Anomalous subsidence on the rifted volcanic margin of Pakistan: No influence from Deccan plume

The role of hotter than ambient plume mantle in the formation of a rifted volcanic margin in the northern Arabian Sea is investigated using subsidence analysis of a drill site located on the seismically defined Somnath volcanic ridge. The ridge has experienced > 4 km of subsidence since 65 Ma and lies within oceanic lithosphere. We estimate crustal thickness to be 9.5–11.5 km. Curiously < 400 m of the thermal subsidence occurred prior to 37 Ma, when subsidence rates would normally be at a maximum. We reject the hypothesis that this was caused by increasing plume dynamic support after continental break-up because the size of the thermal anomalies required are unrealistic (> 600 °C), especially considering the rapid northward drift of India relative to the Deccan-Réunion hotspot. We suggest that this reflects very slow lithospheric growth, possibly caused by vigorous asthenospheric convection lasting > 28 m.y., and induced by the steep continent–ocean boundary. Post-rift slow subsidence is also recognized on volcanic margins in the NE Atlantic and SE Newfoundland and cannot be used as a unique indicator of plume mantle involvement in continental break-up.     

Geochemical modeling,fate distribution,and risk exposure of potentially toxic metals in the surface sediment of the Shyok suture zone,northern Pakistan

The objective of the current study was to assess the contamination of potentially toxic metals (PTMs) in weathered surface sediment, along stream tributaries, and surrounding area of the river Chitral, Shyok suture zone district Chitral, Pakistan. To understand the geochemical features of 113 sediment, samples were collected from the Mirkhani and Drosh area. Then, different statistical tools including the geo-accumulation index (Igeo), cluster analysis (CA), principal component analysis (PCA), and ecological risk assessment (ERA) were used to unravel the origin, intensity, and exposure level of PTMs to control risk and restore the ecosystem within the study area. The results for the PTMs namely nickle (Ni), chromium (Cr), copper (Cu), cadmium (Cd), lead (Pb), zinc (Zn), and cobalt (Co) in Mirkhani and Drosh were in the following ranges: 10–150, 15–210, 15–250, 0.08–1.00, 10–70, 76–240 and 14–51; and 13–240, 17–210, 15–150, 0.08–0.60, 7–140, 47–150 and 13–36 mg/kg, respectively. In consequence, the potential ecological risk caused by Pb, Ni, Cu, Co, Cr, and Zn is reflected by the percentages of samples with an ecological risk index (ERI) greater than one which were 100%, 91%, 100%, 100%, 92%, and 100%, respectively. However, the overall mean decreasing order of ecological risk of PTMs in the district Chitral was Pb > Ni > Cu > Co > Cr > Zn > Cd. Moreover, the PCA yielded 78% variability which indicated that mineral prospects play an important role in the contamination of sediment. Furthermore, the mineral phases of Pb and Zn suggested supersaturation, while that for Cd revealed unsaturation. The results of Igeo, ERI, and CA indicated contamination of PTMs in the study area. The ERI value of Pb, Ni, Cu, Co, Cr, and Zn was higher than 1 suggesting an ecological risk in the study area. Moreover, the current study showed the dominance of geogenic contamination with major contributions from ultramafic rock and known mineral prospects. Therefore, contaminated sediment of the Shyok suture zone is extremely detrimental to the aquatic ecosystem of the study area.     

Nickel sulphide fire assay for the collection of the platinum group elements and gold from chromitites using reduced bead size

Summary Fire assay is a classical method for the separation of the platinum group elements and gold (PGE + Au). In nickel sulphide fire assay nickel and sulphur are used for the preconcentration of PGE + Au. In the past the authors have successfully reduced the weight of the collectors used without affecting the recovery of the elements from silicate material and eliminated the reagent blank problem. In this work the authors have applied the small bead size to chromitites. Chromitites can be difficult to fuse, and the authors have applied their modified technique to improve the dissolution of chromitites. This paper describes the application of the reduced bead size to the preconcentration of the PGE + Au from chromitites, by using only 0.5 g of nickel compared to the 10 g used by other fire assay workers.

