Arsenic in the groundwater of Ouro Preto (Brazil): its temporal behavior as influenced by the hydric regime and hydrogeology

In the city of Ouro Preto (MG), water catchment for public supply originates from superficial drainage, springs, old abandoned mines and some driven wells. In the rocks of the region, As is originally found in gold-enriched sulphide-bearing mineral deposits. The weathering process introduces As into the hydrological system by dissolution of this element into the leachate. Measurement of the As content in the groundwater of some catchments was carried out during 1 year and these measurements demonstrated high As content—up to 224 μg L⁻¹ of As(V)—during the rainy season (the maximum concentration limit according to World Health Organization is 10 μg L⁻¹). Lower values were observed during the dry season and in some sampling stations, As was not even detected. The As concentration variability during 1 year shows a strict and direct relationship to seasonal and hydrological conditions. For city authorities, responsible for public water supply, it is necessary to perform a complete inventory of the water sources used and constantly monitor the As content in the water.     

Characterization and evaluation of a tropical peat for the removal of Cr(VI) from solution

Tropical peat soils present higher ash content than those generated at temperate climate areas. Therefore, this study evaluated the characteristics of a Brazilian organic soil (OS), commercialized as peat, as well as its capacity in removing Cr(VI) from contaminated waters. The OS is composed of 35.5 wt% of organic matter and 56 wt% of inorganic fraction (ash), which is formed by minerals and phytoliths rich in silica (29.2 wt%) and alumina (23.6 wt%). The Cr(VI) removal tests were carried out in batch and column systems using OS and solutions of Cr(VI) prepared with distilled water and groundwater. Batch tests revealed that the organic substances in the OS caused the reduction of Cr(VI) to Cr(III), with an efficiency depending on solution pH. At pH 5.0 the Cr(VI) removal was 0.45 mg g^?1 in 24 h; whereas at pH 2.0, this removal increased to 1.10 mg g^?1. Since this redox reaction is very slow, the removal of Cr(VI) at pH 5.0 increased to around 2 mg g^?1 after 5 days. The removal of Cr(VI) was more effective in the column tests than in the batch test due to the greater solid/solution ratio, and their half-lives were 4.4 and 26.2 h, respectively. Chemical analysis indicated that Cr(VI) was reduced by the humic substances of OS, followed by the precipitation and/or adsorption of Cr(III) into the organic and inorganic components, as anatase. The presence of Cr(III) increased the stability of anatase structure, avoiding its transformation into rutile, even after being heated at 800 °C/2 h.     

Modeling Geospatial Uncertainty of Geometallurgical Variables with Bayesian Models and Hilbert–Kriging

Mathematical Geosciences - In mine planning, geospatial estimates of variables such as comminution indexes and metallurgical recovery are extremely important to locate blocks for which the energy...     

The kpc-scale radio source population

We are conducting a multi-wavelength (radio, optical, and X-ray) observational campaign to classify, morphologically and physically, a sample of 55 flat-spectrum radio sources dominated by structure on kpc-scales. This sample contains 22 compact-/medium-sized symmetric object candidates, a class of objects thought to be in the early stages of the evolution of radio galaxies. The vast majority of the remaining objects have core-plus-one-sided-jet structures, half of which show sharply bent jets, probably due to strong interactions with the interstellar medium of the host galaxies. Once the observational campaign is completed, we will constrain evolutionary theories of radio galaxies at their intermediate stages and possibly understand the physics of the hypothesised narrow-line region in active galactic nuclei, given our advantageous statistical position.     

