A multi-isotope approach (O,H, C,S, B and Sr) to understand the source of water and solutes in some the thermal springs from West Coast geothermal area,India

The West Coast belt, consisting of nearly 60 thermal springs, is one of the most diversified geothermal fields in India. The present work describes the multi-isotopic (O, H, C, S, B and Sr) characterization of thermal waters carried out in the Tural-Rajwadi geothermal field, situated in southern sector of the west coast geothermal area. The aim of this study is to delineate the origin of thermal water as well as to ascertain the sources of carbon, sulphur, boron and strontium dissolved in those thermal springs. The stable isotopes (δ²H and δ¹⁸O) and tritium data indicate that these thermal springs are not recently recharged rain water rather, it contains very old component of water. Oxygen-18 shift is observed due to rock-water interaction over a long period of time. Carbon isotopic composition of DIC points out to the silicate weathering with soil CO₂ coming from C₃ type of plants whereas δ³⁴S of dissolved sulphate confirms the marine origin of sulphate. This marine signature is basically derived from paleo-seawater possibly entrapped within the flows. Boron isotopic data reveals that both the seawater and rock dissolution are the sources of boron in the thermal waters whereas high ⁸⁷Sr/⁸⁶Sr ratios (0.7220–0.7512) of the thermal waters conclusively establishes that archean granitic basement is the predominant rock source of strontium, not the Deccan flood basalts. In addition, like strontium, concentrations of lithium, rubidium and caesium are also governed by the rock-water interaction. Thus, the combined use of this multi-isotope technique coupled with trace element concentrations proves to be an effective tool to establish the sources of solutes in the thermal water.     

Source parameters for the 2013–2015 earthquake sequence in Nógrád county,Hungary

Between 2013 June and 2015 January, 35 earthquakes with local magnitude M _L ranging from 1.1 to 4.2 occurred in Nógrád county, Hungary. This earthquake sequence represents above average seismic activity in the region and is the first one that was recorded by a significant number of three-component digital seismographs in the county. Using a Bayesian multiple-event location algorithm, we have estimated the hypocenters of 30 earthquakes with M _L ≥1.5. The events occurred in two small regions of a few squared kilometers: one to the east of Érsekvadkert and the other at Iliny. The uncertainty of the epicenters is about 1.5–1.7 km in the E-W direction and 1.8–2.1 km in the N-S direction at the 95 % confidence level. The estimated event depths are confined to the upper 3 km of the crust. We have successfully estimated the full moment tensors of 4 M _w ≥3.6 earthquakes using a probabilistic waveform inversion procedure. The non-double-couple components of the retrieved moment tensor solutions are statistically insignificant. The negligible amount of the isotropic component implies the tectonic nature of the investigated events. All of the analyzed earthquakes have strike-slip mechanism with either right-lateral slip on an approximately N-S striking or left-lateral movement on a roughly E-W striking nodal plane. The orientations of the obtained focal mechanisms are in good agreement with the main stress pattern published for the epicentral region. Both the P and T principal axes are horizontal, and the P axis is oriented along a NE-SW direction.     

Study of terrestrial carbon flux by eddy covariance method in revegetated manganese mine spoil dump at Gumgaon,India

The micrometeorological technique of eddy covariance is a powerful tool for characterizing the carbon (C) budget of terrestrial ecosystems. Eddy covariance method was used for estimating Net Ecosystem Exchange (NEE) of carbon dioxide between atmosphere and revegetated manganese mine spoil dump at Gumgaon, India. In this paper, we analyzed the diel CO₂ flux pattern and its response to various physical environmental conditions. The carbon balance of terrestrial ecosystems is particularly sensitive to climatic changes. Study of diel pattern of CO₂ flux showed that carbon uptake was dependent on sunlight. Effect of temperature and latent heat on the CO₂ flux showed that rate of CO₂ uptake increased proportionally, but later declined due to various factors like stomatal response, high evaporative demand, circadian rhythm and/or a combination of all three. Net ecosystem production of revegetated land was found to be 28.196 KgC/ha/day whereas average net carbon release by the ecosystem, through respiration was observed to be 5.433 KgC/ha/day. Thus, quantifying net carbon (C) storage in degraded land is a necessary step in the validation of carbon sequestration estimates and in assessing the possible role of these ecosystems in offsetting adverse impacts of fossil fuel emissions.     

