Petrogenesis of the Late Cretaceous Tholeiitic Volcanism and Oceanic Island Arc Affinity of the Chagai Arc, Western Pakistan

The Late Cretaceous Chagai arc outcrops in western Pakistan, southern Afghanistan and eastern Iran. It is in the Tethyan convergence zone, formed by northward subduction of the Arabian oceanic plate beneath the Afghan block. The oldest unit of the Chagai arc is the Late Cretaceous Sinjrani Volcanic Group. This is composed of porphyritic lava flows and volcaniclastic rocks, and subordinate shale, sandstone, limestone and chert. The flows are fractionated low-K tholeiitic basalts, basaltic-andesites, and andesites. Relative enrichment in their LILE and depletion in HFSE, and negative Nb and Ta and positive K, Ba and Sr anomalies point to a subduction-related origin. Compared to MORB, the least fractionated Chagai basalts have low Na2O, Fe2O3T, CaO, Ti, Zr, Y and 87Sr/86Sr. Rather than an Andean setting, these results suggest derivation from a highly depleted mantle in an intraoceanic arc formed by Late Cretaceous convergence in the Ceno-Tethys. The segmented subduction zone formed between Gondwana and a collage of small continental blocks (Iran, Afghan, Karakoram, Lhasa and Burma) was accompanied by a chain of oceanic island arcs and suprasubduction ophiolites including Semail, Zagros, Chagai-Raskoh, Kandahar, Muslim Bagh, Waziristan and Kohistan-Ladakh, Nidar, Nagaland and Manipur. These complexes accreted to the southern margin of Eurasia in the Late Cretaceous.     

Weather yield model for the semi tropical region (Pakistan)

Weather models are essential tools for checking of the effect of the weather elements in terms of their effect on the production of the crop. This research is an attempt to see the effect of only two variables i.e., temperature and rainfall for the division Faisalabad (semitropical region of Pakistan).The model fitted is of the linear form:the values of a,b, c have been found. The expected yield has been calculated by using the aridity indices (X1 and X2 ) and the result in the form of coefficient of determination R2 has been found equal to 0.166. The significance of the regression coefficient has been tested, which shows that the contribution to the yield from aridity index at germination and that at ripening is significant.The wheat yields are the results of a wide variety of variables, most of which show varying degree of relationship with one another, some positive and some negative in terms of output. These variables may be technology, fertilizers, pesticides, epidemics, kinds of seeds used, market price of crop and the area under cultivation etc, which can be the source of variation in the wheat yield. Since rainfall during germination and temperature at the ripening periods are the necessary factors for the yield of wheat, for this purpose these parameters have been studied in order to their contribution.     

Reconnaissance geology in Upper Chitral,Baroghil and Karambar districts (northern Karakorum,Pakistan)

During the summer of 1992 a geological expedition crossed the northern Karakorum range in northern Pakistan, from the Chitral to Karambar valleys, from the villages of Mastuj to Imit. Some of the areas visited were geologically unknown. A number of structural units were crossed, belonging to the Karakorum block or to other crustal blocks north of it. They are: (a) the axial batholith, in which three plutonic bodies have been identified, and (b) the northern sedimentary belt (NSB), in which three major tectonostratigraphic units form thrust stacks dipping to the north. Their internal stratigraphy and structural style are partly different. The most complete contains a crystalline basement, transgressed by a marine succession during the Early Ordovician. The youngest strata are represented by the Reshun conglomerate, of inferred Cretaceous age. The northernmost unit of the NSB is tightly folded, whereas the central one forms a monocline. Vertical faults, mainly strike-slip, dissect the thrusted slabs. Metamorphic deformation is absent or reaches only the anchizone in the studied sector of the Karakorum NSB. To the north of the Karakorum proper there are several other tectonic units, separated by vertical faults. They are, from south to north: (a) the Taš Kupruk zone, with metavolcanics of basaltic to latibasaltic composition; (b) the Atark unit, mostly consisting of massive carbonate rocks of Mesozoic age; and (c) the Wakhan slates which consist of a thick widespread succession of dark slates, metasiltites and sandstones. The fine-grained elastic rocks are supposed to be Palaeozoic to Early Triassic in age. The Wakhan slates are intruded by plutons belonging to the East Hindu Kush batholith, from which a single K/Ar age on muscovite gave a Jurassic age.     

