Modelling δC and δO in the solution layer on stalagmite surfaces

We derive equations describing the evolution of the carbon and oxygen isotope composition of the bicarbonate in a calcite precipitating solution on the surface of a stalagmite using a classical Rayleigh approach. The combined effects of calcite precipitation, degassing of CO₂ and the buffering effect of the water reservoir are taken into account. Whereas δ¹³C shows a progressive increase to a final constant value, δ¹⁸O shows an initial isotopic enrichment, which exponentially decays due to the buffering effect of the water reservoir. The calculated evolution is significantly different for both carbon and oxygen isotopes than derived in a recent paper [Dreybrodt W. (2008) Evolution of the isotopic composition of carbon and oxygen in a calcite precipitating H₂O-CO₂-CaCO₃ solution and the related isotopic composition of calcite in stalagmites. Geochim. Cosmochim. Acta72, 4712-4724.].Furthermore, we discuss the isotopic evolution of the bicarbonate in the solution for long residence times on the stalagmite surface, i.e., for t→∞. The equilibrium isotope ratio of the bicarbonate is then determined by isotopic exchange between the cave atmosphere and the bicarbonate in the solution and can be calculated by equilibrium isotope fractionation. For strongly ventilated caves exchange with the cave atmosphere will result in higher δ¹³C and δ¹⁸O values than those observed in a pure Rayleigh distillation scenario, for sparsely ventilated caves it will result in lower δ¹³C and δ¹⁸O values.     

Large scale features and energetics of the hybrid subtropical low ‘Duck’ over the Tasman Sea

New aspects of the genesis and partial tropical transition of a rare hybrid subtropical cyclone on the eastern Australian coast are presented. The ‘Duck’ (March 2001) attracted more recent attention due to its underlying genesis mechanisms being remarkably similar to the first South Atlantic hurricane (March 2004). Here we put this cyclone in climate perspective, showing that it belongs to a class within the 1 % lowest frequency percentile in the Southern Hemisphere as a function of its thermal evolution. A large scale analysis reveals a combined influence from an existing tropical cyclone and a persistent mid-latitude block. A Lagrangian tracer showed that the upper level air parcels arriving at the cyclone’s center had been modified by the blocking. Lorenz energetics is used to identify connections with both tropical and extratropical processes, and reveal how these create the large scale environment conducive to the development of the vortex. The results reveal that the blocking exerted the most important influence, with a strong peak in barotropic generation of kinetic energy over a large area traversed by the air parcels just before genesis. A secondary peak also coincided with the first time the cyclone developed an upper level warm core, but with insufficient amplitude to allow for a full tropical transition. The applications of this technique are numerous and promising, particularly on the use of global climate models to infer changes in environmental parameters associated with severe storms.     

Origins and development of Holocene coral reefs: a revisited model based on reef boreholes in the Seychelles, Indian Ocean

 Until recently, concepts of coral reef growth and accumulation have been predominantly based on a Darwinian model. In this, the upwards and outwards growth of a reef core (a coral framework) takes place over a foreslope consisting of reef talus, with the simultaneous filling of the back-reef lagoon by reef-derived debris. The principal adaptations of this pattern relate to the influence of relative changes in sea level and commonly ignore oceanographic factors such as storm frequency and severity. Boreholes through the outer edge of a fringing reef in the Seychelles, western Indian Ocean, reveal a record of Holocene sediment accumulation first established approximately 8 ka ago. Faunal and floral associations show that growth of this body began in relatively deep water but that this shallowed to <5 m within 1 ka. Subsequent accumulation was of “keep-up” style but, as the rate of sea-level rise slowed, shoaling became more frequent and aggradation was limited by reducing accommodation space. Constructional facies are characterised either by massive corals, including Leptastrea, Porites and faviids, or by branching corals, typically Acropora of the danai-robusta group. Coral surfaces may be encrusted by red algae, foraminifera and vermetids, and are commonly bored by filamentous algae, clionids and molluscs. However, detrital facies are volumetrically dominant, and the paucity of a constructional framework requires a re-evaluation of models of reef accretion. New models relate the geometry of accretion to the interplay between extreme storm events and fairweather hydrodynamic conditions. These suggest that a contiguous framework forms in areas of moderate fairweather energy without extreme storm events. Severe storms destroy the continuity of reef structures and generate increasing volumes of coarse detritus. Low storm severity, coupled with low fairweather hydrodynamic energy, may promote the accumulation of fine-grained reef-derived sediments that inhibit framework growth. While ecology reflects year-by-year sea conditions, lithology and structure are controlled by exceptional storms, with the effects of changing sea level superimposed. Received: 30 November 1998 / Accepted: 4 November 1999     

