Isolation and characterization of alkane degrading bacteria from petroleum reservoir waste water in Iran (Kerman and Tehran provenances)

Petroleum products spill and leakage have become two major environmental challenges in Iran. Sampling was performed in the petroleum reservoir waste water of Tehran and Kerman Provinces of Iran. Alkane degrading bacteria were isolated by enrichment in a Bushnel–Hass medium, with hexadecane as sole source of carbon and energy. The isolated strains were identified by amplification of 16S rDNA gene and sequencing. Specific primers were used for identification of alkane hydroxylase gene. Fifteen alkane degrading bacteria were isolated and 8 strains were selected as powerful degradative bacteria. These 8 strains relate to Rhodococcus jostii, Stenotrophomonas maltophilia, Achromobacter piechaudii, Tsukamurella tyrosinosolvens, Pseudomonas fluorescens, Rhodococcus erythropolis, Stenotrophomonas maltophilia, Pseudomonas aeruginosa genera. The optimum concentration of hexadecane that allowed high growth was 2.5%. Gas chromatography results show that all strains can degrade approximately half of hexadecane in one week of incubation. All of the strains have alkane hydroxylase gene which are important for biodegradation. As a result, this study indicates that there is a high diversity of degradative bacteria in petroleum reservoir waste water in Iran.     

Geochemistry, petrogenesis and radioactivity of El Hudi I-type younger granites, South Eastern Desert, Egypt

The present study deals with geochemical characteristics and petrogenesis of three younger granite varieties (coarse-grained biotite-muscovite granites (CBG), garnetiferous muscovite granites (GMG) and Abu Aggag biotite granites (AAG)) in El-Hudi area, east of Aswan, southeastern desert of Egypt. Mineral chemistry and whole rock chemistry data revealed that all granites have high SiO₂ (70.8-74.7 wt.%), Al₂O₃ (12.8-14.3 wt.%), Na₂O and K₂O (>3.2 wt.%) contents with high Na₂O/K₂O ratios (～>1). Plagioclase feldspars range in composition from albite to oligoclase (An_9-27) in CBG, oligoclase (An_13-18) in GMG and albite (An_2-6) in AAG. Potash feldspars are mainly perthitic microcline and exhibit chemical formulae as (Or_93-96 Ab_7-4 An₀) in CBG, (Or_95-98 Ab_5-2 An₀) in GMG and (Or_82-98 Ab_18-2 An₀) in AAG. Biotites from CBG and GMG are enriched in (Mg and Ti) and depleted in (Al, Fe, Mn and K) compared with those of AAG. Biotites from CBG and GMG had been derived from calc-alkaline magma, whereas those from AAG had been derived from peraluminous magma. Chlorites from CBG and GMG are Mg-Fe bearing, while that from AAG is Fe-rich chlorite (chamosite). The CBG and GMG are Mg-rich monzogranites originated from high-K calc-alkaline magma with metaluminous to mildly peraluminous nature. The AAG are Fe-rich monzogranites to syenogranites generated from high-K calc-alkaline peraluminous magma. Both CBG and GMG are late- to post-orogenic granites, while the AAG are post-orogenic granites. All three granite varieties are considered as evolved I-type granites, formed under low to moderate water pressures (～ 0.5-7 kbars) and relatively high ranges of crystallization temperatures (～700-890°C). They were generated from partial melting of crustal materials at lower (CBG >30 km depth) and intermediate (GMG & AAG ～20-30 km depth) levels. The crystal fractionation was the predominant process during differentiation of parent magmas of these granites. Geochemical characteristics manifest that AAG represent the highly fractionated member of magma cycle differs from that produced CBG and GMG. The CBG are relatively enriched in both U and Th existing only within the accessory minerals such as zircon, sphene, and allanite.     

Sorption of lead by chemically modified rice bran

In this work, the effectiveness of native and chemically modified rice bran to remove heavy metal Pb(II) ions from aqueous solution was examined. Chemical modifications with some simple and low-cost chemicals resulted in enhancement of the adsorption capacities and had faster kinetics than native rice bran. Experiments were conducted in shake flasks to monitor the upshot of parameters over a range of pH, initial Pb(II) concentrations and contact times using a batch model study. The sorption capacities q (mg g^?1) increased in the following order: NaOH (147.78), Ca(OH)₂ (139.08), Al(OH)₃ (127.24), esterification (124.28), NaHCO₃ (118.08), methylation (118.88), Na₂CO₃ (117.12) and native (80.24). The utmost uptake capacity q (mg g^?1) was shown by NaOH-pretreated rice bran. The results showed that, using NaOH-modified rice bran, the chief removal of Pb(II) was 74.54 % at pH 5, primary Pb(II) concentration 100 mg L^?1 and contact time 240 min. Equilibrium isotherms for the Pb(II) adsorption were analyzed by Langmuir and Freundlich isotherm models. The Langmuir isotherm model, showing Pb(II) sorption as accessible through the high value of the correlation coefficient (R ² = 0.993), showed a q _max value of 416.61 mg g^?1. The kinetic model illustrated adsorption rates well, depicted by a second order, which gives an indication concerning the rate-limiting step. Thermodynamic evaluation of the metal ion ?G ^o was carried out and led to the observation that the adsorption reaction is spontaneous and endothermic in nature. NaOH chemically modified rice bran was a superb biosorbent for exclusion of Pb(II) and proved to be excellent for industrial applications.     

