shinyNORRRM: A Cross-Platform Software to Calculate the CIPW Norm

In this paper, a novelty-free software to assess an efficient CIPW Norm (± 0.006 wt.% in differences between input and output data) is presented. The package is available in the official repository for user-contributed R packages (CRAN: Comprehensive R Archive Network). The software is able to handle big data sets and considers minor and trace element compositions. The algorithm can calculate odd minerals in igneous rocks, such as cancrinite and calcite, adjust the Fe⁺³/Fe⁺² ratio in different standard approaches, and recalculate the compositions of the rocks in an anhydrous basis (100 ± 0.003 wt.% volatile-free adjusted). Furthermore, the package calculates several petrological parameters, and the graphical outputs are displayed following IUGS scheme standards. The prime aspect of shinyNORRRM is the symbiosis of native R functions with the R package’s shiny (Web Application Framework for R) to run the norm in a user-friendly interface. shinyNORRRM can be executed in any operating system and requires no previous programming knowledge, thus promising to be the universal computational program in this matter. The output data are printed in the standard comma-separated values (*.csv) format, which is highly compatible with general spreadsheet editors. In this work, the algorithm of our program is validated using already compiled whole-rock geochemical databases.

     

Structural features of humic acids from a sedimentary sequence in the Guadiana estuary (Portugal–Spain border)

The structural characteristics of humic acids (HAs) from two different depths of a sedimentary sequence representing the last 13 kyr in the valley of Guadiana river estuary (SW Portugal/Spain border) have been approached using a combination of spectroscopic techniques, wet chemical degradation methods (sequential oxidation with sodium persulfate followed by KMnO₄, and oxidation with RuO₄) and analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) in the presence and absence of tetramethylammonium hydroxyde (TMAH). The aim was to obtain complementary information on the sources and alteration of the organic matter (OM) provided by a previous study on the vertical distribution of terrestrial and phytoplankton biogeochemical markers in the sequence. Both the FT-IR (Fourier transformed infrared) and ¹³C NMR (nuclear magnetic resonance) spectra showed a close similarity with the structural characteristics of the HA samples. NMR signals in the alkyl region (0–45 ppm) as well as FT-IR band patterns typical for methoxyl-substituted aromatic rings pointed to the presence of an important aliphatic domain, as well as to lignin-derived compounds. This finding was confirmed using analytical pyrolysis. In addition, the main TMAH thermochemolysis products were typical lignin-derived methoxyphenols with both guaicyl and syringyl nuclei. The detection of methoxyphenol units with three to six carbon atom (C₃–C₆) side chains suggests that lignin and possibly suberin were only partially degraded. Compounds arising from proteins and polysaccharides were also detected, although in lesser and varying amount. The major products from persulfate oxidation were series of n-alkanes (C₁₆–C₃₃ with clear odd/even predominance) and n-fatty acids, both saturated (C₁₀–C₂₆ with strong even/odd predominance) and unsaturated, which may arise from the above aliphatic biomacromolecules. The major products from permanganate oxidation of the persulfate residue were α,ω-diacids (C₆–C₁₁) originating from oxidation of the ether bonds linking the building blocks constituting the core of the HA structure. Aromatic compounds (phenols, methoxy-dimethoxybenzene carboxylic acid and benzene di-, tri-, tetra- and pentacarboxylic acids), most probably derived from the aromatic backbone of the HAs, that may also include lignin moieties as well as other polyphenols (flavonoids and tannins) were also detected. The RuO₄ oxidation also released series of n-alkanes (C₁₆–C₃₃), linear saturated fatty acids (C₁₀–C₂₈) and α,ω-diacids (C₇–C₂₅), as well as traces of benzene polycarboxylic acids. Regarding the usefulness of the various techniques used, they provide complementary information. Indeed, spectroscopic techniques and analytical pyrolysis provide information on the backbone of the HAs, and on their origin, whereas the oxidative degradations provide different information on the structural features of the HA, particularly the nature of the linking between the building blocks. In general, the data support the idea that the HAs still contain information about the signature of aliphatic and aromatic biomacromolecules contributing to the OM deposited. The presence of lignin-derived residues suggests a large input from terrestrial carbon throughout the core.     

Microclimatology and forest plague(Dendroctonus adjunctus) in Central Mexico

It has been observed in at least eight places in Central Mexico that hilly zones with certain orientation and slopes have a higher-than-normal incidence of plague. In this paper, the potential insolation and the total microclimatology of an infested and a healthy zone have been studied, with the purpose of determining the condition of natural climatic stress in the vegetation that makes it susceptible to the attack and proliferation of plagues. The infested slope (NE-NW), in contrast to the healthy slope (SE-SW), has greater annual variability in the potential reception of insolation, besides a minor energy availability disposition — on a daily basis — in quantity and in number of hours, by conduction from the ground, which produces more heterogeneity in the gradient of temperature at different depths in the ground; and the wind effect tends to be more frequent, intense and prolonged. The area studied is in the National Park “La Malinche” Tlaxcala in Central Mexico.     