The influence of shrimp farms organic waste management on chemical water quality

We evaluated the physical–chemical properties and nutrient concentrations in two shrimp ponds under conventional management, intensive (I-P) and semi-intensive (SI-P), and one under organic management (O-P), three days after loading and before stoking. The mean’s total alkalinity concentrations were 2.26 ± 0.04 mM, 2.28 ± 0.01 mM and 2.59 ± 0.01 mM, respectively for I-P, SI-P and O-P. Bicarbonate and carbonate accounted for 62% and 37% in I-P, 64% and 36% in SI-P and 83–17% in O-P, respectively. Aragonite and calcite were oversaturated around Ω = 5. Mean total phosphate (TP) concentrations were 441.37 ± 92.06 μg/L, 449 ± 48 μg/L and 473.64 ± 84.17 μg/L, under I-P SI-P and O-P management respectively. Following this sequence, NO₃⁻ concentration was 2.98 ± 0.7 μg/L, 1.16 ± 0.16 μg/L and 0.32 ± 0.12 μg/L, under I-P, SI-P and O-P management respectively. Thus, the data suggest that different management of farm organic waste leads to different chemical water quality.     

黄龙与黄石钙华微生物沉积作用比较研究

本文通过调查黄龙风景区水体的环境地质特征与微生物群落结构及多样性,并与黄石公园对比分析,探讨了两种特殊地理环境下的微生物群落结构和多样性及其对钙华沉积的影响。结果表明：黄龙沟泉水属于地下冷泉,且景区内覆盖着大量植被,水体中有大量藻类和细菌;黄石公园猛犸象温泉区泉水属于地下热泉,植被覆盖率很低,泉水中微生物多为嗜热菌,藻类较少。黄龙与黄石钙华主要由方解石组成并且微生物参与了钙华的形成过程。微生物对钙华沉积的作用,主要分为模板作用、产物诱导作用和代谢调控作用,对比探讨了特殊地质环境下的微生物对钙华沉积的贡献,指出微生物沉积作用在钙华沉积过程中的重要性,可为黄龙钙华“黑化”防治提供理论依据。     

Partitioning of rainfall in a cocoa (Theobroma cacao lour.) plantation

To consolidate knowledge of some aspects of the partitioning of incident rainfall into throughfall, stemflow and interception loss, a study was made in a typical cocoa (Theobroma cacao Lour.) plantation in south-east Bahia, Brazil. The samples were collected, on a per shower basis, from locations at different levels in the canopy over a period of two and a half years. During the period studied, of the amount of incident rainfall reaching the cocoa plantation, on average 16% was retained by shelter trees, 19% by cocoa trees and 9% by the ground litter. Losses due to interception caused some variations and were mainly regulated by temporal variations and by the amount and intensity of rainfall in the plantation. The amount of rainfall intercepted, as determined in this study, is comparable with other tropical stands, but important differences do exist and are believed to be influenced by the previous level of moisture availability within the cocoa plantation.     

Intense drought and flooding events in the Rio Negro and relation with the tropical Pacific and Atlantic variability modes

The relationship of the hydrological variability of the Rio Negro in Manaus and the dominant large-scale climate variability patterns for the 1902–2007 period is investigated using the quantile method and composite analyses. Variations of the Rio Negro Level (RNL) during its 3-month high (May to July—MJJ) and low (October to December—OND) phases are examined separately. The El Niño (La Niña) related maximum warming (cooling) in the central tropical Pacific during its mature and decaying stages modulates the atmospheric circulation in the tropics and displaces the Walker circulation cell eastward (westward), so that its sinking (rising) branch occurs over western Amazon and causes negative (positive) precipitation anomalies in this region. These anomalous climate conditions occur before the Rio Negro high phase (MJJ) and contribute to reduce (increase) the RNL and lead to a very low (very high) event in the river. On the other hand, the SST variability modes in the tropical Atlantic mainly during the transition from wet to dry season modulate the precipitation variations over western Amazon in OND. The very high events are more frequent after the 1960’s decade and the very low events, before the 1930’s decade. Therefore, the occurrence of these events contains a multidecadal scale variability. The results also indicate that the variations in the rainfall in western Amazon occur up to 9 months in advance and modulate the RNL in Manaus. The results presented here might be useful for monitoring purposes of the RNL.

