资料统计显示这些气象站位于同一气候区的不同类型区域，本文中估算了不同类型区域的月平均PET的递减率。各种气候类型区域的季节变化反映了季风影响的程度，PET的年内变化可划分为季风前期，季风期和季风后期。PET的区域月递减率在1mm/10mm0--5mm/100mm间变动，较低的云雾或云层等局部气候将太阳辐射控制在低水平，影响PET的递减率的正，负变化，由太阳辐射和风速主导大部分区域PET的最大值出现在季风来临前的2－5月份。在6－9月的季风期，中国西南山区受西南季风控制，整个区域气候变化比较一致，PET的值较小，其空间变化也较小。     

Capabilities and limitations of detailed hillslope hydrological modelling

Hillslope hydrological modelling is considered to be of great importance for the understanding and quantification of hydrological processes in hilly or mountainous landscapes. In recent years a few comprehensive hydrological models have been developed at the hillslope scale which have resulted in an advanced representation of hillslope hydrological processes (including their interactions), and in some operational applications, such as in runoff and erosion studies at the field scale or lateral flow simulation in environmental and geotechnical engineering. An overview of the objectives of hillslope hydrological modelling is given, followed by a brief introduction of an exemplary comprehensive hillslope model, which stimulates a series of hydrological processes such as interception, evapotranspiration, infiltration into the soil matrix and into macropores, lateral and vertical subsurface soil water flow both in the matrix and preferential flow paths, surface runoff and channel discharge. Several examples of this model are presented and discussed in order to determine the model's capabilities and limitations. Finally, conclusions about the limitations of detailed hillslope modelling are drawn and an outlook on the future prospects of hydrological models on the hillslope scale is given.The model presented performed reasonable calculations of Hortonian surface runoff and subsequent erosion processes, given detailed information of initial soil water content and soil hydraulic conditions. The vertical and lateral soil moisture dynamics were also represented quite well. However, the given examples of model applications show that quite detailed climatic and soil data are required to obtain satisfactory results. The limitations of detailed hillslope hydrological modelling arise from different points: difficulties in the representations of certain processes (e.g. surface crusting, unsaturated–saturated soil moisture flow, macropore flow), problems of small‐scale variability, a general scarcity of detailed soil data, incomplete process parametrization and problems with the interdependent linkage of several hillslopes and channel–hillslope interactions. Copyright © 1999 John Wiley & Sons, Ltd.     

Hydrological model parameter (in)stability – “crash testing” the HBV model under contrasting flood seasonality conditions

This paper investigates the transferability of calibrated HBV model parameters under stable and contrasting conditions in terms of flood seasonality and flood generating processes (FGP) in five Norwegian catchments with mixed snowmelt/rainfall regimes. We apply a series of generalized (differential) split-sample tests using a 6-year moving window over (i) the entire runoff observation periods, and (ii) two subsets of runoff observations distinguished by the seasonal occurrence of annual maximum floods during either spring or autumn. The results indicate a general model performance loss due to the transfer of calibrated parameters to independent validation periods of ?5 to ?17%, on average. However, there is no indication that contrasting flood seasonality exacerbates performance losses, which contradicts the assumption that optimized parameter sets for snowmelt-dominated floods (during spring) perform particularly poorly on validation periods with rainfall-dominated floods (during autumn) and vice versa.     

Climate change effects on hydrological system conditions influencing generation of storm runoff in small Alpine catchments

Floods and debris flows in small Alpine torrent catchments (<10 km²) arise from a combination of critical antecedent system state conditions and mostly convective precipitation events with high precipitation intensities. Thus, climate change may influence the magnitude–frequency relationship of extreme events twofold: by a modification of the occurrence probabilities of critical hydrological system conditions and by a change of event precipitation characteristics. Three small Alpine catchments in different altitudes in Western Austria (Ruggbach, Brixenbach and Längentalbach catchment) were investigated by both field experiments and process‐based simulation. Rainfall–runoff model (HQsim) runs driven by localized climate scenarios (CNRM‐RM4.5/ARPEGE, MPI‐REMO/ECHAM5 and ICTP‐RegCM3/ECHAM5) were used in order to estimate future frequencies of stormflow triggering system state conditions. According to the differing altitudes of the study catchments, two effects of climate change on the hydrological systems can be observed. On one hand, the seasonal system state conditions of medium altitude catchments are most strongly affected by air temperature‐controlled processes such as the development of the winter snow cover as well as evapotranspiration. On the other hand, the unglaciated high‐altitude catchment is less sensitive to climate change‐induced shifts regarding days with critical antecedent soil moisture and desiccated litter layer due to its elevation‐related small proportion of sensitive areas. For the period 2071–2100, the number of days with critical antecedent soil moisture content will be significantly reduced to about 60% or even less in summer in all catchments. In contrast, the number of days with dried‐out litter layers causing hydrophobic effects will increase by up to 8%–11% of the days in the two lower altitude catchments. The intensity analyses of heavy precipitation events indicate a clear increase in rain intensities of up to 10%.     