Geochronology,sediment provenance,and fossil emplacement at Sumidouro Cave,a classic late Pleistocene/early Holocene Paleoanthropological site in eastern Brazil

Peter Wilhelm Lund's (1845a) heavily debated suggestion of a contemporaneity between Paleo‐Indians and extinct Pleistocene fauna at Sumidouro Cave was re‐examined through detailed sedimentological and geochronological analyses of sediment and both human and faunal remains. Sources of the cave's sediment include both entrances as well as ceiling fissures. Non‐human fossils, on the other hand, were probably carried by floodwater through the once more‐spacious swallet entrance. Seasonal flooding reworked and mixed these two highly asynchronous assemblages. U‐series and radiocarbon ages indicate that there are at least two distinct episodes of sediment input in the cave, at ˜240,000 yr B.P. and ˜8000 yr B.P. Human remains represent a later emplacement event, probably at ˜8400 cal yr B.P. Although the human remains are of considerable age, the cave's complex stratigraphy, flooding dynamics, and extensive removal of the cave's filling during earlier excavations do not allow the determination of an unequivocal co‐existence between Paleo‐Indians and extinct megafauna at the site. © 2005 Wiley Periodicals, Inc.     

Monsoon triggered formation of Quaternary alluvial megafans in the interior of Oman

A vast bajada consisting of coalescing low-gradient (< 0.3°) alluvial fans exceeding 100 km in length formed along the southwestern margin of the Oman Mountains. It comprises an old fan sequence of inferred Miocene to Pliocene age termed Barzaman Formation, diagenetically highly altered to dolomitic clays, and a thin veneer of weakly cemented Quaternary gravels. A combination of remote sensing, lithological analyses and luminescence dating is used to interpret the complex aggradation history of the Quaternary alluvial fans from the interior of Oman in the context of independent regional climate records. From satellite imagery and clast analysis four fans can be discerned in the study area. While two early periods of fan formation are tentatively correlated to the Miocene–Pliocene and the Early Pleistocene, luminescence dating allows the distinction of five phases of fan aggradation during the Middle–Late Pleistocene. These phases are correlated with pluvial periods from Marine Isotope Stage (MIS) 11 through 3, when southern Arabia was affected by monsoonal precipitation. It is concluded that the aggradation of the alluvial fans was triggered by the interplay of increased sediment production during arid periods and high rainfall with enhanced erosion of hillslopes and transport rates during strong monsoon phases. However, the lack of fine-grained sediments, bioturbation and organic material implies that although the Quaternary fans are sourced by monsoonal rains they formed in a semi-arid environment. Thus, it appears that, in contrast to the Oman Mountains, the interior was not directly affected by monsoonal precipitation.     

Evaluation and modeling of runoff and sediment yield for different land covers under simulated rain in a semiarid region of Brazil

This paper quantifies the runoff and sediment yield for four different land covers in a semiarid region of Brazil. The WESP model, a distributed, event-oriented runoff-erosion model, was applied and its physical parameters, N_s and K_R, were adjusted based on observed runoff and sediment yield data using simulated rainfall with an average intensity of 53 mm h^-1. The sediment yield obtained was 53.02 kg ha^-1 (caatinga vegetation), 231.96 kg ha^-1 (bare soil), 309.75 kg ha^-1 (beans), and 847.38 kg ha^-1(corn). The results showed that caatinga cover yields the lowest erosion and runoff when compared to the other treatments. The results also show that the sediment yield and runoff values simulated with N_s, K_I, and K_R parameters were well calibrated, within acceptable deviations. The caatinga vegetation was more effective in protecting the soil, when compared to the other types of coverage. The beans and corn covers had the highest values of runoff and sediment yield, even higher than those observed for bare soil.     