     

High-resolution210Pb dating of Lake Constance sediments: Stable lead in Lake Constance

Two sediment cores (BO90/13b and BO90/17b) from Lake Constance were investigated by-spectrometry for²¹⁰Pb,¹³⁴Cs,¹³⁷Cs,²⁴¹Am,²³⁴Th, and other members of the²³⁸U decay chain. The sediments were dated using the constant-flux model for²¹⁰Pb, and accumulation rates were determined. These range from 0.04 to 0.65g/cm ²/yr (BO90/13b) and 0.04 to 0.8g/cm ²/yr (BO90/17b), respectively. The mean accumulation rate amounts to 0.16g/cm ²/yr for both cores. The cores had already been dated by lamination counting and reconstruction of high-water events at the Limnological Institute at Constance, so that a very precise time scale was available. Both ages derived are in agreement within statistical error up to 1900, which means dating with the constant-flux model for²¹⁰Pb was confirmed up to that age. The position of the maxima of bomb cesium and americium confirm the stratigraphic and²¹⁰Pb datings. With²⁴¹Am a further radioactive isotope is available, which can, due to the half-life of²⁴¹Pu (t _1/2=14.4yr) be detected now by-spectrometry and can serve as an additional time indicator, the maximum being dated at 1963. By applying the various time scales, the depth profiles of stable lead and zinc of core BO90/13b were dated. Both heavy metals show a very significant maximum located beneath the layer of the maxima of bomb cesium and americium, showing that these maxima are older than those of the bomb isotopes. It is remarkable in this context that the maximum of zinc concentration occurs a little later than that of stable lead. Similar concentration profiles are observable in core BO90/17b and other, older sediment cores (CS6-CS10) on a transect across the lake. In contrast to a former assumption, the depth profile of stable lead in Lake Constance sediments does not reflect the anthropogenic gasoline lead emissions into the atmosphere for Germany, their maximum being dated at 1971.     

Effects of Explicit Urban-Canopy Representation on Local Circulations Above a Tropical Mega-City

The Advanced Regional Prediction System (ARPS) is coupled with the tropical town energy budget (tTEB) scheme to analyze the effects of the urban canopy circulation over the metropolitan area of São Paulo and its interactions with the sea breeze and mountain-valley circulation in the eastern state of São Paulo, Brazil. Two experiments are carried out for the typical sea-breeze event occurring on 22 August 2014 under weak synoptic forcing and clear-sky conditions: (a) a control run with the default semi-desert surface parametrization and; (b) a tTEB run for the urban canopy of São Paulo. A realistic land-use database over the south-eastern domain of Brazil is used in the downscaling simulation to a horizontal grid resolution of 3 km. Our results indicate that ARPS effectively simulates features of the nighttime and early morning land-breeze circulation, which is affected by the surrounding hills and the nocturnal heat island of São Paulo. By early afternoon, the south-eastern sea-breeze circulation moves inland perpendicular to the upslope of the Serra do Mar scarp, which generates a line of moisture convergence and updrafts further inland. Later, the convergence line reaches São Paulo and interacts with the circulation arising from the urban heat island (UHI), which increases the moisture convergence and strength of updrafts. The surface energy balance indicates that the UHI is caused by large sensible heat storage within the urban canopy during the day, which is later released in the afternoon and at night. The simulations are verified with available radiosonde and surface weather station data, land-surface-temperature estimates from the moderate resolution imaging spectroradiometer, as well as the National Center for Atmospheric Research reanalysis databases. The three-dimensional geometry of the urban canyons within the tTEB scheme consistently improves the thermodynamically-induced circulation over São Paulo.     

The role of floating mucilage in the invasive spread of the benthic microalga Chrysophaeum taylorii

Chrysophaeum taylorii Lewis & Bryan (Pelagophyceae) is a mucilage‐producing benthic microalga that has recently begun to spread in the Mediterranean Sea, where a range expansion is occurring. This paper presents the results of three field experiments that aimed to increase the knowledge on mucilage provision mechanisms for this benthic microalga and to evaluate the importance of mucilage in its range expansion. By means of two correlative field experiments (several years of data were considered to encompass the variability of mucilage cover) we found that, on the sea bottom, mucilage cover does not depend on epilithic cell density and that both its cover and settling are affected by water flow. We also tested the hypothesis that cells embedded in floating mucilage fall on the underlying substratum, where their abundance depends on water flow. To this aim, in the field we manipulated the presence of floating mucilaginous aggregates in cages with different levels of exposure to winds. The abundance of C. taylorii cells on the substratum under cages with mucilage was compared with that of two control treatments: cages without mucilage and mucilage in still water, in the field and lab, respectively. The results suggested that mucilage can represent an excellent strategy for the species to disperse, as C. taylorii cells fall from the floating mucilage and, if the water flow is unimportant, settle on hard substrata just underneath the cage. This study enriches the portfolio of knowledge of the dispersal strategies of microalgae and contributes to the understanding of the spread of invasive species.