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Nickelsulfid Fire assay zur Anreicherung von Platingruppenelementen und Gold aus Chromititen

Zusammenfassung Fire assay ist die klassische Methode um Platingruppenelemente und Gold (PGE + Au) vor der Analyse anzureichern und von der Matrix abzutrennen. Zum Sammeln der PGE und Au wird Nickelsulfid verwendet. Durch Verwendung möglichst kleiner Mengen konnte das Problem eventueller Verunreinigung der verwendeten Reagenzien ausgeschaltet werden. In der vorliegenden Arbeit wird diese Methode bei Chromititen angewendet, wobei hier ein modifiziertes Verfahren zum Lösen dieser Gesteine verwen det wird. Es werden 0.5 g Nickel zum Abtrennen der PGE und Au von Chromititen verwendet, was einer 20-fachen Mengenreduktion des Kollektormaterials gegenüber herkömmlichen Methoden entspricht.

     

Streamflow response to shrinking glaciers under changing climate in the Lidder Valley,Kashmir Himalayas

The study investigated the streamflow response to the shrinking cryosphere under changing climate in the Lidder valley, Upper Indus Basin(UIB), Kashmir Himalayas. We used a combination of multitemporal satellite data and topographic maps to evaluate the changes in area, length and volume of the glaciers from 1962 to 2013. A total of 37 glaciers from the Lidder valley, with an area of 39.76 km~2 in 1962 were selected for research in this study. It was observed that the glaciers in the valley have lost ~28.89 ±0.1% of the area and ~19.65 ±0.069% of the volume during the last 51 years, with variable interdecadal recession rates. Geomorphic and climatic influences on the shrinking glacier resources were studied. 30-years temperature records(1980-2010) in the study area showed a significant increasing trend in all the seasons. However, the total annual precipitation during the same period showed a nonsignificant decreasing trend except during the late summer months(July, August and September), when the increasing trend is significant. The depletion of glaciers has led to the significant depletion of the streamflows under the changing climate in the valley. Summer streamflows(1971-2012) have increased significantly till mid-nineties but decreased significantly thereafter, suggesting that the tipping point of streamflow peak, due to the enhanced glacier-melt contribution under increasing global temperatures, may have been already reached in the basin. The observed glacier recession and climate change patterns, if continued in future, would further deplete the streamflows with serious implications on water supplies for different uses in the region.     

TECTONIC EVOLUTION OF THE EOCENE DROSH-VOLCANO-SEDIMENTARY BASIN IN NW-KOHISTAN ISLAND ARC TERRANE, HINDUKUSH, N. PAKISTAN

In NW Himalayas, the suture zone between the collided Indian and the Karakoram plates is occupied by crust of the Cretaceous Kohistan Island\|Arc Terrane [1] . Late Cretaceous (about 90Ma) accretion with the southern margin of the Karakoram Plate at the site of the Shyok Suture Zone turned Kohistan to become an Andean\|type margin. The Neotethys was completely subducted at the southern margin of Kohistan by Early Tertiary, leading to collision between Kohistan and continental crust of the Indian plate at the site of the Main mantle thrust.More than 80% of the Kohistan terrane comprises plutonic rocks of (1) ultramafic to gabbroic composition forming the basal crust of the intra\|oceanic stage of the island arc, and (2) tonalite\|granodiorite\|granite composition belong to the Kohistan Batholith occupying much of the intermediate to shallow crust of the terrane mostly intruded in the Andean\|type margin stage [2] . Both these stages of subduction\|related magmatism were associated with volcanic and sedimentary rocks formed in Late Cretaceous and Early Tertiary basins. This study addresses tectonic configuration of Early Tertiary Drosh basin exposed in NW parts of the Kohistan terrane, immediately to the south of the Shyok Suture Zone.     