Sensitivity analysis of runoff hydrographs due to temporal rainfall patterns in Makkah Al-Mukkramah region,Saudi Arabia

Runoff peak and volume in flood studies are estimated relying on temporal rainfall distribution from various storm patterns. Usually, SCS distributions types (I, II, III, IA) are commonly used. Using these distributions in runoff calculations assume that the in situ temporal rainfall pattern typically behaves as the one described by the SCS-type distribution, which is due to cyclonic frontal storms and actually developed in temperate environment. To what extent such assumption is valid in the arid environment? How much the impacts of rainfall temporal patterns are reflected in runoff volumes and peaks? The aim objectives of the current study are to answer the above two questions and clarify the validity of aforementioned assumption and exemplify such effect. Real rainfall data collected from rain gauges of Makkah Al-Mukkramah region over a period of more than 20 years are utilized. Temporal rainfall patterns and their parameters are deduced. Many hydrological simulations are performed and comparisons, in terms of runoff volume and peak flows, are made to show the effects of the common rainfall storm patterns and the developed rainfall storm patterns in the region based on the current study. Results indicate that major bursts of the design rainfall storm pattern are located in the first time of the storm period in the two quartiles which is mainly due to convective rainfall type in thunderstorms unlike the commonly used by SCS types relying on frontal cyclonic storms. Makkah Al-Mukkramah temporal rainfall pattern does not behave as the “typical pattern” assumed by SCS distributions that are deduced from different environments. The impacts of the temporal pattern reflected as an overestimate in the runoff peak reached to 68 %. The developed hyetographs and tables presented in the current study are recommended to enhance economical and rational design practice in watersheds of Makkah Al-Mukkramah region.     

Predators of juvenile blue crabs outside of refuge habitats in lower Chesapeake Bay

Blue crabsCallinectes sapidus in lower Chesapeake Bay are subject to high rates of predation during the late summer of their first year of growth as they migrate out of vegetated nursery habitats. Predators, potentially contributing to this pattern, were identified in video-recorded field observations of tethered juvenile crabs (20–25 mm carapace width). Predators were also tested in large laboratory tanks containing similarly-sized untethered crabs as prey. Seven different predators attacked tethered crabs in the field. Only two predators, larger blue crabs and northern puffers,Sphoeroides maculatus, consistently succeeded in preying on crabs in both field and laboratory settings. These results confirm the importance of cannibalism on juvenile blue crabs and identify puffers as a potentially overlooked source of predation pressure.     

Seismic vulnerability evaluation of axially loaded steel built-up laced members I： experimental results

An experimental program was initiated to investigate the seismic performance of built-up laced steel brace members. Quasi-static testing of twelve typical steel built-up laced member （BLM） specimens was conducted. These were designed to span a range of parameters typically encountered for such members based on findings from a survey of commonly used shapes and details that have been historically used. The specimens were subdivided into groups of three different cross-sectional shapes, namely built-up I-shape section, and built-up box shapes buckling about the x or the y axis. Within each group, global and local buckling slenderness ratios had either kl/r values of 60 or 120, and b/t ratios of 8 or 16. The specific inelastic cyclic behavior germane to each specimen, and general observations on overall member hysteretic behavior as a function of the considered parameters, are reported. A companion paper （Lee and Bruneau 2008） investigates this observed response against predictions from analytical models, and behavior in the perspective of system performance.     

Testing the suitability of frictional behaviour for pyroclastic flow simulation by comparison with a well-constrained eruption at Tungurahua volcano (Ecuador)

We use a well-monitored eruption of Tungurahua volcano to test the validity of the frictional behaviour, also called Mohr–Coulomb, which is generally used in geophysical flow modelling. We show that the frictional law is not appropriate for the simulation of pyroclastic flows at Tungurahua. With this law, the longitudinal shape of the simulated flows is a thin wedge of material progressively passing, over several hundreds of metres, from an unrealistic thickness at the front (<<1 mm) to some tens of centimetres. Simulated deposits form piles which accumulate at the foot of the volcano and are more similar to sand piles than natural pyroclastic deposits. Finally, flows simulated with a frictional rheology are not channelised by the drainage system, but affect all the flanks of the volcano. In addition, their velocity can exceed 150 m s⁻¹, allowing pyroclastic flows to cross interfluves at bends in the valley, affecting areas that would not have been affected in reality and leaving clear downstream areas that would be covered in reality. Instead, a simple empirical law, a constant retarding stress (i.e. a yield strength), involving only one free parameter, appears to be much better adapted for modelling pyroclastic flows. A similar conclusion was drawn for the Socompa debris avalanche simulation (Kelfoun and Druitt, J Geophys Res 110:B12202, 2005).     

