Upper Cretaceous bottom current deposits,north-east Greenland

Reported ancient bottom current deposits in deep marine settings are scarce and most of them remain contentious. This study describes sedimentological, ichnological and petrographical characteristics of a drill core that covers ca 10 Myr of Upper Cretaceous stratigraphy at Hold with Hope, north-east Greenland. The core is divided into four facies associations, which are interpreted to reflect deposition from bottom currents, turbidity flows and hemipelagic settling in slope and/or near slope environments. The evidence for bottom current influence is three-fold. Firstly, pervasive indications of winnowing such as marine bioclast-rich lags and outsized clasts on ‘mud on mud’ contacts are suggestive of low-sediment concentration flows capable of transporting up to pebble-sized clasts. Common Mn–Fe–Mg rich carbonate matrix cements and various types of hiatal chemogenic lag deposits showing glauconite, apatite and carbonate clasts also point to condensation, prolonged exposure at the sediment–water interface and recurrent phases of sea-floor erosion. Secondly, such deposits can show indicators for tidal processes such as double mud-drapes, tangential bottom sets in dune-scale cross-bedding and cyclic rhythmites. Thirdly, inverse to normal grading at various scales is common in fully marine, commonly seafloor-derived sediments. Ichnological data indicate considerable taxonomic variability in the bottom current deposits, but recurrent fabrics are characteristically dominated by morphologically simple burrows such as Thalassinoides and Planolites, with secondary Phycosiphon, Nereites, Zoophycos and/or Chondrites. In general, opportunistic taxa are common whereas mature composite ichnofabrics are rare. The omission surfaces are locally burrowed with stiffground to firmground trace fossil suites. The results contribute to establishing sedimentological, ichnological and mineralogical criteria for recognition of bottom current deposits as well as to the understanding of the Late Cretaceous palaeoenvironmental evolution of the Arctic region.     

Properties of dust source material and volcanic ash in Iceland

The volcanic origin, primarily basaltic, of most of the surface material in Iceland influences its physical properties and appearance. Size distributions, shape analyses and melting experiments were made for surface material collected in high-erosion dust source areas and fresh volcanic ash deposits to determine whether they differ from one another and from dust from other major dust sources. The major differences found between Icelandic dust and dust from other major dust sources in the world, such as the Sahara, are in the particle shapes, lower density and darker colour. Icelandic dust particles greater than 20 μm retain volcanic morphological properties that are also found in fresh volcanic ash. Dust and fresh volcanic ash particles less than 20 μm are crystalline and blocky in nature, similar to the dust from other global source regions. The finer grained (<20 μm) Icelandic particles will have similar suspension and transport behaviours and be similarly hazardous to health and infrastructure as non-Icelandic dust. The coarser particles (>20 μm) will have different suspension and transport behaviours than other dusts due to the volcanic morphology. Icelandic surface material has between 5% and 30% glassy particles compared to fresh volcanic ash which has more than 50% glassy particles. Glassy particles were observed to melt at a lower temperature than the mineral grains; and, as a result, volcanic ash is found to be more threatening to aircraft engines than the typical dust from Iceland. Icelandic dust was observed to be blocky, or plate-like in the respirable size fraction, suggesting similar health hazards as dust from other regions.     