Mid Campanian‐Lower Maastrichtian magnetostratigraphy of the James Ross Basin,Antarctica: Chronostratigraphical implications

The James Ross Basin, in the northern Antarctic Peninsula, exposes which is probably the world thickest and most complete Late Cretaceous sedimentary succession of southern high latitudes. Despite its very good exposures and varied and abundant fossil fauna, precise chronological determination of its infill is still lacking. We report results from a magnetostratigraphic study on shelfal sedimentary rocks of the Marambio Group, southeastern James Ross Basin, Antarctica. The succession studied covers a ~1,200 m‐thick stratigraphic interval within the Hamilton Point, Sanctuary Cliffs and Karlsen Cliffs Members of the Snow Hill Island Formation, the Haslum Crag Formation, and the lower López de Bertodano Formation. The basic chronological reference framework is given by ammonite assemblages, which indicate a Late Campanian – Early Maastrichtian age for the studied units. Magnetostratigraphic samples were obtained from five partial sections located on James Ross and Snow Hill islands, the results from which agree partially with this previous biostratigraphical framework. Seven geomagnetic polarity reversals are identified in this work, allowing to identify the Chron C32/C33 boundary in Ammonite Assemblage 8‐1, confirming the Late Campanian age of the Hamilton Point Member. However, the identification of the Chron C32/C31 boundary in Ammonite Assemblage 8‐2 assigns the base of the Sanctuary Cliffs Member to the early Maastrichtian, which differs from the Late Campanian age previously assigned by ammonite biostratigraphy. This magnetostratigraphy spans ~14 Ma of sedimentary succession and together with previous partial magnetostratigraphies on Early‐Mid Campanian and Middle Maastrichtian to Danian columns permits a complete and continuous record of the Late Cretaceous distal deposits of the James Ross Basin. This provides the required chronological resolution to solve the intra‐basin and global correlation problems of the Late Cretaceous in the Southern Hemisphere in general and in the Weddellian province in particular, given by endemism and diachronic extinctions on invertebrate fossils, including ammonites. The new chronostratigraphic scheme allowed us to calculate sediment accumulation rates for almost the entire Late Cretaceous infill of the distal James Ross Basin (the Marambio Group), showing a monotonous accumulation for more than 8 Myr during the upper Campanian and a dramatic increase during the early Maastrichtian, controlled by tectonic and/or eustatic causes.     

The 2015 Summer Solstice Storm: One of the Major Geomagnetic Storms of Solar Cycle 24 Observed at Ground Level

We report on the 22?–?23 June 2015 geomagnetic storm that occurred at the summer solstice. There have been fewer intense geomagnetic storms during the current solar cycle, Solar Cycle 24, than in the previous cycle. This situation changed after mid-June 2015, when one of the largest solar active regions (AR 12371) of Solar Cycle 24 that was located close to the central meridian, produced several coronal mass ejections (CMEs) associated with M-class flares. The impact of these CMEs on the Earth’s magnetosphere resulted in a moderate to severe G4-class geomagnetic storm on 22?–?23 June 2015 and a G2 (moderate) geomagnetic storm on 24 June. The G4 solstice storm was the second largest (so far) geomagnetic storm of Cycle 24. We highlight the ground-level observations made with the New-Tupi, Muonca, and the CARPET El Leoncito cosmic-ray detectors that are located within the South Atlantic Anomaly (SAA) region. These observations are studied in correlation with data obtained by space-borne detectors (ACE, GOES, SDO, and SOHO) and other ground-based experiments. The CME designations are taken from the Computer Aided CME Tracking (CACTus) automated catalog. As expected, Forbush decreases (FD) associated with the passing CMEs were recorded by these detectors. We note a peculiar feature linked to a severe geomagnetic storm event. The 21 June 2015 CME 0091 (CACTus CME catalog number) was likely associated with the 22 June summer solstice FD event. The angular width of CME 0091 was very narrow and measured \({\sim}\, 56^{\circ }\) degrees seen from Earth. In most cases, only CME halos and partial halos lead to severe geomagnetic storms. We perform a cross-check analysis of the FD events detected during the rise phase of Solar Cycle 24, the geomagnetic parameters, and the CACTus CME catalog. Our study suggests that narrow angular-width CMEs that erupt in a westward direction from the Sun–Earth line can lead to moderate and severe geomagnetic storms. We also report on the strong solar proton radiation storm that began on 21 June. We did not find a signal from this SEP at ground level. The details of these observations are presented.