Acute toxicity of temporally varying seawater CO2 conditions on juveniles of Japanese sillago (Sillago japonica)

CO(2) ocean storage by which liquefied CO(2) is injected into the deep-sea to mitigate the climate change would increase the CO(2) concentrations of the surrounding seawater. The biological impacts of such dynamic CO(2) environments are, however, unknown. We examined the acute toxicity of temporally changing seawater CO(2) concentrations on juveniles of Sillago japonica. Step-wise increases in ambient CO(2) to fCO(2) (fractional CO(2) concentration of the gas mixture bubbled into seawater) levels of 7% and 9% resulted in mortalities of 0.15 and 0.40-0.67 after 18 h, respectively. In contrast, one-step increases to these CO(2) levels killed all fish within 15 min. Further, a sudden drop of fCO(2) from 9-10% CO(2) to normocapnia (0.038%) killed all the surviving fish within a few minutes. These results demonstrate that impacts of ocean CO(2) storage need to be examined under conditions mimicking the dynamic changes in CO(2) levels expected to occur by the CO(2) injection procedure.     

Chemical overprinting of magmatism by weathering: A practical method for evaluating the degree of chemical weathering of granitoids

Quantitative determination of the degree of chemical weathering of rocks is a fundamental task in environmental and engineering geology, and many weathering indices based on whole-rock chemistry have been proposed. However, most classical indices are of limited application to granitoids in a wide area, because these lithotypes generally exhibit wide chemical variation arising from their petrogenesis. The chemical evolution produced during rock weathering, therefore, overprints pre-existing magmatic chemical variation. This problem can cause many classical weathering indices to yield misleading results. This study proposes a method that compensates for the influence of petrogenesis on calculation of the weathering index. The method is based on a bivariate plot of the magmatic chemical variation (MCV) in granitoids, and the degree of chemical weathering (DCW). The MCV axis must be based on an element that reflects magmatic processes and is also relatively immobile during rock weathering. In this study TiO₂ contents are utilized for the MCV. The DCW axis is fundamentally defined by the ratios of more-mobile to less-mobile elements during weathering, and hence many classical indices can be applied. The improved value of the degree of chemical weathering (DCW_i) for a weathered rock is derived by:

DCWi=s×(MCVCV-MCV₁)+DCW₁${\text{DCW}}_{\text{i}}=\text{s}\times ({\text{MCV}}_{\text{CV}}-{\text{MCV}}_1)+{\text{DCW}}_1$

where MCV₁ is the measured composition (e.g. TiO₂ content) of the weathered rock. DCW₁ denotes the ratios of more-mobile to less-mobile elements of the weathered rock. The “s” parameter is the slope of the least square linear regression for fresh granitoids in the MCV–DCW relationship. MCV_CV is a correction factor which is given by the average point on the MCV axis (e.g. average TiO₂) of the fresh rocks. This method is useful for evaluating the degree of weathering of various granitoids, and enhances the practical application of many weathering indices.     

The effect of a thin weak layer covering a basalt block on the impact cratering process

To clarify the effect of a surface regolith layer on the formation of craters in bedrock, we conducted impact-cratering experiments on two-layered targets composed of a basalt block covered with a mortar layer. A nylon projectile was impacted on the targets at velocities of 2 and 4 km s^?1, and we investigated the crater size formed on the basalt. The crater size decreased with increased mortar thickness and decreased projectile mass and impact velocity. The normalized crater volume, π_V, of all the data was successfully scaled by the following exponential equation with a reduction length λ₀: ${\pi }_{\text{V}}=b_0{\pi }_{\text{Y}}^{-b_1}\exp (-\lambda /{\lambda }_0)$, where λ is the normalized thickness T/L_p, T and L_p are the mortar thickness and the projectile length, respectively, b₀ and b₁ are fitted parameters obtained for a homogeneous basalt target, 10^?2.7±0.7 and ?1.4 ± 0.3, respectively, and λ₀ is obtained to be 0.38 ± 0.03. This empirical equation showing the effect of the mortar layer was physically explained by an improved non-dimensional scaling parameter, ${\pi }_{\text{Y}}^1$, defined by ${\pi }_{\text{Y}}^1=Y/({\rho }_{\text{t}}{u}_{\text{p}}^2)$, where u_p was the particle velocity of the mortar layer at the boundary between the mortar and the basalt. We performed the impact experiments to obtain the attenuation rate of the particle velocity in the mortar layer and derived the empirical equation of $\frac{u_{\text{p}}}{v_{\text{i}}}=0.50\exp \left(-\frac{\lambda }{1.03}\right)$, where v_i is the impact velocity of the projectile. We propose a simple model for the crater formation on the basalt block that the surface mortar layer with the impact velocity of u_p collides on the surface of the basalt block, and we confirmed that this model could reproduce our empirical equation showing the effect of the surface layer on the crater volume of basalt.     

