Benthic geochemistry of manganese in the Bay of Biscay,and sediment mass accumulation rate

Manganese is a major redox reactive element of benthic metabolism. We have built a database of existing knowledge on the benthic geochemistry of Mn in the Bay of Biscay, in order to comprehensively assess the behaviour of Mn in a variety of environments during early diagenesis. The database contains vertical profiles of particulate and dissolved Mn species of 59 cores collected during 17 cruises between 1997 and 2006 at nine stations positioned between 140 and 4,800 m water depths. At all studied stations, Mn species follow the conventional distribution, where Mn(III,IV) species are enriched in the oxic layer, and dissolved Mn is present in the anoxic sediments. A minor part of Mn-oxides originates from sedimenting particles. The major part is of diagenetic origin, and derives from the oxidation of upward-diffusing dissolved Mn(II). Mn-oxide inventories are higher at the deeper stations than at the shallower ones. This difference cannot be attributed to different sources of sedimenting particles, but it must depend on sedimentation rate and diagenetic processes. At depth, dissolved Mn(II) concentrations are constant. This probably reflects equilibrium with an authigenic Mn(II) phase, which is the ultimate phase into which Mn is fossilized. The Mn content of deeper anoxic sediments is similarly low in all the cores studied, associated with corresponding trends of Mn content in sedimenting particles of the Bay of Biscay. Bioturbation, rather than redox oscillations, can convey Mn(III,IV) species downwards into the anoxic sediments where they are reduced, associated with a peak of dissolved Mn. Because dissolved Mn(II) is re-oxidized when it diffuses towards the oxic layer, the inventory of the diagenetic Mn(III,IV) phase remains at steady state, especially at stations where the oxic layer is thick. It then becomes possible to calculate the residence time of diagenetic Mn(III,IV) particles within the oxic layer, using the upward-directed flux of pore water Mn(II). By applying this residence time to the accumulation of sediments within the oxic layer, we obtain the sediment mass accumulation rate. The values calculated for the sediments of the Bay of Biscay fit well with accumulation rates obtained from radionuclides or sediment traps. The method has also been validated with data collected in other marine sedimentary environments. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Application of Laser‐Induced Breakdown Spectroscopy and Hyperspectral Images for Direct Evaluation of Chemical Elemental Profiles of Coprolites

This study demonstrates the application of laser‐induced breakdown spectroscopy (LIBS) and hyperspectral imaging to the investigation of coprolite and fossil samples. Solid samples from the Permian (seven coprolites and one fossil), Cretaceous (one coprolite) and Oligo‐Miocene (two coprolites) periods were directly analysed, and emission spectra from 186 to 1042 nm were obtained in several areas covering coprolite/fossil and rock material. Initial exploratory analyses were performed using principal component analysis with the data set normalised by the norm (Euclidean norm = 1). After identification and selection of emission lines of eleven elements (Al, Ca, Cr, Fe, K, Mg, Mn, Na, Ni, P and Si), the signals were normalised again by the relative intensity of the selected element. Phosphorus was identified mainly in the coprolites, while K and Na were primarily found in the rock material. In several cases, there was a positive correlation between Ca and P. A sample from the Oligo‐Miocene series was also analysed using inductively coupled plasma‐optical emission spectrometry (ICP‐OES) (rock and coprolites were analysed separately). Based on the quantitative results from ICP‐OES, it was confirmed that the tendency was the same as that observed with the results obtained from LIBS directly in the solid sample.     