Biotransformation of polycyclic aromatic hydrocarbons in marine polychaetes

Deposit-feeding polychaetes constitute the dominant macrofauna in marine environments that tend to be depositional centers for organic matter and contaminants. Polychaetes are known to accumulate polycyclic aromatic hydrocarbons (PAHs) from both particulate and dissolved phases but less is known about the mechanisms underlying elimination of accumulated PAHs. An important pathway of elimination is through biotransformation which results in increased aqueous solubility of the otherwise hydrophobic PAHs. Biotransformation in marine polychaetes proceeds in a two phased process similar to those well studied in vertebrates, phase I enzymes belonging to the Cytochrome P450 (CYP) enzyme family, along with a few phase II enzymes have been identified in marine polychaetes. In this review we aim at highlighting advances in the mechanistic understanding of PAH biotransformation in marine polychaetes by including data obtained using analytical chemistry and molecular techniques. In marine polychaetes induction of CYP enzyme activity after exposure to PAHs and the mechanism behind this is currently not well established. Conflicting results regarding the inducibility of CYP enzymes from polychaetes have led to the suggestion that induction in polychaetes is mediated through a different mechanistic pathway, which is corroborated by the apparent lack of an AhR homologous in marine polychaetes. Also, none of the currently identified CYP genes from marine polychaetes are isoforms of those regulated by the AhR in vertebrates. Relatively few studies of phase II enzymes in marine polychaetes are currently available and most of these studies have not measured the activity of specific phase II enzymes and identified phase II metabolites but used an extraction technique only allowing determination of the overall amount of phase II metabolites. Studies in insects and various marine invertebrates suggest that in invertebrates, enzymes in the important phase II enzyme family, UDP-glucuronosyl transferases primarily use glucoside as co-substrate as opposed to the vertebrate cosubstrate glucuronic acid. Recent studies in marine polychaetes have however identified glucuronidation of PAHs indicating no mechanistic difference in co-substrate preference among UDP-glucuronosyl transferases between vertebrates and marine polychaetes but it might suggest a mechanistic difference between marine polychaetes and insects.     

Origin and fate of particulate organic matter in the southern Beaufort Sea – Amundsen Gulf region,Canadian Arctic

To establish the relative importance of terrigenous and marine organic matter in the southern Beaufort Sea, we measured the concentrations and the stable isotopic compositions of organic carbon and total nitrogen in sediments and in settling particles intercepted by sediment traps. The organic carbon content of surface sediment in the Chukchi and southern Beaufort Seas ranged from 0.6 to 1.6% dry wt., without a clear geographical pattern. The C_ORG:N_TOT ratio ranged from 7.0 to 10.4 and did not vary significantly downcore at any one station. Values of δ¹³C_ORG and δ¹⁵N_TOT in the sediment samples were strongly correlated, with the highest values, indicative of a more marine contribution, in the Amundsen Gulf. In contrast, the organic matter content, elemental (C_ORG:N_TOT ratio) and isotopic (δ¹³C_ORG and δ¹⁵N_TOT) composition of the settling particles was different from and much more variable than in the bottom sediments. The isotopic signature of organic matter in the Beaufort Sea is well constrained by three distinct end-members: a labile marine component produced in situ by planktonic organisms, a refractory marine component, the end product of respiration and diagenesis, and a refractory terrigenous component. A three-component mixing model explains the scatter observed in the stable isotope signatures of the sediment trap samples and accommodates an apparent two-component mixing model of the organic matter in sediments. The suspended matter in the water column contains organic matter varying from essentially labile and marine to mostly refractory and terrigenous. As it settles through the water column, the labile marine organic matter is degraded, and its original stable isotope signature changes towards the signature of the marine refractory component. This process continues in the bottom sediment with the result that the sedimentary organic matter becomes dominated by the refractory terrigenous and marine components.     

Coastal currents adjacent to the Caeté Estuary,Pará Region,North Brazil

We examined and compared tidal currents and water column structure between a near-shore station (12 km from the coast) and an offshore station (32 km from the coast) adjacent to the Caeté River, Pará Region, Brazil. Although the coastal system of Pará is largely influenced by local tides and wind, we found substantial differences in the dominant forcing agents between stations. Water column dynamics at the near-shore station were largely affected by local tidal processes, while differences between surface and bottom layer flows also indicated the importance of gravitational circulation at this station and a substantial influence of the adjacent Caeté River discharge. In comparison, at the offshore station, water column structure was largely influenced by a semi-diurnal tidal flow, an along-coastal current flow (mainly associated with the North Brazil Current) and the dynamics of local wind flow. The near-shore station at low tide showed a high level of stratification; at high tide such stratification was reduced. In comparison, stratification was only apparent within the upper 6 m at the offshore station, the rest of the water column was relatively well-mixed. The stratification within Station 1 at low tide was a result of the bi-directional movement of water discharged from the Caeté River, with lower salinity surface water and high salinity bottom water resulting in an estuarine-like circulation environment. The spatial variability and lack of correlation in current flow and water column structure between the near-shore and offshore stations suggest that a flow field resulting from differences in local circulation, tidal variability and wind persistence separate areas. We argue that this separation may indicate that the offshore station is located in a transition region between the Caeté River waters and the local coastal area.     