A joint analysis of river runoff and meteorological forcing in the Karakoram,upper Indus Basin

Satellite‐geodetic altimetry investigations in the Karakoram have indicated slight mass gain or loss of the glaciers during the early part of 21st century. Equivalent discharge in the upper Indus Basin due to these mass changes has been estimated at 5 to 10% of mean annual flow. However, satellite altimetry and geodetic glacier mass estimates in the extreme topography of the Karakoram have not yet been counter‐validated by hydrological analysis. Therefore, we present a first cross validation of three to five decades of river flow data from the three major watersheds in the Karakoram, with matching series of monthly precipitation, temperature, and evaporation provided by six atmospheric reanalysis products for 1979–2014. The analyses suggest that in most cases river flows have been increasing steadily from the end of the 1960s and 1970s to the middle of the 1990s and have stabilized or are in decline since then. Hunza watershed in Karakoram West shows consistently declining flows over the first half of the analysis period and stable flows during the second half for most of the summer melting season, suggesting mass accumulation. Rising river flows in the Shyok and Shigar watersheds, followed by stabilizing or slightly declining flows from 1995 onward, can be explained by consistently increasing precipitation during the first half of the analysis period, and successive stabilization or minor decline thereof. Flow data do not necessarily suggest considerable loss or gain of glacial mass in the Karakoram during the late 90s and early 2000s as suggested by satellite‐based altimetry studies.     

Petroleum geochemistry of the Potwar Basin, Pakistan: 1. Oil-oil correlation using biomarkers, δC and δD

Geochemical characterisation of 18 crude oils from the Potwar Basin (Upper Indus), Pakistan is carried out in this study. Their relative thermal maturities, environment of deposition, source of organic matter (OM) and the extent of biodegradation based on the hydrocarbon (HC) distributions are investigated. A detailed oil-oil correlation of the area is established. Gas chromatography-mass spectrometry (GC-MS) analyses and bulk stable carbon and hydrogen isotopic compositions of saturated and aromatic HC fractions reveals three compositional groups of oils. Most of the oils from the basin are typically generated from shallow marine source rocks. However, group A contains terrigenous OM deposited under highly oxic/fluvio-deltaic conditions reflected by high pristane/phytane (Pr/Ph), C₃₀ diahopane/C₂₉Ts, diahopane/hopane and diasterane/sterane ratios and low dibenzothiophene (DBT)/phenanthrene (P) ratios. The abundance of C₁₉-tricyclic and C₂₄-tetracyclic terpanes are consistent with a predominant terrigenous OM source for group A. Saturated HC biomarker parameters from the rest of the oils show a predominant marine origin, however groups B and C are clearly separated by bulk δ¹³C and δD and the distributions of the saturated HC fractions supporting variations in source and environment of deposition of their respective source rocks. Moreover, various saturated HC biomarker ratios such as steranes/hopanes, diasteranes/steranes, C₂₃-tricyclic/C₃₀ hopane, C₂₈-tricyclic/C₃₀ hopane, total tricyclic terpanes/hopanes and C₃₁(R + S)/C₃₀ hopane show that two different groups are present. These biomarker ratios show that group B oils are generated from clastic-rich source rocks deposited under more suboxic depositional environments compared to group C oils. Group C oils show a relatively higher input of algal mixed with terrigenous OM, supported by the abundance of extended tricyclic terpanes (up to C₄₁₊) and steranes.Biomarker thermal maturity parameters mostly reached to their equilibrium values indicating that the source rocks for Potwar Basin oils must have reached the early to peak oil generation window, while aromatic HC parameters suggest up to late oil window thermal maturity. The extent of biodegradation of the Potwar Basin oils is determined using various saturated HC parameters and variations in bulk properties such as API gravity. Groups A and C oils are not biodegraded and show mature HC profiles, while some of the oils from group B show minor levels of biodegradation consistent with high Pr/n-C₁₇, Ph/n-C₁₈ and low API gravities.     