Mineralogy and microchemistry of the Egat gold deposit, South Eastern Desert of Egypt

Gold-bearing quartz lodes from the Egat gold mine, South Eastern Desert of Egypt, are associated with pervasively silicified, highly sheared ophiolitic metagabbro and island-arc metavolcanic rocks. The mineralized quartz veins and related alteration haloes are controlled by NNW-trending shear/fault zones. Microscopic and electron probe microanalyses (EPMA) data of the ore and gangue minerals reveal that fine-grained auriferous sulfarsenides represent early high-temperature (355–382 °C) phases, with formation conditions as (fS₂?=??10, and fO₂ around ?31). A late, low-temperature (302–333 °C) assemblage includes coarse pyrite, arsenopyrite, and free-milling gold grains (88–91 wt.% Au), with formation conditions as (fS₂?=??8 and fO₂ around ?30). Gold was impounded within early sulfarsenides, while free-milling gold blebs occur along microfractures in quartz veins and as inclusions in late sulfides. Infiltration of hydrothermal fluids under brittle–ductile shear conditions led to mobilization of refractory Au from early sulfarsenide phases and reprecipitated free gold, simultaneous with silicification of the host rocks. The positive correlation between Au and As favors and verifies the use of As as the best pathfinder for gold targets, along the NNW-trending shear zones.     

Evidences of Holocene transgression on Domingos Petrolini Swamp, southern coastal plain, Rio Grande do Sul, Brazil

The Domingos Petrolini Swamp, located on the Southern Coastal Plain of Rio Grande do Sul, near the town of Rio Grande, constitutes an ample holocene lagoonal deposit. Events related to the holocene transgression and their diverse phases of glacial-eustatic ocillations were found through palynological analysis. Bases on these palynological data, four distinct phases to the paleoenvironmental evolution of the ecosystem were identified. It has also shown a transgressive restricted marine sequence on the base , which suggests the existence of a coastal brackish lagoon or a marisme type of environment. Later, there was a gradation for continentality conditions along with a scarce pollinical record. The third phase is characterized by the presence of marine components and halophyte vegetation, showing another transgressive event in that place. Lastly, the end of direct marine influence over the swamp was recorded and also the vegetation development as it appears these days.     

Impact of desalination plants brine injection wells on coastal aquifers

A new methodology is developed in assessing environmental impacts of desalination plants discharging brine into the ground. The main environmental problem of the desalination of seawater is the brine disposal. The brine is commonly discharged into the sea or injected into a saline aquifer. In the case of injection into the ground, it is necessary to design a disposal system in a way that respects the environment and is sustainable. Laboratory and computational methods have been utilized to simulate the unsteady three-dimensional (3D) phenomena of subsurface brine disposal. The computational software used is SEAWAT, which is a 3D unsteady variable-density flow simulation model. The model is first used to simulate the laboratory results, and good agreement is achieved. Then, hypothetical problems are designed and simulated of groundwater extraction and brine disposal by desalination stations. The major purpose of these hypothetical problems is to delineate a methodology and to create design charts for design and management of production and injection well fields for coastal desalination plants. Several design charts have been developed with 36 scenarios for two well configurations created by four design parameters: relative salt concentration (RSC), production and injection rates (Q _d , Q _r ), well spacing (S), and simulation period (T).     

Dynamics of particle creation in relativistic viscous fluid Universe in Brans Dicke theory

The study of dynamics of the particle creation in relativistic viscous fluid in Robertson-Walker Universe is studied by using Brans-Dicke theory. The behaviour of these solutions with respect to Dirac's hypothesis are investigated along with the discussion of the physical parameters as well as the variable gravitational constant. By adopting a particular method of integration, exact solutions are obtained and physical interpretations are presented.     

The role of blocking system in heavy precipitation of Iran (a case study: southeast of Iran January 2008)

This article concerns the analysis of the heavy precipitation, which allows investigating the effect of the blocking system on the unusual precipitation and temperature occurrence in Iran. The days of January 2008 have been the coldest days during the history of recorded data in Iran. Variation of precipitation during January 2008 compared with long-term data (30 years) shows the maximum positive anomaly in the stations located in southeast of Iran. However, the precipitation in consecutive days, 14–15 and 15–16 of January, produce a more important proportion of the heavy precipitation in this region. In order to study the role of the blocking system related to heavy precipitation in January 2008, the position and movement of the atmospheric systems including cyclones, anticyclones, fronts, and wind fields have been analyzed by the use of synoptic maps by the environment to circulation approach. Consequently, the weather maps indicated that the blocking system over the north of the Caspian Sea has caused the relatively deep low trough on January 5, 7, 14, 15, and 16, 2008, while the thermal and moisture gradients in the warm section of air masses have produced heavy precipitation. As a result, wind field of low levels (850 hPa) provided remarkable moisture fed by the Arabian Sea, Oman Sea, and Persian Gulf in the study area. Furthermore, the speed of wavelength and the position of the blocking system associated with the heavy precipitation can be clearly identified.     

Mobilized side and tip resistances of piles in clay

This paper presents a procedure to assess the mobilized pile side and tip resistance versus pile head and tip settlement under axial load in clay soil. The load transfer (t–z) curve is evaluated at any point on the loaded pile based on the combined pile tip/side resistance–displacement mechanisms along the length of the pile. Unlike current methods that assume the pile settlements as a percentage of the pile/shaft diameter, the presented technique determines the side and tip resistance of the pile and the associated pile settlement under existing load based on the current stress/strain level in the surrounding soil up to failure (excessive settlement). The technique employs the concepts of the elastic theory and Ramberg–Osgood characterization of the stress–strain behavior of the clay soil. Case studies are also presented to exhibit the capabilities of the proposed procedure. The good agreement between measured and calculated load transfer curves along the pile and pile tip resistance versus pile head, side, and tip displacements shows the consistency of the proposed procedure. A computer code is developed to employ the presented technique.