Oxidation of pyrite during extraction of carbonate associated sulfate

The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ³⁴S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ³⁴S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ³⁴S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ³⁴S_pyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe³⁺ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H₂O, not O₂. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.     

Dispersion of the salt-marsh periwinkle Littoraria irrorata: Effects of water level,size, and season

This paper documents horizontal and vertical dispersion patterns of a Texas population of the saltmarsh periwinkle, Littoraria irrorata, over a 15-month period. The study was conducted within a tidal marsh on the Anahuac National Wildlife Refuge in Galveston Bay. Two mark-recapture experiments demonstrated that L. irrorata rarely move more than 2 m from their release point over long periods of time and do not home to individual Spartina plants. Adult L. irrorata forage farther away from the base of Spartina stalks at low tide than do juvenile snails. Remaining near the plant base may decrease both temperature and desiccation stress on juveniles. During warm months, L. irrorata climb grass stalks with tidal inundation and forage on the substratum at low tide. Snails are inactive and aggregate in detrital debris at the base of Spartina clumps during the winter. *** DIRECT SUPPORT *** A01BY058 00016     

The agricultural utility of lithic-mulch gardens: Past and present

The mulching of agricultural fields and gardens with stones, pebbles, volcanic ash and similar lithic materials is a variant agricultural strategy uniquely suited to the constraints of a dryland environment. While the agricultural literature contains reports on limited experiments with stone or gravel mulch, data regarding the employment of lithic mulch are lacking. This paper works to bridge this gap by comparing empirical data collected from prehistoric pebble-mulch gardens in the Galisteo Basin (New Mexico) to contemporary agricultural experiments with lithic mulch. Such past-present and experimental-real world comparisons allow us to more fully address the effectiveness of lithic mulching as an agricultural strategy. It is affirmed that lithic mulch is applied to garden plots, especially during periods of drought, in order to reduce soil erosion from wind and water, increase soil temperature to extend the growing season, increase water infiltration, and reduce the evaporative loss of water from wind and sun. The cumulative effect of this soil and water conserving technique is an increase in crop biomass and crop yield.     

Coupling hydrogeological with surface runoff model in a Poltva case study in Western Ukraine

This paper presents the hydrological coupling of the software framework OpenGeoSys (OGS) with the EPA Storm Water Management Model (SWMM). Conceptual models include the Saint Venant equation for river flow, the 2D Darcy equations for confined and unconfined groundwater flow, a two-way hydrological coupling flux in a compartment coupling approach (conductance concept), and Lagrangian particles for solute transport in the river course. A SWMM river–OGS aquifer inter-compartment coupling flux is examined for discharging groundwater in a systematic parameter sensitivity analysis. The parameter study involves a small perturbation (first-order) sensitivity analysis and is performed for a synthetic test example base-by-base through a comprehensive range of aquifer parametrizations. Through parametrization, the test cases enables to determine the leakance parameter for simulating streambed clogging and non-ocillatory river-aquifer water exchange rates with the sequential (partitioned) coupling scheme. The implementation is further tested with a hypothetical but realistic 1D river–2D aquifer model of the Poltva catchment, where discharging groundwater in the upland area affects the river–aquifer coupling fluxes downstream in the river course (propagating feedbacks). Groundwater contribution in the moving river water is numerically determined with Lagrangian particles. A numerical experiment demonstrates that the integrated river–aquifer model is a serviceable and realistic constituent in a complete compartment model of the Poltva catchment.     

Nonlinear Effect of Wave Propagation in Shallow Water

—In this paper,a nonlinear model is presented to describe wave transformation in shallow wat-er with the zero-vorticity equation of wave-number vector and energy conservation equation.Thenonlinear effect due to an empirical dispersion relation(by Hedges)is compared with that of Dalrymple＇sdispersion relation.The model is tested against the laboratory measurements for the case of a submergedelliptical shoal on a slope beach,where both refraction and diffraction are significant.The computation re-sults,compared with those obtained through linear dispersion relation.show that the nonlinear effect ofwave transformation in shallow water is important.And the empirical dispersion relation is suitable for re-searching the nonlinearity of wave in shallow water.     