Quality of reprocessed GPS satellite orbits

High-precision Global Positioning System (GPS) satellite orbits are one of the core products of the International GNSS Service (IGS). Since the establishment of the IGS in 1994, the quality and consistency of the IGS orbits has steadily been improved by advances in the modeling of GPS observations. However, due to these model improvements and reference frame changes, the time series of operational orbits are inhomogeneous and inconsistent. This problem can only be overcome by a complete reprocessing starting with the raw observation data. The quality of reprocessed GPS satellite orbits for the time period 1994–2005 will be assessed in this paper. Orbit fits show that the internal consistency of the orbits could be improved by a factor of about two in the early years. Comparisons with the operational IGS orbits show clear discontinuities whenever the reference frame was changed by the IGS. The independent validation with Satellite Laser Ranging (SLR) residuals shows an improvement of up to 30% whereas a systematic bias of 5 cm still persists.     

Production of bioavailable and refractory dissolved organic matter by coastal heterotrophic microbial populations

Production of dissolved organic matter (DOM) by heterotrophic microbial communities isolated from Loch Creran (Scotland) was studied in time course incubations in which cells were re-suspended in artificial seawater amended with variable proportions of glucose, ammonium and phosphate. The incubation experiments demonstrated that microheterotrophs released part of the substrate as new DOM, with a production efficiency of 11 ± 1% for DOC, 18 ± 2% for DON and 17 ± 2% for DOP. Estimating the impact of this production in Loch Creran, showed that from 3 ± 1% (DOC) to 72 ± 16% (DOP) of DOM could originate from the heterotrophic microbial community. The produced DOM (PDOM) was both bioavailable (BDOM) and refractory (RDOM). Bioavailability as assessed by the difference between the maximum and the end DOM concentration, was generally higher than found in natural systems, with DOP (73 ± 15%, average ± SD) more bioavailable than DON (70 ± 15%), and DON than DOC (34 ± 13%).The stoichiometry of PDOM was linked to both nutrient uptake and BDOM ratios. Absorption and fluorescence of DOM increased significantly during the incubation time, indicating that microheterotrophs were also a source of coloured DOM (CDOM) and that they produce both bioavailable protein-like and refractory humic-like fluorophores.     

Localizing and quantifying groundwater-surface water interactions at different scales: A tracer approach at the River Moselle,Germany

Groundwater-surface water interactions (GSI) connect rivers and streams with riparian areas and the adjacent aquifer. Although these interactions exert a substantial control of quantity and quality of both groundwater and surface water, knowledge on GSI along rivers at the regional scale, particularly for inland waterways, is still limited. We investigated GSI along the river Moselle, an important federal inland waterway in Germany, by using radon and tritium to identify gaining (water flux from the aquifer to the surface water) and losing (water flux from the surface water to the aquifer) stream conditions, respectively. Gaining stream conditions were identified by continuously measuring radon along the river during boat surveys with a high spatial resolution (every 2 km) during intermediate (October 2020) and near low flow conditions (August/September 2021). The tritium concentrations in surface water and groundwater and the resulting tritium inventories were used to characterize losing stream conditions Monthly tritium inventories from 2017 to 2022 revealed a mean loss for the whole period of 20.3 % and a mean gain of 21.8%. Both were probably triggered by a combination of losing stream conditions and flood-induced mass transfer of water from the aquifer back into the river as well as discharge fluctuations. At the investigated site Lehmen there were direct indications of an influence of surface water due to elevated tritium concentrations in the groundwater (up to 13.3 Bq L⁻¹). Using radon mass balance modelling, good agreements of simulated versus measured radon data with respect to two groundwater end-member scenarios were obtained during intermediate flow (Spearman's ρ: 0.97 and 0.99; MAE: 10.1 and 3.4 Bq L⁻¹) and near low flow (Spearman's ρ: 0.97 and 0.99; MAE: 11 and 6.5 Bq L⁻¹). Considerable groundwater inflow was limited to the meander of Detzem, where cumulated groundwater inflow of about 19 m³ s⁻¹ (9.5% of total discharge) and 4.2 m³ s⁻¹ (3.8% of total discharge) was simulated during intermediate and near low flow, respectively. However, the groundwater inflow was relatively low compared to alpine streams, for example. The study will help to better identify and quantify GSI at the regional scale and provide methodological guidance for future studies focusing on inland waterways.     

Improved UT1 predictions through low-latency VLBI observations

The quality of predictions of Earth orientation parameters (EOPs) in general, and of Universal Time (UT1) in particular, depends strongly on the time delay between the last observation available and the first prediction. Since 30 September 2007 (MJD 54373), the latency of UT1 results from a subset of single baseline VLBI observations running once per week (Mondays) has been decreased from 2 to 3 days to about 8 h. This was achieved by transmitting the raw VLBI data of 1-h duration from the observing sites in Tsukuba (Japan), Wettzell (Germany) and Ny-Ålesund (Norway) to the correlator of the Max-Planck-Institute for Radio Astronomy and the German Federal Agency of Cartography and Geodesy at Bonn, Germany, by high-speed Internet connections (e-Transfer). The reduced latency of the observations has improved the accuracy of the combined International Earth Rotation and Reference Systems Service (IERS) Rapid Service/Prediction Center (RS/PC) UT1-UTC solution by roughly 50% on the days when the data are available. Because this combination is an input to the UT1-UTC prediction process, the improved latency is also responsible for a roughly 21% improvement in the accuracy of short-term IERS RS/PC UT1-UTC predictions on the days where the data are available.