Interactions between groundwater and seasonally ice‐covered lakes: Using water stable isotopes and radon‐222 multilayer mass balance models

Interactions between lakes and groundwater are of increasing concern for freshwater environmental management but are often poorly characterized. Groundwater inflow to lakes, even at low rates, has proven to be a key in both lake nutrient balances and in determining lake vulnerability to pollution. Although difficult to measure using standard hydrometric methods, significant insight into groundwater–lake interactions has been acquired by studies applying geochemical tracers. However, the use of simple steady‐state, well‐mixed models, and the lack of characterization of lake spatiotemporal variability remain important sources of uncertainty, preventing the characterization of the entire lake hydrological cycle, particularly during ice‐covered periods. In this study, a small groundwater‐connected lake was monitored to determine the annual dynamics of the natural tracers, water stable isotopes and radon‐222, through the implementation of a comprehensive sampling strategy. A multilayer mass balance model was found outperform a well‐mixed, one‐layer model in terms of quantifying groundwater fluxes and their temporal evolution, as well as characterizing vertical differences. Water stable isotopes and radon‐222 were found to provide complementary information on the lake water budget. Radon‐222 has a short response time, and highlights rapid and transient increases in groundwater inflow, but requires a thorough characterization of groundwater radon‐222 activity. Water stable isotopes follow the hydrological cycle of the lake closely and highlight periods when the lake budget is dominated by evaporation versus groundwater inflow, but continuous monitoring of local meteorological parameters is required. Careful compilation of tracer evolution throughout the water column and over the entire year is also very informative. The developed models, which are suitable for detailed, site‐specific studies, allow the quantification of groundwater inflow and internal dynamics during both ice‐free and ice‐covered periods, providing an improved tool for understanding the annual water cycle of lakes.     

Impact of long separating distances on the energy production of two interacting wave energy converters

In this paper, wave farms composed of two either surging or heaving wave energy converters are considered. Using a numerical model which takes into account wave interactions, the impact on the absorbed wave power of the separating distance between the two systems and the wave direction is studied. In regular waves, a modified q_mod factor is introduced and it is found to be more relevant than the usual q factor for identifying this impact. Then, it is shown that, asymptotically, the alteration of the energy absorption due to wave interaction effects decreases with the square root of the distance. This is a slow decay, which leads to a still significant modification of the wave energy absorption at long distance (up to 15% at a distance of 2000 m). In irregular waves, it is shown that constructive and destructive effects compensate each other, particularly when considering the mean annual power. It leads to a smaller impact of the wave interactions on the absorbed energy and shorter distances (smaller than 10% for distances greater than 400 m). Finally, conclusions on if wave interactions should be taken into account or not when designing a wave farm are drawn in function of the distance.     

Structure,composition, and location of organic matter in the enstatite chondrite Sahara 97096 (EH3)

Abstract– The insoluble organic matter (IOM) of an unequilibrated enstatite chondrite Sahara (SAH) 97096 has been investigated using a battery of analytical techniques. As the enstatite chondrites are thought to have formed in a reduced environment at higher temperatures than carbonaceous chondrites, they constitute an interesting comparative material to test the heterogeneities of the IOM in the solar system and to constrain the processes that could affect IOM during solar system evolution. The SAH 97096 IOM is found in situ: as submicrometer grains in the network of fine‐grained matrix occurring mostly around chondrules and as inclusions in metallic nodules, where the carbonaceous matter appears to be more graphitized. IOM in these two settings has very similar δ¹⁵N and δ¹³C; this supports the idea that graphitized inclusions in metal could be formed by metal catalytic graphitization of matrix IOM. A detailed comparison between the IOM extracted from a fresh part and a terrestrially weathered part of SAH 97096 shows the similarity between both IOM samples in spite of the high degree of mineral alteration in the latter. The isolated IOM exhibits a heterogeneous polyaromatic macromolecular structure, sometimes highly graphitized, without any detectable free radicals and deuterium‐heterogeneity and having mean H‐ and N‐isotopic compositions in the range of values observed for carbonaceous chondrites. It contains some submicrometer‐sized areas highly enriched in ¹⁵N (δ¹⁵N up to 1600‰). These observations reinforce the idea that the IOM found in carbonaceous chondrites is a common component widespread in the solar system. Most of the features of SAH 97096 IOM could be explained by the thermal modification of this main component.     