Restitution coefficients and sticking velocities of a chondrule analogue colliding on a porous silica layer at impact velocities between 0.1 and 80 m s−1

To study the accretional growth of rimmed chondrules and their agglomerates in the solar nebula, we measured the restitution coefficients, ε, and the sticking velocities to a porous silica layer, v_c, by impacting the silica layer with a glass ball at velocities from 0.1 to 80 m s^?1. We used a porous silica layer covering a basalt block with thicknesses ranging from 1/5 of the glass ball radius to equal to the glass ball radius as a rimmed chondrule analogue, and the porosity of the silica layer was set to be 70%, 80%, 85%, and 90%. Collisional experiments were conducted by means of the free fall method or by the use of a spring gun or a gas gun, allowing us to vary the impact velocity. We used a laser displacement meter to estimate the impact and rebound velocities as well as the acceleration during the collision at impact velocities below 1 m s^?1. As a result, the sticking velocity, v_c, of 90%- and 85%- porosity layers with a thickness equal to 1/2 of the glass ball diameter was 0.44 and 2.4 m s^?1, respectively. On the other hand, we found a distinct barrier to sticking for smaller-porosity layers: the silicate layer with a porosity smaller than 80% never exhibited sticking at any impact velocity below 1 m s^?1. Instead, we observed a rebound effect with restitution coefficients larger than 0.2. In the case of a silica layer with a porosity smaller than 80%, we observed the sub-sticking condition defined by ε < 0.1 at velocities extending from 5 m s^?1 to 70 m s^?1.     

Phytoplankton assemblage in the Plio-Pleistocene record of Lake Baikal as indicated by sedimentary steryl chlorin esters

Past changes in phytoplankton assemblages in Lake Baikal over the last 4.5 Ma, both in population and composition, are inferred from the downcore profiles of the relatively stable chlorophyll derivatives steryl esters of pyropheophorbides a and b (steryl chlorine esters; SCEs) in the 0–200 m section of the BDP-98 drill core, supplemented by the data on biogenic silica (BSi) and total organic carbon (TOC) contents. SCEs-a and -b dominate among sedimentary chlorophyll derivatives in the BDP-98 sediments except for the upper few meters, indicating their high stability during diagenetic alteration of sediments. The depth (age) profiles of SCEs-a are consistent with BSi and TOC profiles and are interpreted as reflecting primary productivity of the lake in the past. Baikal proxies reveal close correlation with marine oxygen isotope records (MIS stratigraphy). These observations confirm that climate change in the northern hemisphere has been a primary factor controlling the total phytoplankton productivity in Lake Baikal during the last several million years.Among SCEs-a, C₃₀ (dinostanol)-SCE-a, a marker of dinoflagellates was identified by GC–MS analysis. SCE-b, a marker of green algae, was identified by its UV–vis spectrum. The ratio of C₃₀-SCE-a to total SCEs-a (TSCEs-a) was higher during 4.5–4.2 and 1.7–1.3 Ma, suggesting that dinoflagellates proliferated preferentially in those periods. The early Pleistocene maximum of this ratio corresponds to the broad minimum of diatom abundance previously suggested to have recorded a prolonged regional cooling. An abrupt increase in the SCE-b/TSCEs-a ratio was observed at 2.5–2.6 Ma, indicating that green algae containing chlorophyll b have proliferated in Lake Baikal during this period. This interval has also been suggested to contain evidence for a significant regional cooling based on minima of diatom abundance and BSi in sediments. The depth profile of C₂₇Δ⁵ (cholesterol)-SCE-a relative to TSCEs-a showed a trend similar to that of BSi, suggesting that C₂₇Δ⁵-SCE-a/TSCEs-a ratio is a potential marker of diatoms in Lake Baikal.Certain mismatches between the Lake Baikal profiles of biological indicators and the marine oxygen isotope records, as well as the slight temporal offsets between different Lake Baikal biological marker signals suggest that the regional component of climatic and/or lacustrine environmental changes also have played a role in determining the composition of the Lake Baikal Plio-Pleistocene phytoplankton assemblage.     

Contributions of sandy lands and stony deserts to long-distance dust emission in China and Mongolia during 2000–2006

More than 400 Moderate Resolution Imaging Spectroradiometer (MODIS) images of dust storm events were collected and analyzed, and individual events were tracked back to their origins. Dust tracks were determined from color composite images, brightness temperature difference (BTD) and the NOAA Hybrid Single-Particle Lagrangian Integrated Trajectory model. The results showed that five regions (sandy lands in central Inner Mongolia and the adjacent area of Mongolia; the Gobi Desert in Xinjiang and Gansu provinces, western Inner Mongolia, and the adjacent southwestern area of Mongolia; the Gobi Desert in southern Mongolia and the adjoining area of northern Inner Mongolia; sandy lands and deserts around the middle reaches of the Yellow River; and the area rimming the Taklimakan Desert) were the main contributors to long-lived mineral dusts in northern China and Mongolia. Of these dust production areas, sandy lands and stony deserts, rather than the sandy deserts of Inner Mongolia and Mongolia, were found to be the dominant dust sources, accounting for more than 75% of regional dust emission events. Dust events in the Taklimakan Desert were often local phenomena, although they could also be transported eastward if they were uplifted high enough to escape the enclosing topographic highs. Dust sources in northwestern China are mainly alluvial fans and dry lake and river beds. Success in identifying the sources and trajectories of Asian dust storms would guide future ground-based research and steppe degradation countermeasures and help reduce the uncertainties in modern modeling of Asian dust.     