Potentially harmful metals,and health risk evaluation in groundwater of Mardan,Pakistan: Application of geostatistical approach and geographic information system

This study investigates the values of pH, total dissolved solids (TDS), elevation, oxidative reduction potential (ORP), temperature, and depth, while the concentrations of Br, and potentially harmful metals (PHMs) such as Cr, Ni, Cd, Mn, Cu, Pb, Co, Zn, and Fe in the groundwater samples. Moreover, geographic information system (GIS), XLSTAT, and IBM SPSS Statistics 20 software were used for spatial distribution modeling, principal component analysis (PCA), cluster analysis (CA), and Quantile-Quantile (Q-Q) plotting to determine groundwater pollution sources, similarity index, and normal distribution reference line for the selected parameters. The mean values of pH, TDS, elevation, ORP, temperature, depth, and Br were 7.2, 322 mg/L, 364 m, 188 mV, 29.6 °C, 70 m, 0.20 mg/L, and PHMs like Cr, Ni, Cd, Mn, Cu, Pb, Co, Zn, and Fe were 0.38, 0.26, 0.08, 0.27, 0.36, 0.22, 0.04, 0.43 and 0.86 mg/L, respectively. PHMs including Cr (89%), Cd (43%), Mn (23%), Pb (79%), Co (20%), and Fe (91%) exceeded the guideline values set by the world health organization (WHO). The significant R² values of PCA for selected parameters were also determined (0.62, 0.67, 0.78, 0.73, 0.60, 0.87, ?0.50, 0.69, 0.70, 0.74, ?0.50, 0.70, 0.67, 0.79, 0.59, and ?0.55, respectively). PCA revealed three geochemical processes such as geogenic, anthropogenic, and reducing conditions. The mineral phases of Cd(OH)_2, Fe(OH)_3, FeOOH, Mn₃O_4, Fe₂O_3, MnOOH, Pb(OH)_2, Mn(OH)_2, MnO_2, and Zn(OH)₂ (?3.7, 3.75, 9.7, ?5.8, 8.9, ?3.6, 2.2, ?4.6, ?7.7, ?0.9, and 0.003, respectively) showed super-saturation and under-saturation conditions. Health risk assessment (HRA) values for PHMs were also calculated and the values of hazard quotient (HQ), and hazard indices (HI) for the entire study area were increased in the following order: Cd>Ni>Cu>Pb>Mn>Zn>Cr. Relatively higher HQ and HI values of Ni, Cd, Pb, and Cu were greater than one showing unsuitability of groundwater for domestic, agriculture, and drinking purposes. The long-term ingestion of groundwater could also cause severe health concerns such as kidney, brain dysfunction, liver, stomach problems, and even cancer.     

A field study investigating the potential use of phosphorus combined with organic amendments on cadmium accumulation by wheat and subsequent rice

A field study was performed to determine the efficiency of diammonium phosphate (DAP) applied alone or combined with biochar, lignite, and farmyard manure (FYM) on growth and cadmium (Cd) accumulation in wheat and rice. Before crop sowing, different treatments were applied in the field such as a control (T₁), DAP alone (0.1%, T₂), DAP + lignite (0.05% each, T₃), DAP + FYM (0.05% each, T₄), and DAP + biochar (0.05% each, T₅). Afterwards, the wheat seeds were sown in the soil. At wheat postharvest, rice was sown without any further treatment. Raw effluent was applied as an irrigation source during the whole growth period of both crops since it is the common practice of the farmers of study area. It was revealed that the use of amendments enhanced the yield and photosynthesis but lowered the Cd contents in straw as well as grains of both crops. In both crops, the highest yield of straw and grain was found in DAP + FYM whereas the lowest Cd concentration was found in DAP alone. The ammonium bicarbonate-DTPA extractable Cd of post wheat and post rice soils were decreased while the soil pH and immobilization index were increased in all treatments as compared with the control. The present field study highlighted that the DAP + FYM can be effective in increasing yield with decreased Cd concentrations in crop grains.