A High-accuracy, Small Field of View Star Guider with Application to SNAP

To accomplish its mission, the spaceborne observatory SNAP (SuperNova Acceleration Probe) requires a pointing stability of <0.03 arcseconds during exposures lasting up to 500 sec. A Monte Carlo simulation of the photoelectron statistics from the guiding star investigates geometrical (such as the pixel size of the detector or the plate scale) and physical parameters (such as the magnitude of the star). It is shown that simple centroiding calculations can lead to the desired accuracy with guide stars as faint as magnitude 16. Availability of these stars is verified thanks to the HST Guide Star Catalog complemented with a statistical model of the distribution of stars. Thus a through-the-lens sensor that uses stars as faint as magnitude 16 to provide the necessary guiding signals is feasible. This revised version was published online in July 2006 with corrections to the Cover Date.     

Detrital chromites in metasediments of the East-Arabian continental margin in the Saih Hatat area: constraints for the palaeogeographic setting of the Hawasina and Semail basins (Oman Mountains)

 In Oman, the convergence between Arabia and Eurasia resulted in the Late Cretaceous overthrusting of oceanic crust and mantle lithosphere onto the Arabian continental margin. During this compressional event, a part of the continental plate was subducted to a depth of more than 60 km (0.5 GPa, 250–350  °C to more than 2.0 GPa, 550  °C) resulting in progressive metamorphism of the continental margin sediments, well exposed in the Saih Hatat tectonic window, northeastern Oman Mountains. We attempt to constrain the possibility of one continuous history of extension (starting along the east Arabian continental margin in the Permian) that was followed by one continuous history of convergence starting at 90 Ma near a dead oceanic ridge. This compression resulted in the observed progressive metamorphism by ophiolite overthrusting onto the continental margin. Constraining arguments are the palaeogeographic setting before ophiolite obduction of the As Sifah units and the Hawasina Complex near Ghurba. Detrital chromites in the Triassic–Cretaceous metasediments of the Hawasina Complex are compared with magmatic Semail chromites, and the whole-rock chemistry of these metasediments and associated metabasites are investigated. In contrast to former hypotheses, differences in the chemical composition between detrital and magmatic chromites, and the probable origin of all detrital chromites in the Hawasina Basin from Permian age oceanic rocks, suggest that the high-pressure metamorphic sediments of As Sifah can be considered as part of the basal deposits of the Hawasina Basin. Received: 1 September 1998 / Accepted: 18 January 1999     

Chain of galaxies in centaurus

Further photometric and spectroscopic observations of a chain of galaxies in Centaurus are presented and discussed.     

Non-linear stability of the equilibria in the gravity field of a finite straight segment

We study the non-linear stability of the equilibria corresponding to the motion of a particle orbiting around a finite straight segment. The potential is a logarithmic function and may be considered as an approximation to the one generated by elongated celestial bodies. By means of the Arnold's theorem for non-definite quadratic forms we determine the orbital stability of the equilibria, for all values of the parameter k of the problem, resonant cases included.     

Did the Sun Change Its Behaviour During the Decline of Cycle 23 and Into Cycle 24?

The activity minimum between the end of cycle 23 and the beginning of cycle 24 was the longest and deepest since at least the beginning of the 20th century. This has led to speculation that the Sun is changing its behaviour. The sunspot number and 10.7-cm solar radio flux indices have traditionally been highly correlated, so a change in the relationship between them might flag at such a change. An examination of this relationship suggests a significant change in the relationship between activity in the photosphere and in the chromosphere/corona happened soon after the maximum of cycle 23 and has continued into cycle 24. However, there are indications of change as early as 1980.     

An approximate energy cycle for inter-member variability in ensemble simulations of a regional climate model

The presence of internal variability (IV) in ensembles of nested regional climate model (RCM) simulations is now widely acknowledged in the community working on dynamical downscaling. IV is defined as the inter-member spread between members in an ensemble of simulations performed by a given RCM driven by identical lateral boundary conditions (LBC), where different members are being initialised at different times. The physical mechanisms responsible for the time variations and structure of such IV have only recently begun to receive attention. Recent studies have shown empirical evidence of a close parallel between the energy conversions associated with the time fluctuations of IV in ensemble simulations of RCM and the energy conversions taking place in weather systems. Inspired by the classical work on global energetics of weather systems, we sought a formulation of an energy cycle for IV that would be applicable for limited-area domain. We develop here a novel formalism based on local energetics that can be applied to further our understanding IV. Prognostic equations for ensemble-mean kinetic energy and available enthalpy are decomposed into contributions due to ensemble-mean variables (EM) and those due to deviations from the ensemble mean (IV). Together these equations constitute an energy cycle for IV in ensemble simulations of RCM. Although the energy cycle for IV was developed in a context entirely different from that of energetics of weather systems, the exchange terms between the various reservoirs have a rather similar mathematical form, which facilitates some interpretations of their physical meaning.