The geochemistry of volatile species in melt inclusions and sulfide minerals from Izu-Oshima volcano, Japan

Olivine-hosted melt inclusions in the O95 pyroclastic layer of Izu-Oshima volcano, Japan are basaltic to basaltic-andesitic in composition. The negative correlation between SiO₂ and H₂O in melt inclusions and reverse compositional zoning observed in olivine and other mineral phenocrysts is inferred to arise from mixing between a highly evolved and a less evolved magma. The latter is characterized by the highest S (0.15 wt.%) and H₂O (3.4 wt.%) concentrations among those described in reports of previous studies. The S⁶⁺/S_total ratios in melt inclusions were 0.64?–?0.73, suggesting a relatively high oxidation state (NNO + 0.87 at 1150°C). The presence of pyrrhotites, which are found only in titanomagnetite microlites, suggests that sulfide saturation occurred during microlite growth under at a sulfur fugacity (log fS₂) value of around + 0.5 for T = 1060°C. The groundmass glass compositions are more evolved (andesitic composition) than any melt inclusions containing high amounts of Cl (0.13 wt.%) but negligible H₂O (0.20 wt.%) and S (< 70 ppm), suggesting that Cl was retained in the magma, in contrast to S and H₂O, which degassed strongly during magma effusion.     

Spectrum of slowly varying component of solar radio emission on millimeter wavelengths

The spectrum of the S-component of solar radio emission has been investigated at 4 GHz, 17 GHz, 35 GHz, 70 GHz, and 94 GHz. The spectrum for a spot group which appeared late in March 1966 (McMath plage No. 8223), seems to be flat at the frequencies above about 35 GHz. This implies that the emission is due to pure free-free emission at the frequencies above 35 GHz.     

A complex earth slide–earth flow induction by the heavy rainfall in July 2006, Okaya City, Nagano Prefecture, Japan

A seasonal rain front (Baiu front) accompanied a long-term accumulation of precipitation propagated over the wide areas of the main island of Japan during 15–24 July 2006. In Okaya City, Nagano Prefecture, several flow-type landslides occurred in the early morning of 19 July 2006, claiming eight lives. Among these landslides, a most peculiar complex earth slide–earth flow occurred on a north gentle slope of the upstream portion of the Motosawagawa River. In the source area, volcanoclastic soils overlying tuffaceous rocks at about 4-m depth slid due to the prolonged precipitation that raised the water table level in the soil. Along with the travel path, the failed materials fluidized causing the liquefaction of the volcanoclastic soils underlain by volcanic black ash soils. The resulting flow spread over a wide area up to the final deposition. Constant volume box-shear tests on undisturbed volcanoclastic soil specimens taken from the source area showed effective normal stress tended to decrease during shearing. The ring shear tests on saturated disturbed specimens produced the large loss of shear resistance, which may explain the fluidized motion of the complex landslide.     

Evaluation of tsunami impacts on shallow marine sediments: An example from the tsunami caused by the 2003 Tokachi-oki earthquake, northern Japan

A combined approach of field geology and numerical simulation was conducted for evaluating the tsunami impacts on the shelf sediments. The 2003 Tokachi-oki earthquake, M 8.0, that occurred on 25 September 2003 off southeastern Hokkaido, northern Japan, generated a locally destructive tsunami. Maximum run-up height of the tsunami waves reached 4 m above sea level. In order to estimate the tsunami impacts on shallow marine sediments, we compared pre- and post-tsunami marine sediments in water depths of 38–112 m in terms of grain size, sedimentary structure, and microfossil content. Decreases of fine fractions, especially finer than very fine sand, which led to coarsen the mean grain size, were detected in the inner shelf of the northern part of the study area. Foraminiferal assemblages also changed in the coarsened sediments. On the other hand, the other shelf sediments largely unchanged or slightly fined. We also simulated the tsunami wave velocity and direction, and grain size entrained by the modeled tsunami. The numerical simulation resulted in that the 2003 tsunami could transport very fine sand in water depths shallower than 45–95 m at the northern part of the study area. This is comparable with the actual grain-size changes after the tsunami had passed. However, some storms and tidal currents might also be possible to stir the surface sediments after the pre-tsunami survey, so we could not conclude that the grain-size changes had been caused only by the tsunami. Nevertheless, a combined approach of sampling and modeling was powerful for estimating the tsunami impacts under the sea.