Solubility of platinum and palladium in silicate melts under high water pressure as a function of redox conditions

The solubility of platinum and palladium in a silicate melt of the composition Di ₅₅ An ₃₅ Ab ₁₀ was determined at 1200°C and 2 kbar pressure in the presence of H₂O-H₂ fluid at an oxygen fugacity ranging from the HM to WI buffer equilibria. The influence of sulfur on the solubility of platinum in fluid-bearing silicate melt was investigated at a sulfur fugacity controlled by the Pt-PtS equilibrium at 1200°C and a pressure defined in such a way that the \(f_{H_2 O} \) and \(f_{O_2 } \) values were identical to those of the experiments without sulfur. The experiments were conducted in a high pressure gas vessel with controlled hydrogen content in the fluid. Oxygen fugacity values above the NNO buffer were controlled by solid-phase buffer mixtures using the two-capsule technique. Under more reducing conditions, the contents of H₂O and H₂ were directly controlled by the argon to hydrogen ratio in a special chamber. The hydrogen fugacity varied from 5.2 × 10^?2 bar (HM buffer) to 1230 bar (\(X_{H_2 } \) = 0.5). Pt and Pd contents were measured in quenched glass samples by neutron activation analysis. The results of these investigations showed that the solubility of Pt and Pd increases significantly in the presence of water compared with experiments in dry systems. The content of Pd within the whole range of redox conditions and that of Pt at an oxygen fugacity between the HM to MW buffer reactions are weakly dependent on \(f_{O_2 } \) and controlled mainly by water fugacity. This suggests that, in addition to oxide Pt and Pd species soluble at the ppb level in haplobasaltic melts, much more soluble (ppm level) hydroxide complexes of these metals are formed under fluid-excess conditions. Despite a decrease in water fugacity under reducing conditions, Pt solubility increases sharply near the MW buffer. It was shown by electron paramagnetic resonance spectrometry that, in contrast to dry melts, fluid-saturated silicate melts do not contain a pure metal phase (micronuggets). Therefore, the increase in Pt solubility under reducing conditions can be explained by the formation of Pt hydride complexes or Pt-fluid-silicate clusters. At a sulfur fugacity controlled by the Pt-PtS equilibrium, the solubility of Pt in iron-free silicate melts as a function of redox conditions is almost identical to that obtained in the experiments without sulfur at the same water and oxygen fugacity values. These observations also support Pt dissolution in iron-free silicate melts as hydroxide species.     

Groundwater resource development in Jamui District,Bihar, India: an overview

Because agriculture is the main source of livelihood for the bulk of the population in Jamui District, the importance of developing irrigation facilities in any programme of economic regeneration can hardly be over emphasized. It is, therefore, imperative that groundwater development be considered as an important step to drought mitigation in the Jamui district. The present study was carried out in such a way that technical and economic viability of any groundwater development plan can be thoroughly scrutinized. In this paper the hydrogeological framework of the district was established based on aquifer disposition, orientation of potential fracture systems and their hydraulic characteristics. Considering the aquifer geometry and yield potential of different structures, a blueprint for a groundwater development plan was prepared. An economic analysis of the development plan also was attempted. The analysis yielded results that made it possible to evaluate parameters such as cost–benefit ratio, incremental benefits and internal rate of return used to assess the economic viability of the groundwater development plan. Electronic Publication     

Riverine flood mapping and impact assessment using remote sensing technique: a case study of Chenab flood-2014 in Multan district,Punjab, Pakistan

The Multan district is mainly prone to riverine floods but has remained understudied. Chenab flood-2014 was the worst flood that this district experienced in recorded history. This study applies remote sensing (RS) techniques to estimate the extent, calculate duration, assess the major causes and resulting impacts of the flood-2014, using Landsat-8 OLI images. These images were obtained for pre-flood, during-flood and post-flood instances. Secondary data of flood causing factors were obtained for comprehensive analysis. Spatially trained and validated datasets were obtained through Google Earth platform and Global positioning system. The supervised classification with maximum likelihood algorithm was used to classify land use and land cover of the study area. The Modified Normalized Difference Water Index was utilized to detect flood inundation extent and duration, and Normalized Difference Vegetation Index was utilized to monitor vegetation coverage and changes. The analysis allowed us to assess flood causes, and calculate the extent of the flooded areas with duration and recession, as well as damages to standing crops and built-up areas. The results revealed that the flood-2014 occurred due to heavy rains in early September in upper Chenab catchment. The flood inundation continued for around two months, which heavily affected agriculture and built-up areas. The present study introduces practical use of RS techniques to provide basis for effective flood inundation mapping and impact assessment, as an application for early flood response and recovery in the world.