Shear waves at a corrugated interface between anisotropic elastic and visco-elastic solid half-spaces

Rayleigh’s method of approximation is employed to find out the reflection and transmission coefficients due to an incident plane SH wave at a corrugated interface between a laterally and vertically inhomogeneous anisotropic elastic solid half-space and a laterally and vertically inhomogeneous isotropic visco-elastic solid half-space. The lateral and vertical inhomogeneities are described by the exponential variations of elastic parameters. The formulae of reflection and transmission coefficients are derived in closed form for the first-order approximation of the corrugation. The effects of the corrugation of the interface, the inhomogeneity, the anisotropy, the visco-elasticity and the frequency of the incident wave on these coefficients are studied analytically and numerically for a specific model containing a periodic interface. The results of earlier workers have been reduced as particular cases from the present formulation.     

Earthquake hazard assessment through geospatial model and development of EaHaAsTo tool for visualization: an integrated geological and geoinformatics approach

An earthquake is a natural phenomenon which is very frequent in Himalayan region in India. In southern peninsula India, the spatial occurrence of earthquake is irregular, whereas the northeastern, the north and the northwestern Himalayan parts of India are subjected to regular occurrences of earthquakes as they mark the boundary of the Eurasian and the Indian Plate. Hence, it is important to study and develop spatial model and information tool to understand the seismic phenomenon. The geoinformatic technique plays a significant role in the analysis of geodatabase to study the natural disaster and hazard assessment. The main aim of the present study is to develop geospatial model based on earthquake hazard assessment tool (EaHaAsTo) through integrated geological and geoinformatic techniques to better understand the earthquake occurrences zones. The spatial and non-spatial data were collected and integrated in a GIS to prepare geospatial databases. The thematic and quantitative databases were generated, and analysis was carried out to understand the seismic characteristics of the study area. The geospatial model was developed by integrating thematic databases and geospatial analyzed using weighted linear combination method. Finally, the GIS based on customized EaHaAsTo was developed to visualize the output of the model in qualitative and quantitative forms.     

Effectiveness of Mg–Al-layered double hydroxide for heavy metal removal from mine wastewater and sludge volume reduction

Health hazards from heavy metal pollution in water systems are a global environmental problem. Of similar concern is sludge that results from wastewater treatment due to unsatisfactory sludge management technology. Therefore, the effectiveness of using Mg–Al-layered double hydroxide in the removal of heavy metals from mine wastewater was tested and compared with that of calcium hydroxide [Ca(OH)₂], which is a common treatment method for heavy metal removal. Initially, the mine wastewater contained cations of the heavy metals iron (Fe), zinc (Zn), copper (Cu), and lead (Pb). The Mg–Al-layered double hydroxides were able to remove 371, 7.2, 121, and 0.4 mg/L of these pollutants, respectively, using the co-precipitation method. The removal of these metals is most effective using 0.5 g Mg–Al-layered double hydroxide (Mg/Al molar ratio 4) and 20 min of shaking. Zn was removed by the formation of Zn(NO₃)(OH)·H₂O and Zn₅(NO₃)₂(OH)₈ when LDH, Mg/Al molar ratios of 4 and 2, respectively, were used. Similarly, Fe, Cu, and Pb were removed by the formation of Fe–Al-layered double hydroxide, Cu₂(OH)₃·NO₃ and Pb₄(OH)₄(NO₃)₄, respectively. While Ca(OH)₂ is also capable of reducing the heavy metal concentrations below the Japanese recommended values, this analysis shows that using 0.5 g Mg–Al-layered double hydroxide is a better treatment condition for mine wastewater, because it generates lower sludge volumes than 0.1 g of Ca(OH)₂. The measured sludge volume was 1.5 mL for Mg–Al-layered double hydroxide and 2.5 mL for Ca(OH)₂, a nearly twofold further reduction.