Phytoscreening for Vinyl Chloride in Groundwater Discharging to a Stream

This study applies an optimized phytoscreening method to locate a chlorinated ethene plume discharging into a stream. To evaluate the conditions most suitable for successful phytoscreening, trees along the stream bank were monitored through different seasons with different environmental conditions and hence different uptake/loss scenarios. Vinyl chloride (VC) as well as cis‐dichloroethylene (cis‐DCE), trichloroethylene (TCE), and tetrachloroethylene (PCE) were detected in the trees, documenting that phytoscreening is a viable method to locate chlorinated ethene plumes, including VC, discharging to streams. The results reveal, that phytoscreening for VC is more sensitive to environmental conditions affecting transpiration than for the other chlorinated ethenes detected. Conditions leading to higher groundwater uptake by transpiration than contaminant loss by diffusion from the tree trunks are optimal (e.g., low relative humidity, plentiful hours of sunshine and an intermediate air temperature). Additionally, low precipitation prior to the sampling event is beneficial, as uptake of infiltrating precipitation dilutes the concentration in the trees. All chlorinated ethenes were sensitive to dilution by clean precipitation and in some months, this resulted in no detection of contaminants in the trees at all. Under optimal environmental conditions the tree cores allowed detection of chlorinated solvents and their metabolites in the underlying groundwater. Whereas, for less ideal conditions there was a risk of no detection of the more volatile VC. This study is promising for the future applicability of phytoscreening to locate shallow groundwater contamination with the degradation products of chlorinated solvents.     

Using an eddy-tracking algorithm to understand the impact of assimilating altimetry data on the eddy characteristics of the Agulhas system

A complex and highly dynamical ocean region, the Agulhas Current System plays an important role in the transfer of energy, nutrients and organic material from the Indian to the Atlantic Ocean. Its dynamics are not only important locally, but affect the global ocean-atmosphere system. In working towards improved ocean reanalysis and forecasting capabilities, it is important that numerical models simulate mesoscale variability accurately—especially given the scarcity of coherent observational platforms in the region. Data assimilation makes use of scarce observations, a dynamical model and their respective error statistics to estimate a new, improved model state that minimises the distance to the observations whilst preserving dynamical consistency. Qualitatively, it is unclear whether this minimisation directly translates to an improved representation of mesoscale dynamics. In this study, the impact of assimilating along-track sea-level anomaly (SLA) data into a regional Hybrid Coordinate Ocean Model (HYCOM) is investigated with regard to the simulation of mesoscale eddy characteristics. We use an eddy-tracking algorithm and compare the derived eddy characteristics of an assimilated (ASSIM) and an unassimilated (FREE) simulation experiment in HYCOM with gridded satellite altimetry-derived SLA data. Using an eddy tracking algorithm, we are able to quantitatively evaluate whether assimilation updates the model state estimate such that simulated mesoscale eddy characteristics are improved. Additionally, the analysis revealed limitations in the dynamical model and the data assimilation scheme, as well as artefacts introduced from the eddy tracking scheme. With some exceptions, ASSIM yields improvements over FREE in eddy density distribution and dynamics. Notably, it was found that FREE significantly underestimates the number of eddies south of Madagascar compared to gridded altimetry, with only slight improvements introduced through assimilation, highlighting the models’ limitation in sustaining mesoscale activity in this region. Interestingly, it was found that the threshold for the maximum eddy propagation velocity in the eddy detection scheme is often exceeded when data assimilation relocates an eddy, causing the algorithm to interpret the discontinuity as eddy genesis, which directly influences the eddy count, lifetime and propagation velocity, and indirectly influences other metrics such as non-linearity. Finally, the analysis allowed us to separate eddy kinetic energy into contributions from detected mesoscale eddies and meandering currents, revealing that the assimilation of SLA has a greater impact on mesoscale eddies than on meandering currents.     