     

Riverine flood assessment in Jhang district in connection with ENSO and summer monsoon rainfall over Upper Indus Basin for 2010

Pakistan has experienced severe floods over the past decades due to climate variability. Among all the floods, the flood of 2010 was the worst in history. This study focuses on the assessment of (1) riverine flooding in the district Jhang (where Jhelum and Chenab rivers join, and the district was severely flood affected) and (2) south Asiatic summer monsoon rainfall patterns and anomalies considering the case of 2010 flood in Pakistan. The land use/cover change has been analyzed by using Landsat TM 30 m resolution satellite imageries for supervised classification, and three instances have been compared, i.e., pre-flooding, flooding, and post-flooding. The water flow accumulation, drainage density and pattern, and river catchment areas have been calculated by using Shutter Radar Topography Mission digital elevation model 90 m resolution. The standard deviation of south Asiatic summer monsoon rainfall patterns, anomalies and normal (1979–2008) has been calculated for July, August, and September by using rainfall data set of Era interim (0.75° × 0.75° resolution). El Niño Southern Oscillation has also been considered for its role in prevailing rainfall anomalies during the year 2010 over Upper Indus Basin region. Results show the considerable changing of land cover during the three instances in the Jhang district and water content in the rivers. Abnormal rainfall patterns over Upper Indus Basin region prevailed during summer monsoon months in the year 2010 and 2011. The El Niño (2009–2010) and its rapid phase transition to La Niña (2011–2012) may be the cause of severity and disturbances in rainfall patterns during the year 2010. The Geographical Information System techniques and model based simulated climate data sets have been used in this study which can be helpful in developing a monitoring tool for flood management.     

A PETROLOGICAL OVERVIEW OF THE KOHISTAN MAGMATIC ARC, NW HIMALAYA, N. PAKISTAN

A PETROLOGICAL OVERVIEW OF THE KOHISTAN MAGMATIC ARC, NW HIMALAYA, N. PAKISTAN1　TahirkheliRAK ,MattauerM .ProustF ,etal.1979.In :GeodynamicsofPakistan[C].FarahA ,DeJongKA ,eds.GeolSurvPakistan ,Quetta ,1979.12 5～ 130 . 2　CowardMP ,WindleyBF ,BroughtonRD ,etal.In :CollisionTectonics[C]..CowardMP ,RiesAC ,eds.GeolSoc,London ,SpecPub ,1986 ,19:2 0 3～ 2 19. 3　BardJP ,MaluskiH ,MattePh ,etal.GeolBull ,PeshawarUniversity ,1980 ,13:87～ 93. …     

Assessment of petroleum biodegradation using stable hydrogen isotopes of individual saturated hydrocarbon and polycyclic aromatic hydrocarbon distributions in oils from the Upper Indus Basin,Pakistan

The stable hydrogen isotopic compositions (δD) of selected aliphatic hydrocarbons (n-alkanes and isoprenoids) in eight crude oils of similar source and thermal maturity from the Upper Indus Basin (Pakistan) were measured. The oils are derived from a source rock deposited in a shallow marine environment. The low level of biodegradation under natural reservoir conditions was established on the basis of biomarker and aromatic hydrocarbon distributions. A plot of pristane/n-C₁₇ alkane (Pr/n-C₁₇) and/or phytane/n-C₁₈ alkane (Ph/n-C₁₈) ratios against American Petroleum Institute (API) gravity shows an inverse correlation. High Pr/n-C₁₇ and Ph/n-C₁₈ values and low API gravity values in some of the oils are consistent with relatively low levels of biodegradation. For the same oils, δD values for the n-alkanes relative to the isoprenoids are enriched in deuterium (D). The data are consistent with the removal of D-depleted low molecular weight (LMW) n-alkanes (C₁₄–C₂₂) from the oils. The δD values of isoprenoids do not change with progressive biodegradation and are similar for all the samples. The average D enrichment for n-alkanes with respect to the isoprenoids is found to be as much as 35‰ for the most biodegraded sample. For example, the moderately biodegraded oils show an unresolved complex mixture (UCM), loss of LMW n-alkanes (<C₁₅) and moderate changes in the alkyl naphthalene distributions. The relative susceptibility of alkyl naphthalenes at low levels of biodegradation is discussed. The alkyl naphthalene biodegradation ratios were determined to assess the effect of biodegradation. The dimethyl, trimethyl and tetramethyl naphthalene biodegradation ratios show significant differences with increasing extent of biodegradation.     

Geosynthesis of dibenzothiophene and alkyl dibenzothiophenes in crude oils and sediments by carbon catalysis

Sediment extracts and crude oils have been shown to contain methyl substituted biphenyls and dibenzothiophenes, with isomer distributions suggesting a geochemical relationship between the two compound classes. Laboratory simulation experiments have shown that carbon catalyses the reaction between surface adsorbed sulfur and biphenyl to form dibenzothiophene. Similarly, the methyl substituted biphenyls reacted to yield corresponding methyl dibenzothiophenes. We suggest that the widespread distribution of dibenzothiophene and alkylated dibenzothiophenes in sediments and crude oils is the result of a catalytic reaction of biphenyl ring systems and surface-adsorbed sulfur on the surface of carbonaceous material.