Impact Buckling and Post-Buckling of Elasto-Viscoplastic Cylindrical Shell Under Torsion

The dynamic torsional buckling and post-buckling of elasto-plastic circular cylindrical shell isstudied.By the usage of the Bodner-Partom constitutive relation,the present visco-plastic problem is treat-ed as an orthotropic elastic problem.Based on the nonlinear large deflection shell therory,the governingdynamic buckling equation is solved by the Runge-Kutta method,and the critical buckling stress is deter-mined by the B-R criterion.The present paper is mainly focused on the imperfection sensitivity,the strainrate sensitivity,and the dynamic post-buckling characters for the shell loaded dynamically with a constantshear strain rate.Numerical results show that the critical shear stress and imperfection sensitivity will in-crease with the increase of strain rate.It is found that the elastic buckling stress is more sensitive toimperfection than the visco-plastic buckling.The present research also reveals some dynamic post-bucklingcharacters for the cylindrical shell,and it is shown that the shell will vibra     

Strength Analysis of Turret Mooring Productive/Storage Tanker

The longitudinal strength of turret mooring productive/storage tanker is studied.A numeri-cal example has been implemented according to the method presented in this paper to give practical il-lustration.From the results of the numerical example,it is concluded that the turret hole located near theforward of the amidships has small effect on the longitudinal strength of the ship hull.As for design ex-treme value of wave bending moment of storage tanker,statistic method is a more reasonablemethodology,especially with the consideration of the servere environmental conditions.The primary esti-mation of design section modulus of turret storage tanker can be determined by this design bending mo-ment.     

The thermal boundary-layer interpretation of D″ and its role as a plume source

The “anomalous” layer in the lowermost mantle, identified as D″ in the notation of K.E. Bullen, appears in the PREM Earth model as a 150 km-thick zone in which the gradient of incompressibility with pressure, $\text{d}\text{K}\text{d}\text{P}$, is almost 1.6, instead of 3.2 as in the overlying mantle. Since PREM shows no accompanying change in density or density gradient, we identify D″ as a thermal boundary layer and not as a chemically distinct zone. The anomaly in $\text{d}\text{K}\text{d}\text{P}$ is related to the temperature gradient by the temperature dependence of K_s, for which we present a thermodynamic identity in terms of accessible quantities. This gives the numerical result (?K_s/?T)_P=?1.6×10⁷ Pa K^?1 for D″ material. The corresponding temperature increment over the D″ range is 840 K. Such a layer cannot be a static feature, but must be maintained by a downward motion of the lower mantle toward the core-mantle boundary with a strong horizontal flow near the base of D″. Assuming a core heat flux of 1.6 × 10¹² W, the downward speed is 0.07 mm y^?1 and the temperature profile in D″, scaled to match PREM data, is approximately exponential with a scale height of 73 km. The inferred thermal conductivity is 1.2 W m^?1 K^?1. Using these values we develop a new analytical model of D″ which is dynamically and thermally consistent. In this model, the lower-mantle material is heated and softened as it moves down into D″ where the strong temperature dependence of viscosity concentrates the horizontal flow in a layer ～ 12 km thick and similarly ensures its removal via narrow plumes.     

A Probabilistic Model for Fatigue Crack Propagation Analysis

A simple probabilistic model for predicting crack growth behavior under random loading is pre-sented.In the model,the parameters c and m in the Paris-Erdogan Equation are taken as random variables,and their stochastic characteristic values are obtained through fatigue crack propagation tests on an offshorestructural steel under constant amplitude loading.Furthermore,by using the Monte Carlo simulation tech-nique,the fatigue crack propagation life to reach a given crack length is predicted.The tests are conducted toverify the applicability of the theoretical prediction of the fatigue crack propagation.