The relative impact of future storminess versus offshore dredging on suspended sediment concentration in a shallow coastal embayment: Rødsand lagoon,western Baltic Sea

Natural and human-induced disturbances challenge the resilience of coastal ecosystems. The relative impact of a projected increase in storm intensity versus a temporary sediment spill from the construction of the planned Fehmarnbelt Fixed Link on the suspended sediment concentrations was estimated in the shallow coastal embayment of Rødsand lagoon. The investigations were performed through a combination of field observations and numerical modeling. The numerical model was calibrated and validated with the field observations. The lagoonal response to a regional increase in wind speed showed temporarily amplified suspended particulate matter concentration (SPMC) levels (26–37%) and amplified exceedance duration above wash load (30–32%) in the entire lagoon, but especially in the shallow regions. The lagoonal response to a sediment spill outside Rødsand lagoon showed temporarily amplified SPMC levels (2–4%) and amplified exceedance duration above wash load (1–2%) in the entire lagoon, but especially in the regions in close proximity to the spill source. The regional response to increasing wind speed was thus 10-fold larger than the sediment spill where only advective sediment transport took place. This highlights the importance of the internal lagoonal processes as opposed to exterior disturbances. The study contributed to an improved understanding of the potential natural and human-induced stressors on the sediment dynamics in lagoonal ecosystems.

     

Direct finite element method for nonlinear analysis of semi‐unbounded dam–water–foundation rock systems

A direct finite element method is presented for nonlinear earthquake analysis of interacting dam–water–foundation rock systems. The analysis procedure applies viscous damper absorbing boundaries to truncate the semi‐unbounded fluid and foundation‐rock domains and specifies at these boundaries effective earthquake forces determined from the design ground motion defined at a control point on the free surface. The analysis procedure is validated numerically by computing the frequency response functions and transient response of an idealized dam–water–foundation rock system and comparing with results from the substructure method. Because the analysis procedure is applicable to nonlinear systems, it allows for modeling of concrete cracking, as well as sliding and separation at construction joints, lift joints, and at concrete–rock interfaces. Implementation of the procedure is facilitated by commercial finite element software with nonlinear material models that permit modeling of viscous damper boundaries and specification of effective earthquake forces at these boundaries. Copyright © 2017 John Wiley & Sons, Ltd.     

A simple approach to adjust tidal forcing in fjord models

To model currents in a fjord accurate tidal forcing is of extreme importance. Due to complex topography with narrow and shallow straits, the tides in the innermost parts of a fjord are both shifted in phase and altered in amplitude compared to the tides in the open water outside the fjord. Commonly, coastal tide information extracted from global or regional models is used on the boundary of the fjord model. Since tides vary over short distances in shallower waters close to the coast, the global and regional tidal forcings are usually too coarse to achieve sufficiently accurate tides in fjords. We present a straightforward method to remedy this problem by simply adjusting the tides to fit the observed tides at the entrance of the fjord. To evaluate the method, we present results from the Oslofjord, Norway. A model for the fjord is first run using raw tidal forcing on its open boundary. By comparing modelled and observed time series of water level at a tidal gauge station close to the open boundary of the model, a factor for the amplitude and a shift in phase are computed. The amplitude factor and the phase shift are then applied to produce adjusted tidal forcing at the open boundary. Next, we rerun the fjord model using the adjusted tidal forcing. The results from the two runs are then compared to independent observations inside the fjord in terms of amplitude and phases of the various tidal components, the total tidal water level, and the depth integrated tidal currents. The results show improvements in the modelled tides in both the outer, and more importantly, the inner parts of the fjord.