Towards a better understanding of changes in wintertime cold extremes over Europe: a pilot study with CNRM and IPSL atmospheric models

Recent winter seasons have evidenced that global warming does not exclude the occurrence of exceptionally cold and/or snowy episodes in the Northern mid-latitudes. The expected rarefaction of such events is likely to exacerbate both their societal and environmental impacts. This paper therefore aims to evaluate model uncertainties underlying the fate of wintertime cold extremes over Europe. Understanding why climate models (1) still show deficiencies in simulating present-day features and (2) differ in their responses under future scenarios for the twentyfirst century indeed constitutes a crucial challenge. Here we propose a weather-regime approach in order to separate the contributions of large-scale circulation and non-dynamical processes to biases or changes in the simulated mean and extreme temperatures. We illustrate our methodology from the wintertime occurrence of extremely cold days in idealized atmosphere-only experiments performed with two of the CMIP5 climate models (CNRM-CM5 and IPSL-CM5A-LR). First we find that most of the present-day temperature biases are due to systematic errors in non-dynamical processes, while the main features of the large-scale dynamics are well captured in such experiments driven by observed sea-surface temperatures, with the exception of a generalized underestimation of blocking episodes. Then we show that uncertainties associated with changes in large-scale circulation modulate the depletion in cold extremes under an idealized scenario for the late twentyfirst century. These preliminary results suggest that the original methodology proposed in this paper can be helpful for understanding spreads of larger model-ensembles when simulating the response of temperature extremes to climate change.     

Earthquake imprints on a lacustrine deltaic system: The Kürk Delta along the East Anatolian Fault (Turkey)

Deltas contain sedimentary records that are not only indicative of water‐level changes, but also particularly sensitive to earthquake shaking typically resulting in soft‐sediment‐deformation structures. The Kürk lacustrine delta lies at the south‐western extremity of Lake Hazar in eastern Turkey and is adjacent to the seismogenic East Anatolian Fault, which has generated earthquakes of magnitude 7. This study re‐evaluates water‐level changes and earthquake shaking that have affected the Kürk Delta, combining geophysical data (seismic‐reflection profiles and side‐scan sonar), remote sensing images, historical data, onland outcrops and offshore coring. The history of water‐level changes provides a temporal framework for the depositional record. In addition to the common soft‐sediment deformation documented previously, onland outcrops reveal a record of deformation (fracturing, tilt and clastic dykes) linked to large earthquake‐induced liquefactions and lateral spreading. The recurrent liquefaction structures can be used to obtain a palaeoseismological record. Five event horizons were identified that could be linked to historical earthquakes occurring in the last 1000 years along the East Anatolian Fault. Sedimentary cores sampling the most recent subaqueous sedimentation revealed the occurrence of another type of earthquake indicator. Based on radionuclide dating (¹³⁷Cs and ²¹⁰Pb), two major sedimentary events were attributed to the ad 1874 to 1875 East Anatolian Fault earthquake sequence. Their sedimentological characteristics were determined by X‐ray imagery, X‐ray diffraction, loss‐on‐ignition, grain‐size distribution and geophysical measurements. The events are interpreted to be hyperpycnal deposits linked to post‐seismic sediment reworking of earthquake‐triggered landslides.     

Modelling the behaviour of a large landslide with respect to hydrogeological and geomechanical parameter heterogeneity

Thanks to a sophisticated transient hydrogeological modelling allowing the determination of the pore pressure fields in La Frasse landslide mass during a crisis, it has been possible to model the mechanical behaviour of the slide and obtain results that prove to be similar to the monitored data, in terms of peak velocity, distribution of velocity with time and space and total displacements. Such results are reached only when appropriate constitutive modelling laws are used, and when geotechnical tests supply all the required parameters. The main results concern the potential effect of a drainage system during a crisis, like the one experienced in 1994. It can include vertical boreholes equipped with pumps or drains drilled from a gallery. The draining system reduces horizontal displacements down to 5% of the values modelled during the crisis. This effect, which appears to extend over a large width, will be even more significant if the boreholes discharge the drained water into the gallery, due to its extension in the presently stabilised landslide mass below the active zone. The modelling tools developed for La Frasse landslide thus provide all the necessary information to optimise the drainage scheme.